| Records |
| Author |
Belz, L.; Schüller, I.; Wehrmann, A.; Köster, J.; Wilkes, H. |
| Title |
The leaf wax biomarker record of a Namibian salt pan reveals enhanced summer rainfall during the Last Glacial-Interglacial Transition |
Type |
Journal Article |
| Year |
2020 |
Publication |
Palaeogeography, Palaeoclimatology, Palaeoecology |
Abbreviated Journal |
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| Volume |
543 |
Issue |
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Pages |
109561 |
| Keywords |
-Alkanes, -Alkanols, Late Quaternary, Organic geochemistry, Palaeohydrology, Southern Africa |
Abstract  |
Conventional continental geoarchives are rarely available in arid southern Africa. Therefore, palaeoclimate data in this area are still patchy and late Quaternary climate development is only poorly understood. In the western Kalahari, salt pans (playas, ephemeral lakes) are common and can feature quasi-continuous sedimentation. This study presents the first climate-related biomarker record using sediments from the Omongwa Pan, a Kalahari salt pan located in eastern Namibia. Our approach to reconstruct vegetation and hydrology focuses on biogeochemical bulk parameters and plant wax-derived lipid biomarkers (n-alkanes, n-alkanols, and fatty acids) and their compound-specific carbon and hydrogen isotopic compositions. The presented record reaches back to 27 ka. During the glacial, rather low δ2H values of n-alkanes and low sediment input exclude a strong influence of winter rainfall. n-Alkane and n-alkanol distributions and δ13C values of n-hentriacontane (n-C31) indicate a shift to a vegetation with a higher proportion of C4 plants at the end of the Last Glacial Maximum until the end of Heinrich Stadial I (ca. 18–14.8 ka), which we interpret to indicate an abrupt excursion to a short wetter period likely to be caused by a temporary southward shift of the Intertropical Convergence Zone. Shifts in δ2H values of n-C31 and plant wax parameters give evidence for changes to drier conditions during early Holocene. Comparison of this dataset with representative continental records from the region points to a major influence of summer rainfall at Omongwa Pan during the regarded time span and demonstrates the potential of southern African salt pans as archives for biomarker-based climate proxies. |
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0031-0182 |
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no |
| Call Number |
THL @ christoph.kuells @ belz_leaf_2020 |
Serial |
104 |
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| Author |
Heaton, T.H.E.; Talma, A.S.; Vogel, J.C. |
| Title |
Origin and history of nitrate in confined groundwater in the western Kalahari |
Type |
Journal Article |
| Year |
1983 |
Publication |
Journal of Hydrology |
Abbreviated Journal |
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| Volume |
62 |
Issue |
1 |
Pages |
243-262 |
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| Abstract |
Data are presented for nitrate, dinitrogen and argon concentrations and 15N14N ratios in groundwater, with radiocarbon ages up to 40,000 yr. for three confined sandstone aquifers in the western Kalahari of South West Africa/Namibia. The nitrate is probably generated within the soil of the recharge areas, and its production rate during the period 3000-40,000 B.P. has remained between 0.5 and 1.6 meq NO−3l−1 of recharge water, with ° 15N between + 4 and + 8‰. Variations in the amount of nitrate and of “excess air” in groundwater recharge are found, and can only reflect changes in the environmental conditions during recharge. They must therefore be caused by the climatic changes that have taken place during the past 25,000 yr. |
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0022-1694 |
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no |
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THL @ christoph.kuells @ heaton_origin_1983 |
Serial |
95 |
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| Author |
Heaton, T.H.E.; Talma, A.S.; Vogel, J.C. |
| Title |
Origin and history of nitrate in confined groundwater in the western Kalahari |
Type |
Journal Article |
| Year |
1983 |
Publication |
Journal of Hydrology |
Abbreviated Journal |
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| Volume |
62 |
Issue |
1 |
Pages |
243-262 |
| Keywords |
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| Abstract |
Data are presented for nitrate, dinitrogen and argon concentrations and 15N14N ratios in groundwater, with radiocarbon ages up to 40,000 yr. for three confined sandstone aquifers in the western Kalahari of South West Africa/Namibia. The nitrate is probably generated within the soil of the recharge areas, and its production rate during the period 3000-40,000 B.P. has remained between 0.5 and 1.6 meq NO−3l−1 of recharge water, with ° 15N between + 4 and + 8‰. Variations in the amount of nitrate and of “excess air” in groundwater recharge are found, and can only reflect changes in the environmental conditions during recharge. They must therefore be caused by the climatic changes that have taken place during the past 25,000 yr. |
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0022-1694 |
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THL @ christoph.kuells @ Heaton1983243 |
Serial |
282 |
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| Author |
Külls, C. |
| Title |
Demonstration des Potentials der Nitrat-Isotopenanalytik für die Strategieentwicklung der Sanierung Nitrat-belasteter Brunnen |
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Report |
| Year |
2004 |
Publication |
Umweltbundesamt |
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Issue |
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Pages |
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Demonstration des Potentials der Nitrat-Isotopenanalytik für die Strategieentwicklung der Sanierung Nitrat-belasteter Brunnen |
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no |
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THL @ christoph.kuells @ |
Serial |
75 |
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Sahoo, P.K.; Virk, H.S.; Powell, M.A.; Kumar, R.; Pattanaik, J.K.; Salomão, G.N.; Mittal, S.; Chouhan, L.; Nandabalan, Y.K.; Tiwari, R.P. |
| Title |
Meta-analysis of uranium contamination in groundwater of the alluvial plains of Punjab, northwest India: Status, health risk, and hydrogeochemical processes |
Type |
Journal Article |
| Year |
2022 |
Publication |
Science of The Total Environment |
Abbreviated Journal |
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| Volume |
807 |
Issue |
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Pages |
151753 |
| Keywords |
Agrochemicals, Geogenic contamination, Punjab, Salinity, Shallow aquifer, Uranium enrichment |
| Abstract |
Despite numerous studies, there are many knowledge gaps in our understanding of uranium (U) contamination in the alluvial aquifers of Punjab, India. In this study, a large hydrogeochemical dataset was compiled to better understand the major factors controlling the mobility and enrichment of uranium (U) in this groundwater system. The results showed that shallow groundwaters (\textless60 m) are more contaminated with U than from deeper depths (\textgreater60 m). This effect was predominant in the Southwest districts of the Malwa, facing significant risk due to chemical toxicity of U. Groundwaters are mostly oxidizing and alkaline (median pH: 7.25 to 7.33) in nature. Spearman correlation analysis showed that U concentrations are more closely related to total dissolved solids (TDS), salinity, Na, K, HCO3−, NO3− Cl−, and F− in shallow water than deep water, but TDS and salinity remained highly correlated (U-TDS: ρ = 0.5 to 0.6; U-salinity: ρ = 0.5). This correlation suggests that the salt effect due to high competition between ions is the principal cause of U mobilization. This effect is evident when the U level increased with increasing mixed water species (Na-Cl, Mg-Cl, and Na-HCO3). Speciation data showed that the most dominant U species are Ca2UO2(CO3)2− and CaUO2(CO3)3−, which are responsible for the U mobility. Based on the field parameters, TDS along with pH and oxidation-reduction potential (ORP) were better fitted to U concentration above the WHO guideline value (30 μg.L−1), thus this combination could be used as a quick indicator of U contamination. The strong positive correlation of U with F− (ρ = 0.5) in shallow waters indicates that their primary source is geogenic, while anthropogenic factors such as canal irrigation, groundwater table decline, and use of agrochemicals (mainly nitrate fertilizers) as well as climate-related factors i.e., high evaporation under arid/semi-arid climatic conditions, which result in higher redox and TDS/salinity levels, may greatly affect enrichment of U. The geochemical rationale of this study will provide Science-based-policy implications for U health risk assessment in this region and further extrapolate these findings to other arid/semi-arid areas worldwide. |
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0048-9697 |
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no |
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THL @ christoph.kuells @ sahoo_meta-analysis_2022 |
Serial |
150 |
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