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Author Edmunds, W.M.; Shand, P.; Hart, P.; Ward, R.S.
Title The natural (baseline) quality of groundwater: a UK pilot study Type Journal Article
Year 2003 Publication Science of The Total Environment Abbreviated Journal
Volume 310 Issue 1 Pages 25-35
Keywords Baseline quality, Groundwater, Hydrogeochemistry, Monitoring, Water Policy
Abstract (up) Knowledge of the natural baseline quality of groundwaters is an essential prerequisite for understanding pollution and for imposing regulatory limits. The natural baseline of groundwaters may show a range of concentrations depending on aquifer mineralogy, facies changes, flow paths and residence time. The geochemical controls on natural concentrations are discussed and an approach to defining baseline concentrations using geochemical and statistical tools is proposed. The approach is illustrated using a flowline from the Chalk aquifer in Berkshire, UK where aerobic and anaerobic sections of the aquifer are separately considered. The baseline concentrations for some elements are close to atmospheric values whereas others evolve through time-dependent water–rock interaction. Certain solutes (K, NH4+), often considered contaminants, reach naturally high concentrations due to geochemical controls; transition metal concentrations are generally low, although their concentrations may be modified by redox controls. It is recommended that the baseline approach be incorporated into future management strategies, notably monitoring.
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Series Volume Series Issue Edition
ISSN 0048-9697 ISBN Medium
Area Expedition Conference
Notes Approved no
Call Number THL @ christoph.kuells @ edmunds_natural_2003 Serial 166
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Author Musy, S.; Meyzonnat, G.; Barbecot, F.; Hunkeler, D.; Sültenfuss, J.; Solomon, D.K.; Purtschert, R.
Title In-situ sampling for krypton-85 groundwater dating Type Journal Article
Year 2021 Publication Journal of Hydrology X Abbreviated Journal
Volume 11 Issue Pages 100075
Keywords Noble gases, Tracers, Groundwater, Dating, Sampling Methodology
Abstract (up) Krypton-85 and other radioactive noble gases are widely used for groundwater dating purposes. 85Kr analysis require large volumes of water to reach the analytical requirements. Conventionally, this water is pumped to the surface to be degassed with a gas extraction system. The large pumping rate may disturb the natural flow field and requires substantial field logistics. Hence, we propose a new in-situ degassing method, in which membrane contactors are used to degas the groundwater directly in the well and gas is collected at the surface. This way, field work is facilitated, groundwater system disturbance is minimized, and the gas sample is collected at a specific depth. We demonstrate the tightness of the system regarding atmospheric air contamination for a collection times of 24 h, which is sufficient for both low-level counting and laser-based counting methods for 85Kr. The minimal borehole diameter is 7.5 cm for the prototype presented in this research but can easily be reduced to smaller diameters. In a case study, we compare the results obtained with the new passive method with those from a conventional packer setup sampling. Additionally, 3H/3He samples were collected for both sampling regimes and the dating results were compared with those from 85Kr. A good agreement between tracer ages is demonstrated and the age stratigraphy is consistent with the expected age distribution for a porous unconfined aquifer. In addition, our study emphasizes the differences between the age information sampled with various methods. In conclusion, we demonstrate that the new in situ quasi-passive method provides a more representative age stratigraphy with depth in most cases.
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Series Editor Series Title Abbreviated Series Title
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ISSN 2589-9155 ISBN Medium
Area Expedition Conference
Notes Approved no
Call Number THL @ christoph.kuells @ Musy2021100075 Serial 215
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Author Liu, Z.; Tan, K.; Li, C.; Li, Y.; Zhang, C.; Song, J.; Liu, L.
Title Geochemical and S isotopic studies of pollutant evolution in groundwater after acid in situ leaching in a uranium mine area in Xinjiang Type Journal Article
Year 2023 Publication Nuclear Engineering and Technology Abbreviated Journal
Volume 55 Issue 4 Pages 1476-1484
Keywords Acid in situ leaching of uranium, Pollution evolution, Sulfate elimination, Sulfur isotopes analysis
Abstract (up) Laboratory experiments and point monitoring of reservoir sediments have proven that stable sulfate reduction (SSR) can lower the concentrations of toxic metals and sulfate in acidic groundwater for a long time. Here, we hypothesize that SSR occurred during in situ leaching after uranium mining, which can impact the fate of acid groundwater in an entire region. To test this, we applied a sulfur isotope fractionation method to analyze the mechanism for natural attenuation of contaminated groundwater produced by acid in situ leaching of uranium (Xinjiang, China). The results showed that δ34S increased over time after the cessation of uranium mining, and natural attenuation caused considerable, area-scale immobilization of sulfur corresponding to retention levels of 5.3%–48.3% while simultaneously decreasing the concentration of uranium. Isotopic evidence for SSR in the area, together with evidence for changes of pollutant concentrations, suggest that area-scale SSR is most likely also important at other acid mining sites for uranium, where retention of acid groundwater may be strengthened through natural attenuation. To recapitulate, the sulfur isotope fractionation method constitutes a relatively accurate tool for quantification of spatiotemporal trends for groundwater during migration and transformation resulting from acid in situ leaching of uranium in northern China.
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Language Summary Language Original Title
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 1738-5733 ISBN Medium
Area Expedition Conference
Notes Approved no
Call Number THL @ christoph.kuells @ liu_geochemical_2023 Serial 192
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Author Uhrie, J.L.; Drever, J.I.; Colberg, P.J.S.; Nesbitt, C.C.
Title In situ immobilization of heavy metals associated with uranium leach mines by bacterial sulfate reduction Type Journal Article
Year 1996 Publication Hydrometallurgy Abbreviated Journal
Volume 43 Issue 1 Pages 231-239
Keywords
Abstract (up) Laboratory experiments with mixed populations of sulfate-reducing bactreria were shown to mediate the removal of milligrams/liter concentrations of uranium, selenium, arsenic and vanadium from aqueous solution via reduction, precipitation and adsorption. Results of laboratory experiments with active sulfidogenic biomass suggest that injection of sulfate and a source of carbon could enhance anaerobic microbial activity in and around uranium leach mines leading to in situ immobilization contaminating metals.
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Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0304-386x ISBN Medium
Area Expedition Conference
Notes Approved no
Call Number THL @ christoph.kuells @ uhrie_situ_1996 Serial 197
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Author Leeuwen, Z.R. van; Klaar, M.J.; Smith, M.W.; Brown, L.E.
Title Quantifying the natural flood management potential of leaky dams in upland catchments, Part II: Leaky dam impacts on flood peak magnitude Type Journal Article
Year 2024 Publication Journal of Hydrology Abbreviated Journal
Volume 628 Issue Pages 130449
Keywords Nature based solutions, Large wood, Empirical, Hydrograph analysis, Ecosystem services, Transfer function noise model
Abstract (up) Leaky dams are an increasingly popular natural flood management measure, yet their impacts on flood peak magnitude have not yet been empirically quantified for a range of event types and magnitudes, even at the stream scale. In this study, the novel application of a transfer function noise modelling approach to empirical Before-After-Control-Impact stage data from an upland catchment allowed leaky dam effectiveness in reducing flood peak magnitude to be quantified. Flood peak stage and discharge magnitude changes were assessed from empirical data for 50 single and multi-peaked high flow events with return periods ranging from less than one year to six years. Overall, event peak magnitude was significantly reduced following the installation of eight leaky dams on the impact stream. Effectiveness was highly variable, but on average, flood peak magnitude was reduced by 10% for events with a return period up to one year. Some of the variability was explained by the size of the event and whether it was a single or multi-peaked event. This finding emphasises the need to manage expectations by considering both a range of event magnitudes and types when designing or assessing leaky dam natural flood management schemes.
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Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0022-1694 ISBN Medium
Area Expedition Conference
Notes Approved no
Call Number THL @ christoph.kuells @ Vanleeuwen2024130449 Serial 228
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Author Saini, K.; Singh, P.; Bajwa, B.S.
Title Comparative statistical analysis of carcinogenic and non-carcinogenic effects of uranium in groundwater samples from different regions of Punjab, India Type Journal Article
Year 2016 Publication Applied Radiation and Isotopes Abbreviated Journal
Volume 118 Issue Pages 196-202
Keywords Carcinogenic, Groundwater, LED fluorimeter, Uranium
Abstract (up) LED flourimeter has been used for microanalysis of uranium concentration in groundwater samples collected from six districts of South West (SW), West (W) and North East (NE) Punjab, India. Average value of uranium content in water samples of SW Punjab is observed to be higher than WHO, USEPA recommended safe limit of 30µgl−1 as well as AERB proposed limit of 60µgl−1. Whereas, for W and NE region of Punjab, average level of uranium concentration was within AERB recommended limit of 60µgl−1. Average value observed in SW Punjab is around 3–4 times the value observed in W Punjab, whereas its value is more than 17 times the average value observed in NE region of Punjab. Statistical analysis of carcinogenic as well as non carcinogenic risks due to uranium have been evaluated for each studied district.
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Language Summary Language Original Title
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0969-8043 ISBN Medium
Area Expedition Conference
Notes Approved no
Call Number THL @ christoph.kuells @ saini_comparative_2016 Serial 130
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Author Remmington, G.
Title Transforming tradition: The aflaj and changing role of traditional knowledge systems for collective water management Type Journal Article
Year 2018 Publication Journal of Arid Environments Abbreviated Journal
Volume 151 Issue Pages 134-140
Keywords Collective action, Subterranean tunnel-wells, , Traditional knowledge, Hydraulic heritage
Abstract (up) Living in a harsh, desert climate, Omani rural communities have developed locally-appropriate knowledge to deal with water scarcity. Similar to the qanat, the aflaj taps into the natural water table and uses a gravity system to channel water through underground channels to villages. Traditional techniques of water management, such as the aflaj, represents a way of adapting to and coping with difficult climates which have persisted for millennia. However, knowledge systems have often ‘decayed’ with the onset of modernity. These management systems, which developed concurrently with early Omani date palm cultivation, have defined customary and hereditary water rights which are in decline. This article uses Ostrom’s Common Pool Resource (CPR) framework, which prioritises the collective management of shared resources to maximise the benefit for all involved and avoid diminishing benefits that are created by the pursuit of individual goals. Using this framework, this article’s evaluation of the literature found that traditional aflaj management systems have a great capacity to evolve and, therefore, the aflaj represents both a dying system, and a potential for climate adaptation. Historically, aflaj have been managed by ancient water users associations, which provide social controls and govern usage norms. The findings of this review are that the aflaj system’s ability to respond to pressures of modernity from competing institutions, including markets, and embedded social capital mechanisms will influence its capacity to mitigate uncertain hydrology and climate. This article suggests ways in which the management of the aflaj can adapt to a multiple institutional framework to ‘transform’ collective water management.
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Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0140-1963 ISBN Medium
Area Expedition Conference
Notes Approved no
Call Number THL @ christoph.kuells @ Remmington2018134 Serial 258
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Author Zhao, Y.; Li, X.; Lei, L.; Chen, L.; Luo, Z.
Title Permeability evolution mechanism and the optimum permeability determination of uranium leaching from low-permeability sandstone treated with low-frequency vibration Type Journal Article
Year 2023 Publication Journal of Rock Mechanics and Geotechnical Engineering Abbreviated Journal
Volume 15 Issue 10 Pages 2597-2610
Keywords Chemical reactive rate, Low-frequency vibration, Low-permeability sandstone, Optimum permeability, Permeability evolution mechanism, Uranium migration
Abstract (up) Low-frequency vibrations can effectively improve natural sandstone permeability, and higher vibration frequency is associated with larger permeability. However, the optimum permeability and permeability evolution mechanism for uranium leaching and the relationship between permeability and the change of chemical reactive rate affecting uranium leaching have not been determined. To solve the above problems, in this study, identical homogeneous sandstone samples were selected to simulate low-permeability sandstone; a permeability evolution model considering the combined action of vibration stress, pore water pressure, water flow impact force, and chemical erosion was established; and vibration leaching experiments were performed to test the model accuracy. Both the permeability and chemical reactions were found to simultaneously restrict U6+ leaching, and the vibration treatment increased the permeability, causing the U6+ leaching reaction to no longer be diffusion-constrained but to be primarily controlled by the reaction rate. Changes of the model calculation parameters were further analyzed to determine the permeability evolution mechanism under the influence of vibration and chemical erosion, to prove the correctness of the mechanism according to the experimental results, and to develop a new method for determining the optimum permeability in uranium leaching. The uranium leaching was found to primarily follow a process consisting of (1) a permeability control stage, (2) achieving the optimum permeability, (3) a chemical reactive rate control stage, and (4) a channel flow stage. The resolution of these problems is of great significance for facilitating the application and promotion of low-frequency vibration in the CO2 + O2 leaching process.
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Language Summary Language Original Title
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 1674-7755 ISBN Medium
Area Expedition Conference
Notes Approved no
Call Number THL @ christoph.kuells @ zhao_permeability_2023 Serial 198
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Author Merembayev, T.; Yunussov, R.; Yedilkhan, A.
Title Machine Learning Algorithms for Stratigraphy Classification on Uranium Deposits Type Journal Article
Year 2019 Publication Procedia Computer Science Abbreviated Journal
Volume 150 Issue Pages 46-52
Keywords classification, geophysics logging data, machine learning, stratigraphy, uranium deposit
Abstract (up) Machine learning today becomes more and more effective instrument to solve many particular problems, where there are difficulties to apply well known and described math model. In other words – it is a great tool to describe non-linear phenomena. We tried to use this technique to improve existing process of stratigraphy, and reduce costs on site by applying computer leaded predictions on the basis of existing on-field collected data. Article describes usage of machine learning algorithms for stratigraphy boundaries classification based on geophysics logging data for uranium deposit in Kazakhstan. Correct marking of stratigraphy from geophysics logging data is complex non-linear task. To solve this task we applied several algorithms of machine learning: random forest, logistic regression, gradient boosting, k nearest neighbour and XGBoost.
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Language Summary Language Original Title
Series Editor Series Title Abbreviated Series Title
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ISSN 1877-0509 ISBN Medium
Area Expedition Conference
Notes Approved no
Call Number THL @ christoph.kuells @ merembayev_machine_2019 Serial 113
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Author Bresinsky, L.; Kordilla, J.; Hector, T.; Engelhardt, I.; Livshitz, Y.; Sauter, M.
Title Managing climate change impacts on the Western Mountain Aquifer: Implications for Mediterranean karst groundwater resources Type Journal Article
Year 2023 Publication Journal of Hydrology X Abbreviated Journal
Volume 20 Issue Pages 100153
Keywords Groundwater recharge, Storage, Hydrogeological droughts, Climate change effects, Groundwater management, Mitigation of climate change effects
Abstract (up) Many studies highlight the decrease in precipitation due to climate change in the Mediterranean region, making it a prominent hotspot. This study examines the combined impacts of climate change and three groundwater demand scenarios on the water resources of the Western Mountain Aquifer (WMA) in Israel and the West Bank. While commonly used methods for quantifying groundwater recharge and water resources rely on regression models, it is important to acknowledge their limitations when assessing climate change impacts. Regression models and other data-driven approaches are effective within observed variability but may lack predictive power when extrapolated to conditions beyond historical fluctuations. A comprehensive assessment requires distributed process-based numerical models incorporating a broader range of relevant physical flow processes and, ideally, ensemble model projections. In this study, we simulate the dynamics of dual-domain infiltration and precipitation partitioning using a HydroGeoSphere (HGS) model for variably saturated water flow coupled to a soil-epikarst water balance model in the WMA. The model input includes downscaled high-resolution climate projections until 2070 based on the IPCC RCP4.5 scenario. The results reveal a 5% to 10% decrease in long-term average groundwater recharge compared to a 30% reduction in average precipitation. The heterogeneity of karstic flow and increased intensity of individual rainfall events contribute to this mitigated impact on groundwater recharge, underscoring the importance of spatiotemporally resolved climate models with daily precipitation data. However, despite the moderate decrease in recharge, the study highlights the increasing length and severity of consecutive drought years with low recharge values. It emphasizes the need to adjust current management practices to climate change, as freshwater demand is expected to rise during these periods. Additionally, the study examines the emergence of hydrogeological droughts and their propagation from the surface to the groundwater. The results suggest that the 48-month standardized precipitation index (SPI-48) is a suitable indicator for hydrogeological drought emergence due to reduced groundwater recharge.
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Language Summary Language Original Title
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 2589-9155 ISBN Medium
Area Expedition Conference
Notes Approved no
Call Number THL @ christoph.kuells @ Bresinsky2023100153 Serial 223
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