| Records |
| Author |
Belz, L.; Schüller, I.; Wehrmann, A.; Köster, J.; Wilkes, H. |
| Title |
The leaf wax biomarker record of a Namibian salt pan reveals enhanced summer rainfall during the Last Glacial-Interglacial Transition |
Type |
Journal Article |
| Year |
2020 |
Publication |
Palaeogeography, Palaeoclimatology, Palaeoecology |
Abbreviated Journal |
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| Volume |
543 |
Issue |
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Pages |
109561 |
| Keywords |
-Alkanes, -Alkanols, Late Quaternary, Organic geochemistry, Palaeohydrology, Southern Africa |
Abstract  |
Conventional continental geoarchives are rarely available in arid southern Africa. Therefore, palaeoclimate data in this area are still patchy and late Quaternary climate development is only poorly understood. In the western Kalahari, salt pans (playas, ephemeral lakes) are common and can feature quasi-continuous sedimentation. This study presents the first climate-related biomarker record using sediments from the Omongwa Pan, a Kalahari salt pan located in eastern Namibia. Our approach to reconstruct vegetation and hydrology focuses on biogeochemical bulk parameters and plant wax-derived lipid biomarkers (n-alkanes, n-alkanols, and fatty acids) and their compound-specific carbon and hydrogen isotopic compositions. The presented record reaches back to 27 ka. During the glacial, rather low δ2H values of n-alkanes and low sediment input exclude a strong influence of winter rainfall. n-Alkane and n-alkanol distributions and δ13C values of n-hentriacontane (n-C31) indicate a shift to a vegetation with a higher proportion of C4 plants at the end of the Last Glacial Maximum until the end of Heinrich Stadial I (ca. 18–14.8 ka), which we interpret to indicate an abrupt excursion to a short wetter period likely to be caused by a temporary southward shift of the Intertropical Convergence Zone. Shifts in δ2H values of n-C31 and plant wax parameters give evidence for changes to drier conditions during early Holocene. Comparison of this dataset with representative continental records from the region points to a major influence of summer rainfall at Omongwa Pan during the regarded time span and demonstrates the potential of southern African salt pans as archives for biomarker-based climate proxies. |
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0031-0182 |
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no |
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THL @ christoph.kuells @ belz_leaf_2020 |
Serial |
104 |
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| Author |
Heaton, T.H.E.; Talma, A.S.; Vogel, J.C. |
| Title |
Origin and history of nitrate in confined groundwater in the western Kalahari |
Type |
Journal Article |
| Year |
1983 |
Publication |
Journal of Hydrology |
Abbreviated Journal |
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| Volume |
62 |
Issue |
1 |
Pages |
243-262 |
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| Abstract |
Data are presented for nitrate, dinitrogen and argon concentrations and 15N14N ratios in groundwater, with radiocarbon ages up to 40,000 yr. for three confined sandstone aquifers in the western Kalahari of South West Africa/Namibia. The nitrate is probably generated within the soil of the recharge areas, and its production rate during the period 3000-40,000 B.P. has remained between 0.5 and 1.6 meq NO−3l−1 of recharge water, with ° 15N between + 4 and + 8‰. Variations in the amount of nitrate and of “excess air” in groundwater recharge are found, and can only reflect changes in the environmental conditions during recharge. They must therefore be caused by the climatic changes that have taken place during the past 25,000 yr. |
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0022-1694 |
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no |
| Call Number |
THL @ christoph.kuells @ heaton_origin_1983 |
Serial |
95 |
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| Author |
Heaton, T.H.E.; Talma, A.S.; Vogel, J.C. |
| Title |
Origin and history of nitrate in confined groundwater in the western Kalahari |
Type |
Journal Article |
| Year |
1983 |
Publication |
Journal of Hydrology |
Abbreviated Journal |
|
| Volume |
62 |
Issue |
1 |
Pages |
243-262 |
| Keywords |
|
| Abstract |
Data are presented for nitrate, dinitrogen and argon concentrations and 15N14N ratios in groundwater, with radiocarbon ages up to 40,000 yr. for three confined sandstone aquifers in the western Kalahari of South West Africa/Namibia. The nitrate is probably generated within the soil of the recharge areas, and its production rate during the period 3000-40,000 B.P. has remained between 0.5 and 1.6 meq NO−3l−1 of recharge water, with ° 15N between + 4 and + 8‰. Variations in the amount of nitrate and of “excess air” in groundwater recharge are found, and can only reflect changes in the environmental conditions during recharge. They must therefore be caused by the climatic changes that have taken place during the past 25,000 yr. |
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0022-1694 |
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no |
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THL @ christoph.kuells @ Heaton1983243 |
Serial |
282 |
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| Author |
Külls, C. |
| Title |
Demonstration des Potentials der Nitrat-Isotopenanalytik für die Strategieentwicklung der Sanierung Nitrat-belasteter Brunnen |
Type |
Report |
| Year |
2004 |
Publication |
Umweltbundesamt |
Abbreviated Journal |
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Issue |
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Pages |
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| Keywords |
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| Abstract |
Demonstration des Potentials der Nitrat-Isotopenanalytik für die Strategieentwicklung der Sanierung Nitrat-belasteter Brunnen |
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no |
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THL @ christoph.kuells @ |
Serial |
75 |
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| Author |
Sahoo, P.K.; Virk, H.S.; Powell, M.A.; Kumar, R.; Pattanaik, J.K.; Salomão, G.N.; Mittal, S.; Chouhan, L.; Nandabalan, Y.K.; Tiwari, R.P. |
| Title |
Meta-analysis of uranium contamination in groundwater of the alluvial plains of Punjab, northwest India: Status, health risk, and hydrogeochemical processes |
Type |
Journal Article |
| Year |
2022 |
Publication |
Science of The Total Environment |
Abbreviated Journal |
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| Volume |
807 |
Issue |
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Pages |
151753 |
| Keywords |
Agrochemicals, Geogenic contamination, Punjab, Salinity, Shallow aquifer, Uranium enrichment |
| Abstract |
Despite numerous studies, there are many knowledge gaps in our understanding of uranium (U) contamination in the alluvial aquifers of Punjab, India. In this study, a large hydrogeochemical dataset was compiled to better understand the major factors controlling the mobility and enrichment of uranium (U) in this groundwater system. The results showed that shallow groundwaters (\textless60 m) are more contaminated with U than from deeper depths (\textgreater60 m). This effect was predominant in the Southwest districts of the Malwa, facing significant risk due to chemical toxicity of U. Groundwaters are mostly oxidizing and alkaline (median pH: 7.25 to 7.33) in nature. Spearman correlation analysis showed that U concentrations are more closely related to total dissolved solids (TDS), salinity, Na, K, HCO3−, NO3− Cl−, and F− in shallow water than deep water, but TDS and salinity remained highly correlated (U-TDS: ρ = 0.5 to 0.6; U-salinity: ρ = 0.5). This correlation suggests that the salt effect due to high competition between ions is the principal cause of U mobilization. This effect is evident when the U level increased with increasing mixed water species (Na-Cl, Mg-Cl, and Na-HCO3). Speciation data showed that the most dominant U species are Ca2UO2(CO3)2− and CaUO2(CO3)3−, which are responsible for the U mobility. Based on the field parameters, TDS along with pH and oxidation-reduction potential (ORP) were better fitted to U concentration above the WHO guideline value (30 μg.L−1), thus this combination could be used as a quick indicator of U contamination. The strong positive correlation of U with F− (ρ = 0.5) in shallow waters indicates that their primary source is geogenic, while anthropogenic factors such as canal irrigation, groundwater table decline, and use of agrochemicals (mainly nitrate fertilizers) as well as climate-related factors i.e., high evaporation under arid/semi-arid climatic conditions, which result in higher redox and TDS/salinity levels, may greatly affect enrichment of U. The geochemical rationale of this study will provide Science-based-policy implications for U health risk assessment in this region and further extrapolate these findings to other arid/semi-arid areas worldwide. |
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0048-9697 |
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no |
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THL @ christoph.kuells @ sahoo_meta-analysis_2022 |
Serial |
150 |
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| Author |
Xiao, L.; Robinson, M.; O’Connor, M. |
| Title |
Woodland’s role in natural flood management: Evidence from catchment studies in Britain and Ireland |
Type |
Journal Article |
| Year |
2022 |
Publication |
Science of The Total Environment |
Abbreviated Journal |
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| Volume |
813 |
Issue |
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Pages |
151877 |
| Keywords |
Forest harvesting, Streamflow, Natural flood management, Before-after-control-impact, Evidence-based forest impact |
| Abstract |
Despite the attention currently given to the potential environmental benefits of large-scale forest planting, there is a shortage of clear observational evidence regarding the effects on river flows, and what there is has often been contradictory or inconclusive. This paper presents three independently conducted paired-catchment forestry studies covering 66 station-years of flow measurements in the UK and Ireland. In each case coniferous evergreen trees were removed from one catchment with minimal soil disturbance while the adjoining control catchment was left unchanged. Trees were removed from 20% – 90% of the three experimental basins. Following woodland removal there was an increase in dry weather baseflow at all sites. Baseflows increased by about 8% after tree removal from a quarter of the Hore basin and by 41% for the near-total cut at Howan. But the changes were more complex for peak flows. Tree harvesting increased the smallest and most frequent peak storm flows, indicating that afforestation would lead to the suppression of such events. This was however restricted to events well below the mean annual flood, indicating that the impact of forests upon the largest and most damaging floods is likely to be limited. Whilst a forest cover can be effective in mitigating small and frequent stormflows it should never be assumed to provide protection against major flood events. |
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0048-9697 |
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no |
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THL @ christoph.kuells @ Xiao2022151877 |
Serial |
241 |
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| Author |
Johnson, R.S.H.; Alila, Y. |
| Title |
Nonstationary stochastic paired watershed approach: Investigating forest harvesting effects on floods in two large, nested, and snow-dominated watersheds in British Columbia, Canada |
Type |
Journal Article |
| Year |
2023 |
Publication |
Journal of Hydrology |
Abbreviated Journal |
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| Volume |
625 |
Issue |
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Pages |
129970 |
| Keywords |
Probabilistic physics, Forest hydrology, Attribution science, Flood Frequency Analysis, Stochastic hydrology, Nonstationarity |
| Abstract |
Drawing on advances in nonstationary frequency analysis and the science of causation and attribution, this study employs a newly developed nonstationary stochastic paired watershed approach to determine the effect of forest harvesting on snowmelt-generated floods. Moreover, this study furthers the application of stochastic physics to evaluate the environmental controls and drivers of flood response. Physically-based climate and time-varying harvesting data are used as covariates to drive the nonstationary flood frequency distribution parameters to detect, attribute, and quantify the effect of harvesting on floods in the snow-dominated Deadman River (878 km2) and nested Joe Ross Creek (99 km2) watersheds. Harvesting only 21% of the watershed caused a 38% and 84% increase in the mean but no increase in variability around the mean of the frequency distribution in the Deadman River and Joe Ross Creek, respectively. Consequently, the 7-year, 20-year, 50-year, and 100-year flood events became approximately two, four, six, and ten times more frequent in both watersheds. An increase in the mean is posited to occur from an increase in moisture availability following harvest from suppressed snow interception and increased net radiation reaching the snowpack. Variability was not increased because snowmelt synchronization was inhibited by the buffering capacity of abundant lakes, evenly distributed aspects, and widespread spatial distribution of cutblocks in the watersheds, preventing any potential for harvesting to increase the efficiency of runoff delivery to the outlet. Consistent with similar recent studies, the effect of logging on floods is controlled not only by the harvest rate but most importantly the physiographic characteristics of the watershed and the spatial distribution of the cutblocks. Imposed by the probabilistic framework to understanding and predicting the relation between extremes and their environmental controls, commonly used in the general sciences but not forest hydrology, it is the inherent nature of snowmelt-driven flood regimes which cause even modest increases in magnitude, especially in the upper tail of the distribution, to translate into surprisingly large changes in frequency. Contrary to conventional wisdom, harvesting influenced small, medium, and very large flood events, and the sensitivity to harvest increased with increasing flood event size and watershed area. |
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0022-1694 |
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no |
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THL @ christoph.kuells @ Johnson2023129970 |
Serial |
245 |
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Dąbrowska, J.; Orellana, A.E.M.; Kilian, W.; Moryl, A.; Cielecka, N.; Michałowska, K.; Policht-Latawiec, A.; Michalski, A.; Bednarek, A.; Włóka, A. |
| Title |
Between flood and drought: How cities are facing water surplus and scarcity |
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Journal Article |
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2023 |
Publication |
Journal of Environmental Management |
Abbreviated Journal |
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345 |
Issue |
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Pages |
118557 |
| Keywords |
Urban ecosystem management, Urban floods, Urban droughts, Nature-based solutions, Climate change, Urban resilience |
| Abstract |
Droughts and floods are weather-related hazards affecting cities in all climate zones and causing human deaths and material losses on all inhabited continents. The aim of this article is to review, analyse and discuss in detail the problems faced by urban ecosystems due to water surplus and scarcity, as well as the need of adaptation to climate change taking into account the legislation, current challenges and knowledge gaps. The literature review indicated that urban floods are much more recognised than urban droughts. Amongst floods, flash floods are currently the most challenging, which by their nature are difficult to monitor. Research and adaptation measures related to water-released hazards use cutting-edge technologies for risk assessment, decision support systems, or early warning systems, among others, but in all areas knowledge gaps for urban droughts are evident. Increasing urban retention and introducing Low Impact Development and Nature-based Solutions is a remedy for both droughts and floods in cities. There is the need to integrate flood and drought disaster risk reduction strategies and creating a holistic approach. |
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0301-4797 |
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THL @ christoph.kuells @ Dabrowska2023118557 |
Serial |
227 |
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| Author |
Liesch, T.; Hinrichsen, S.; Goldscheider, N. |
| Title |
Uranium in groundwater — Fertilizers versus geogenic sources |
Type |
Journal Article |
| Year |
2015 |
Publication |
Science of The Total Environment |
Abbreviated Journal |
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| Volume |
536 |
Issue |
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Pages |
981-995 |
| Keywords |
Drinking water, Fertilizer, Geogenic background, Groundwater, Uranium |
| Abstract |
Due to its radiological and toxicological properties even at low concentration levels, uranium is increasingly recognized as relevant contaminant in drinking water from aquifers. Uranium originates from different sources, including natural or geogenic, mining and industrial activities, and fertilizers in agriculture. The goal of this study was to obtain insights into the origin of uranium in groundwater while differentiating between geogenic sources and fertilizers. A literature review concerning the sources and geochemical processes affecting the occurrence and distribution of uranium in the lithosphere, pedosphere and hydrosphere provided the background for the evaluation of data on uranium in groundwater at regional scale. The state of Baden-Württemberg, Germany, was selected for this study, because of its hydrogeological and land-use diversity, and for reasons of data availability. Uranium and other parameters from N=1935 groundwater monitoring sites were analyzed statistically and geospatially. Results show that (i) 1.6% of all water samples exceed the German legal limit for drinking water (10μg/L); (ii) The range and spatial distribution of uranium and occasional peak values seem to be related to geogenic sources; (iii) There is a clear relation between agricultural land-use and low-level uranium concentrations, indicating that fertilizers generate a measurable but low background of uranium in groundwater. |
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0048-9697 |
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THL @ christoph.kuells @ liesch_uranium_2015 |
Serial |
145 |
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| Author |
Yabusaki, S.B.; Fang, Y.; Long, P.E.; Resch, C.T.; Peacock, A.D.; Komlos, J.; Jaffe, P.R.; Morrison, S.J.; Dayvault, R.D.; White, D.C.; Anderson, R.T. |
| Title |
Uranium removal from groundwater via in situ biostimulation: Field-scale modeling of transport and biological processes |
Type |
Journal Article |
| Year |
2007 |
Publication |
Journal of Contaminant Hydrology |
Abbreviated Journal |
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| Volume |
93 |
Issue |
1 |
Pages |
216-235 |
| Keywords |
Bioremediation, Biostimulation, Field experiment, Iron, Reactive transport, Sulfate, Uranium |
| Abstract |
During 2002 and 2003, bioremediation experiments in the unconfined aquifer of the Old Rifle UMTRA field site in western Colorado provided evidence for the immobilization of hexavalent uranium in groundwater by iron-reducing Geobacter sp. stimulated by acetate amendment. As the bioavailable Fe(III) terminal electron acceptor was depleted in the zone just downgradient of the acetate injection gallery, sulfate-reducing organisms came to dominate the microbial community. In the present study, we use multicomponent reactive transport modeling to analyze data from the 2002 field experiment to identify the dominant transport and biological processes controlling uranium mobility during biostimulation, and determine field-scale parameters for these modeled processes. The coupled process simulation approach was able to establish a quantitative characterization of the principal flow, transport, and reaction processes based on the 2002 field experiment, that could be applied without modification to describe the 2003 field experiment. Insights gained from this analysis include field-scale estimates of the bioavailable Fe(III) mineral threshold for the onset of sulfate reduction, and rates for the Fe(III), U(VI), and sulfate terminal electron accepting processes. |
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| ISSN |
0169-7722 |
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no |
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THL @ christoph.kuells @ yabusaki_uranium_2007 |
Serial |
156 |
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