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Bresinsky, L.; Kordilla, J.; Hector, T.; Engelhardt, I.; Livshitz, Y.; Sauter, M. |
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Title |
Managing climate change impacts on the Western Mountain Aquifer: Implications for Mediterranean karst groundwater resources |
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Journal Article |
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Year |
2023 |
Publication |
Journal of Hydrology X |
Abbreviated Journal |
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Volume |
20 |
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100153 |
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Keywords |
Groundwater recharge, Storage, Hydrogeological droughts, Climate change effects, Groundwater management, Mitigation of climate change effects |
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Abstract  |
Many studies highlight the decrease in precipitation due to climate change in the Mediterranean region, making it a prominent hotspot. This study examines the combined impacts of climate change and three groundwater demand scenarios on the water resources of the Western Mountain Aquifer (WMA) in Israel and the West Bank. While commonly used methods for quantifying groundwater recharge and water resources rely on regression models, it is important to acknowledge their limitations when assessing climate change impacts. Regression models and other data-driven approaches are effective within observed variability but may lack predictive power when extrapolated to conditions beyond historical fluctuations. A comprehensive assessment requires distributed process-based numerical models incorporating a broader range of relevant physical flow processes and, ideally, ensemble model projections. In this study, we simulate the dynamics of dual-domain infiltration and precipitation partitioning using a HydroGeoSphere (HGS) model for variably saturated water flow coupled to a soil-epikarst water balance model in the WMA. The model input includes downscaled high-resolution climate projections until 2070 based on the IPCC RCP4.5 scenario. The results reveal a 5% to 10% decrease in long-term average groundwater recharge compared to a 30% reduction in average precipitation. The heterogeneity of karstic flow and increased intensity of individual rainfall events contribute to this mitigated impact on groundwater recharge, underscoring the importance of spatiotemporally resolved climate models with daily precipitation data. However, despite the moderate decrease in recharge, the study highlights the increasing length and severity of consecutive drought years with low recharge values. It emphasizes the need to adjust current management practices to climate change, as freshwater demand is expected to rise during these periods. Additionally, the study examines the emergence of hydrogeological droughts and their propagation from the surface to the groundwater. The results suggest that the 48-month standardized precipitation index (SPI-48) is a suitable indicator for hydrogeological drought emergence due to reduced groundwater recharge. |
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2589-9155 |
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THL @ christoph.kuells @ Bresinsky2023100153 |
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223 |
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Heidari, B.; Prideaux, V.; Jack, K.; Jaber, F.H. |
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Title |
A planning framework to mitigate localized urban stormwater inlet flooding using distributed Green Stormwater Infrastructure at an urban scale: Case study of Dallas, Texas |
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Journal Article |
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Year |
2023 |
Publication |
Journal of Hydrology |
Abbreviated Journal |
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621 |
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129538 |
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Keywords |
Green stormwater infrastructure, Localized inlet pluvial flooding, Opportunity subwatersheds, Stormwater investment prioritization, Resilient urban watershed planning |
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Mitigation of localized pluvial flooding is one of the major resiliency goals in urban environments, and Green Stormwater Infrastructure (GSI) has the potential to deliver such an outcome. However, there is a lack of systematic approaches to prioritize investment in different candidate areas. This study provides a framework to identify vulnerable stormwater drainage inlets and their contributing areas, prioritize them, identify dominant factors in their selection, assess the potential of GSI in mitigating their overflows, and compare the impact and its cost to gray infrastructure upgrade alternatives. Using SWMM 5.1.013, decision trees, and a volumetric-based assessment of GSI overflow capture, we applied the framework to the City of Dallas, Texas, for three design storms with three GSI practices— bioretention cells, raingardens, and rainwater harvesting tanks. Results showed that there was a significant increase in the number of overflowing stormwater drainage inlets, referred to as hotspots, and their contributing subwatersheds, referred to as opportunity areas, with more intense storms especially in problematic watersheds. Also, prioritization results provided a series of maps to rank the opportunity areas based on overflow severity, recurrence of the overflows, and GSI availability. Moreover, classification results showed that inlet features, especially the inlet depth, were the dominant factors in the identification of the non-problematic inlets. Finally, the GSI impact assessment showed substantial overflow mitigation even at the “very high” severity levels when GSI is comprehensively deployed across opportunity areas. Despite gray infrastructure upgrades yielding higher reduction levels, their cost per cubic meter was higher than GSI. Therefore, a combination of GSI and gray results in maximum overflow reduction at a lower cost compared to common practices. |
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0022-1694 |
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THL @ christoph.kuells @ Heidari2023129538 |
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226 |
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Hall, S.M.; Gosen, B.S.V.; Zielinski, R.A. |
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Title |
Sandstone-hosted uranium deposits of the Colorado Plateau, USA |
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Journal Article |
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Year |
2023 |
Publication |
Ore Geology Reviews |
Abbreviated Journal |
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155 |
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105353 |
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Keywords |
Colorado, Plateau, Uranium, Vanadium |
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More than 4,000 sandstone-hosted uranium occurrences host over 1.2 billion pounds of mined and in situ U3O8 throughout the Colorado Plateau. Most of the resources are in two distinct mineral systems with deposits hosted in the Triassic Chinle and Jurassic Morrison Formations. In the Chinle mineral system, base metal sulfides typically accompany mineralization. The Morrison mineral system is characterized by V/U ratios up to 20. The uranium source was likely volcanic ash preserved as bentonitic mudstones in the Brushy Basin Member of the Morrison Formation, and lithic volcanic clasts, ash shards, and bentonitic clay in the lower part of the Chinle Formation. Vanadium originated from two possible sources: iron–titanium oxides that are extensively altered in bleached rock near deposits or from similar minerals in variably bleached red beds interbedded with and beneath the Morrison. In Chinle-hosted deposits, in addition to volcanic ash, a contributing source of both vanadium and uranium is proposed here for the first time to be underlying red beds in the Moenkopi and Cutler Formations that have undergone a cycle of reddening-bleaching-reoxidation. Transport in both systems was likely in groundwater through the more permeable sandstones and conglomerate units. The association of uranium minerals with carbonate and more rarely apatite, suggests that transport of uranium was as a carbonate or phosphate complex. The first comprehensive examination of paleoclimate, paleotopography, and subsurface structure of aquifers coupled with analysis of the geochronology of deposits suggests that that there were distinct pulses of uranium mineralization/redistribution during the period from about 259 Ma to 12 Ma when oxidized mineralizing fluids were intermittently rejuvenated in the Plateau in response to changes in tectonic regime and climate. Multiple lines of evidence indicate that deposits formed at ambient temperatures of about 25 °C to no greater than about 140 °C. In both systems, deposits formed where groundwater flow slowed and was subject to evaporative concentration. Stagnant conditions allowed for prolonged interaction of U- and V-enriched groundwater with ferrous iron-bearing reductants, such as illite and iron–titanium oxides, and more rarely organic material such as plant debris. Paragenetically late in the sequence, reducing fluids introduced additional organic matter to some deposits. Reducing fluids and introduced organic matter (now amorphous and altered by radiolysis) may originate from regional petroleum systems where peak oil and gas generation was from ∼ 82 to ∼ 5 Ma. Our novel analysis indicates that these reducing fluids bleached rock and protected affected deposits from remobilization during exposure and weathering that followed uplift of the Plateau (∼80 to 40 Ma). |
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0169-1368 |
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THL @ christoph.kuells @ hall_sandstone-hosted_2023 |
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111 |
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Gimeno, M.J.; Tullborg, E.-L.; Nilsson, A.-C.; Auqué, L.F.; Nilsson, L. |
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Title |
Hydrogeochemical characterisation of the groundwater in the crystalline basement of Forsmark, the selected area for the geological nuclear repositories in Sweden |
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Journal Article |
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Year |
2023 |
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Journal of Hydrology |
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624 |
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129818 |
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Keywords |
Crystalline bedrock, Deep geological repository, Glacial meltwater intrusion, Groundwater mixing, Hydrogeochemical model, Nuclear waste disposal |
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Numerous groundwater analyses from the crystalline bedrock in the Forsmark area have been performed between 2002 and 2019, together with thorough geological, geophysical, and hydrogeological studies, within the site investigations carried out by the Swedish Nuclear Fuel and Waste Management Company. The groundwater samples have been taken from boreholes down to ≈ 1000 m and the analysis include major- and trace-elements, stable and radiogenic isotopes, gases and microbes. The chemical and isotopic composition of these groundwaters evidences the presence of non-marine brackish to saline groundwaters with very long residence times (many hundreds of thousands of years) and a series of complex mixing events resulting from the recharge of different waters over time: glacial meltwaters, probably from different glaciations of which the latest culminated some 20,000 years ago, and marine waters from the Baltic starting some 7000 years ago. Later, meteoric water and present Baltic Sea water have recharged in different parts of the upper 100 m. These mixing events have also triggered chemical and microbial reactions that have conditioned some of the important groundwater parameters and, together with the structural complexity of the area, they have promoted a heterogeneous distribution of groundwater compositions in the bedrock. Due to these evident differences in chemistry, residence time and origin of the groundwater, several groundwater types were defined in order to facilitate the visualisation and communication. The differentiation (linked to the paleohydrological history of the area) was based on Cl concentration, Cl/Mg ratio (marine component), and δ18O value (glacial component). The work presented in this paper increases the understanding of the groundwater evolution in fractured and compartmentalised aquifers where mixing processes are the most important mechanisms. The model proposed to characterise the present groundwater system of the Forsmark area will also help to predict the future hydrogeochemical behaviour of the groundwater system after the construction of the repositories for the nuclear wastes. |
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0022-1694 |
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THL @ christoph.kuells @ gimeno_hydrogeochemical_2023 |
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137 |
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Lawrinenko, M.; Kurwadkar, S.; Wilkin, R.T. |
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Long-term performance evaluation of zero-valent iron amended permeable reactive barriers for groundwater remediation – A mechanistic approach |
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Journal Article |
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2023 |
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Geoscience Frontiers |
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14 |
Issue |
2 |
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101494 |
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Geochemistry, Iron, Permeable reactive barrier, Plating reactions, Reduction potential, Surface passivation |
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Permeable reactive barriers (PRBs) are used for groundwater remediation at contaminated sites worldwide. This technology has been efficient at appropriate sites for treating organic and inorganic contaminants using zero-valent iron (ZVI) as a reductant and as a reactive material. Continued development of the technology over the years suggests that a robust understanding of PRB performance and the mechanisms involved is still lacking. Conflicting information in the scientific literature downplays the critical role of ZVI corrosion in the remediation of various organic and inorganic pollutants. Additionally, there is a lack of information on how different mechanisms act in tandem to affect ZVI-groundwater systems through time. In this review paper, we describe the underlying mechanisms of PRB performance and remove isolated misconceptions. We discuss the primary mechanisms of ZVI transformation and aging in PRBs and the role of iron corrosion products. We review numerous sites to reinforce our understanding of the interactions between groundwater contaminants and ZVI and the authigenic minerals that form within PRBs. Our findings show that ZVI corrosion products and mineral precipitates play critical roles in the long-term performance of PRBs by influencing the reactivity of ZVI. Pore occlusion by mineral precipitates occurs at the influent side of PRBs and is enhanced by dissolved oxygen and groundwater rich in dissolved solids and high alkalinity, which negatively impacts hydraulic conductivity, allowing contaminants to potentially bypass the treatment zone. Further development of site characterization tools and models is needed to support effective PRB designs for groundwater remediation. |
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1674-9871 |
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THL @ christoph.kuells @ lawrinenko_long-term_2023 |
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143 |
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