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Author (down) Lim, S.; Chase, B.M.; Chevalier, M.; Reimer, P.J. url  openurl
  Title 50,000years of vegetation and climate change in the southern Namib Desert, Pella, South Africa Type Journal Article
  Year 2016 Publication Palaeogeography, Palaeoclimatology, Palaeoecology Abbreviated Journal  
  Volume 451 Issue Pages 197-209  
  Keywords Climate reconstruction, Late Quaternary, Namib Desert, Pollen, Rock hyrax middens, South Africa  
  Abstract This paper presents the first continuous pollen record from the southern Namib Desert spanning the last 50,000years. Obtained from rock hyrax middens found near the town of Pella, South Africa, these data are used to reconstruct vegetation change and quantitative estimates of temperature and aridity. Results indicate that the last glacial period was characterised by increased water availability at the site relative to the Holocene. Changes in temperature and potential evapotranspiration appear to have played a significant role in determining the hydrologic balance. The record can be considered in two sections: 1) the last glacial period, when low temperatures favoured the development of more mesic Nama-Karoo vegetation at the site, with periods of increased humidity concurrent with increased coastal upwelling, both responding to lower global/regional temperatures; and 2) the Holocene, during which time high temperatures and potential evapotranspiration resulted in increased aridity and an expansion of the Desert Biome. During this latter period, increases in upwelling intensity created drier conditions at the site. Considered in the context of discussions of forcing mechanisms of regional climate change and environmental dynamics, the results from Pella stand in clear contrast with many inferences of terrestrial environmental change derived from regional marine records. Observations of a strong precessional signal and interpretations of increased humidity during phases of high local summer insolation in the marine records are not consistent with the data from Pella. Similarly, while high percentages of Restionaceae pollen has been observed in marine sediments during the last glacial period, they do not exceed 1% of the assemblage from Pella, indicating that no significant expansion of the Fynbos Biome has occurred during the last 50,000years. These findings pose interesting questions regarding the nature of environmental change in southwestern Africa, and the significance of the diverse records that have been obtained from the region.  
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  ISSN 0031-0182 ISBN Medium  
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  Notes Approved no  
  Call Number THL @ christoph.kuells @ lim_50000years_2016 Serial 107  
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Author (down) Lightfoot, D.R. url  openurl
  Title Moroccan khettara: Traditional irrigation and progressive desiccation Type Journal Article
  Year 1996 Publication Geoforum Abbreviated Journal  
  Volume 27 Issue 2 Pages 261-273  
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  Abstract A 300 km network of khettara (qanat) subsurface irrigation channels was excavated in the Tafilalt basin beginning in the late 14th century. More than 75 of these chains provided perennial water following the breakup of the ancient city of Sijilmassa. Khettara continued to function for much of the northern oasis until the early 1970s, when new technologies and government policies forced changes. Data on origins, maintenance, and current use were collected from archival sources, aerial photographs, Landsat imagery, and from interviews. Insufficient water resources and unsustainable practices have dramatically lowered the water table, drying up khettara. This has resulted in a loss of local control over water resources, abandonment of a sustainable irrigation system, and progressive desiccation.  
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  ISSN 0016-7185 ISBN Medium  
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  Notes Approved no  
  Call Number THL @ christoph.kuells @ Lightfoot1996261 Serial 257  
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Author (down) Liesch, T.; Hinrichsen, S.; Goldscheider, N. url  openurl
  Title Uranium in groundwater — Fertilizers versus geogenic sources Type Journal Article
  Year 2015 Publication Science of The Total Environment Abbreviated Journal  
  Volume 536 Issue Pages 981-995  
  Keywords Drinking water, Fertilizer, Geogenic background, Groundwater, Uranium  
  Abstract Due to its radiological and toxicological properties even at low concentration levels, uranium is increasingly recognized as relevant contaminant in drinking water from aquifers. Uranium originates from different sources, including natural or geogenic, mining and industrial activities, and fertilizers in agriculture. The goal of this study was to obtain insights into the origin of uranium in groundwater while differentiating between geogenic sources and fertilizers. A literature review concerning the sources and geochemical processes affecting the occurrence and distribution of uranium in the lithosphere, pedosphere and hydrosphere provided the background for the evaluation of data on uranium in groundwater at regional scale. The state of Baden-Württemberg, Germany, was selected for this study, because of its hydrogeological and land-use diversity, and for reasons of data availability. Uranium and other parameters from N=1935 groundwater monitoring sites were analyzed statistically and geospatially. Results show that (i) 1.6% of all water samples exceed the German legal limit for drinking water (10μg/L); (ii) The range and spatial distribution of uranium and occasional peak values seem to be related to geogenic sources; (iii) There is a clear relation between agricultural land-use and low-level uranium concentrations, indicating that fertilizers generate a measurable but low background of uranium in groundwater.  
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  ISSN 0048-9697 ISBN Medium  
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  Notes Approved no  
  Call Number THL @ christoph.kuells @ liesch_uranium_2015 Serial 145  
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Author (down) Li, X.; Shen, K.; Li, Q.; Deng, Y.; Zhu, P.; Wang, D. url  openurl
  Title Roll-over behavior in current-voltage curve introduced by an energy barrier at the front contact in thin film CdTe solar cell Type Journal Article
  Year 2018 Publication Solar Energy Abbreviated Journal  
  Volume 165 Issue Pages 27-34  
  Keywords AlO HRT layer, Band alignment, CdTe solar cell, Roll-over behavior  
  Abstract Roll-over phenomenon in the current–voltage (J–V) curve is often observed in a CdTe thin film solar cell. The roll-over phenomenon, which is occurred near the open-circuit voltage in a light J–V curve, is due to Schottky energy barrier formed at the CdTe/metal interface in a CdTe solar cell back contact. In this study we report a J–V roll-over phenomenon which is induced by an energy barrier at the front contact of a CdTe solar cell. Two kinds of oxides, namely, Al2O3 and SnO2, were deposited as high-resistance transparent (HRT) layer between the window layer CdS and the fluorine doped tin oxide (FTO) front electrode in CdTe solar cells. These two oxides present much different electronic band alignment with FTO and CdS. SnO2 formed almost no energy barrier with CdS, this allowed smooth transport for photo-generated electrons from CdTe to CdS and FTO. However, Al2O3 formed a high energy barrier with CdS. The rather high energy barrier with a value of 3.43 eV at the CdS/Al2O3 interface induced a J–V roll-over phenomenon in a CdTe thin film solar cell, which dramatically led to a quick decrease for the cell device efficiency. The electron transport at the FTO/Al2O3/CdS interface is governed by tunneling effect. The results presented in this study demonstrate that the band structure at the front electrode plays an important role for the performance of a CdTe thin film solar cell.  
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  ISSN 0038-092x ISBN Medium  
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  Notes Approved no  
  Call Number THL @ christoph.kuells @ li_roll-over_2018 Serial 187  
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Author (down) Li, J.; Pang, Z.; Liu, Y.; Hu, S.; Jiang, W.; Tian, L.; Yang, G.; Jiang, Y.; Jiao, X.; Tian, J. url  openurl
  Title Changes in groundwater dynamics and geochemical evolution induced by drainage reorganization: Evidence from 81Kr and 36Cl dating of geothermal water in the Weihe Basin of China Type Journal Article
  Year 2023 Publication Earth and Planetary Science Letters Abbreviated Journal  
  Volume 623 Issue Pages 118425  
  Keywords Kr dating, Cl dating, Geothermal water, Groundwater dynamics, Weihe basin  
  Abstract 81Kr and 36Cl can both be used to date groundwater beyond the dating range of 14C. 81Kr usually provides reliable groundwater ages because it has uniform initial distribution and negligible subsurface generation, while 36Cl is commonly influenced by subsurface sources or “dead” chloride dissolution. Therefore, the combined use of 81Kr and 36Cl could provide clues on the evolution history of groundwater. In the present study, we performed 36Cl and 81Kr dating of geothermal water in Weihe Basin of China and interpreted the possible cause of disagreement. Two distinct water masses were identified with distinctive isotopic signals: groundwater with significant δ18O shifts (up to −2.0‰), dissolved dead Cl and ages < 1.0 Ma (Cluster A), and older water with little δ18O shifts, negligible dissolved Cl and ages >1.0 Ma (Cluster B). The results confirm the eastward flow path of Cluster B to the Ancient Sanmen Lake with an increasing trend of Cl concentration and age. Modern recharge from the mountains flows to the basin center with intense interaction between water and carbonate under respective reservoir temperatures (100 ∼ 130 °C). These waters flow through the saline stratum emerging from the spillover of the Ancient Sanmen Lake, resulting in higher dead Cl dissolution. A significant linear relationship is observed with the older end-member of ∼1.3Ma under the topographically-driven faster circulation effect. 81Kr ages seem to support the hypothesis that the birth of the modern Yellow River was at about 1.0–1.3 Ma. We inferred the drainage reorganization from the Ancient Sanmen Lake to the modern Yellow River since the Mid-Pleistocene Transition induced the change in groundwater dynamics as well as its chemical evolution. The excavation of the Ancient Sanmen Lake and the accentuated incision of the Weihe River induced groundwater gradient, and therefore the recharge from precipitation from both slopes of the Qinling Mountains in the south and the Beishan Mountains in the north. Our results highlight the effects of dead Cl on 36Cl dating and demonstrate the significant impact of catchment reorganization on groundwater dynamics and its chemistry.  
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  ISSN 0012-821x ISBN Medium  
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  Notes Approved no  
  Call Number THL @ christoph.kuells @ Li2023118425 Serial 212  
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