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Musy, S.; Meyzonnat, G.; Barbecot, F.; Hunkeler, D.; Sültenfuss, J.; Solomon, D.K.; Purtschert, R. |
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In-situ sampling for krypton-85 groundwater dating |
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2021 |
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Journal of Hydrology X |
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11 |
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100075 |
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Noble gases, Tracers, Groundwater, Dating, Sampling Methodology |
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Krypton-85 and other radioactive noble gases are widely used for groundwater dating purposes. 85Kr analysis require large volumes of water to reach the analytical requirements. Conventionally, this water is pumped to the surface to be degassed with a gas extraction system. The large pumping rate may disturb the natural flow field and requires substantial field logistics. Hence, we propose a new in-situ degassing method, in which membrane contactors are used to degas the groundwater directly in the well and gas is collected at the surface. This way, field work is facilitated, groundwater system disturbance is minimized, and the gas sample is collected at a specific depth. We demonstrate the tightness of the system regarding atmospheric air contamination for a collection times of 24 h, which is sufficient for both low-level counting and laser-based counting methods for 85Kr. The minimal borehole diameter is 7.5 cm for the prototype presented in this research but can easily be reduced to smaller diameters. In a case study, we compare the results obtained with the new passive method with those from a conventional packer setup sampling. Additionally, 3H/3He samples were collected for both sampling regimes and the dating results were compared with those from 85Kr. A good agreement between tracer ages is demonstrated and the age stratigraphy is consistent with the expected age distribution for a porous unconfined aquifer. In addition, our study emphasizes the differences between the age information sampled with various methods. In conclusion, we demonstrate that the new in situ quasi-passive method provides a more representative age stratigraphy with depth in most cases. |
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2589-9155 |
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THL @ christoph.kuells @ Musy2021100075 |
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215 |
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Zeng, S.; Shen, Y.; Sun, B.; Zhang, N.; Zhang, S.; Feng, S. |
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Title |
Pore structure evolution characteristics of sandstone uranium ore during acid leaching |
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Journal Article |
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2021 |
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Nuclear Engineering and Technology |
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53 |
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12 |
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4033-4041 |
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Acid method, In situ leaching, Nuclear magnetic resonance, Pore characteristic, Sandstone uranium ore |
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To better understand the permeability of uranium sandstone, improve the leaching rate of uranium, and explore the change law of pore structure characteristics and blocking mechanism during leaching, we systematically analyzed the microstructure of acid-leaching uranium sandstone. We investigated the variable rules of pore structure characteristics based on nuclear magnetic resonance (NMR). The results showed the following: (1) The uranium concentration change followed the exponential law during uranium deposits acid leaching. After 24 h, the uranium leaching rate reached 50%. The uranium leaching slowed gradually over the next 4 days. (2) Combined with the regularity of porosity variation, Stages I and II included chemical plugging controlled by surface reaction. Stage I was the major completion phase of uranium displacement with saturation precipitation of calcium sulfate. Stage II mainly precipitated iron (III) oxide-hydroxide and aluminum hydroxide. Stage III involved physical clogging controlled by diffusion. (3) In the three stages of leaching, the permeability of the leaching solution changed with the pore structure, which first decreased, then increased, and then decreased. |
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1738-5733 |
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THL @ christoph.kuells @ zeng_pore_2021 |
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199 |
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de Jong, I.J.H.; Arif, S.S.; Gollapalli, P.K.R.; Neelam, P.; Nofal, E.R.; Reddy, K.Y.; Röttcher, K.; Zohrabi, N. |
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Improving agricultural water productivity with a focus on rural transformation* |
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2021 |
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Irrigation and Drainage |
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70 |
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3 |
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458-469 |
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irrigation efficiency, water productivity, rural transformation, efficacité de l’irrigation, productivité de l’eau, transformation rurale |
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ABSTRACT As a result of population growth, economic development and climate change, feeding the world and providing water security will require important changes in the technologies, institutions, policies and incentives that drive present-day water management, as captured in Goal 6.4 of the Millennium Development Goals. Irrigation is the largest and most inefficient water user, and there is an expectation that even small improvements in agricultural water productivity will improve water security. This paper argues that improvements in irrigation water productivity involves a complex and comprehensive rural transformation that goes beyond mere promotion of water saving technologies. Many of the measures to improve water productivity require significant changes in the production systems of farmers and in the support provided to them. Looking forward, water use and competition over water are expected to further increase. By 2025, about 1.8 billion people will be living in regions or countries with absolute water scarcity. Demand for water will rise exponentially, while supply becomes more erratic and uncertain, prompting the need for significant shifts of inter-sectoral water allocation to support continued economic growth. Advances in the use of remote sensing technologies will make it increasingly possible to cost-effectively and accurately estimate crop evapotranspiration from farmers’ fields. |
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THL @ christoph.kuells @ https://doi.org/10.1002/ird.2451 |
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89 |
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Puri, S. |
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Chapter 9 – Transboundary aquifers: a shared subsurface asset, in urgent need of sound governance |
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2021 |
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Global Groundwater |
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113-128 |
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ILC Draft Articles, impact on GDP, sound governance, Transboundary aquifers |
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Apart from some notable exceptions, the sound governance of transboundary aquifers (coupled or uncoupled to rivers) is seriously lacking in most regions of the world, despite a highly successful 20-year ISARM initiative. The distinction between regions of water abundance (as in the Haute Savoie–Geneva aquifers) and those of water scarcity (\textless1000 m3/an/capita), as in the Rum-Saq aquifer, ought to be a driver for the urgency in adopting sound governance. In the latter regions, however, such an urgent response faces too many hurdles (institutional, financial, and weak capacity). Climate change, one of the global megatrends (among demography, economic shift, resources stress, urbanization, and novel viruses such as COVID-19), will exacerbate the problem in the coming decade and beyond. This chapter provides an critical perspective on the status of this subsurface asset in 570 or so, domestic and transboundary aquifers of the world (self-identified by country experts), while taking full account of their interconnections, or not, with surface waters. This critical perspective will be grounded in two important factors, first the hiatus in adoption by countries of the evolving international water law and guidance on transboundary aquifers (the Draft Articles, which provide legal pathways for collaboration or eventually dispute resolution), and second the framework of the sustainable development goals (SDG) 6 (clean water and sanitation), which countries have committed themselves to with reference to transboundary waters. The critical perspective finds that despite the lack of momentum in adopting formal global norms, sporadic cooperation and collaboration is continuing and is well received, when delivered methodically through the support of international agencies. The findings of the critical perspective are that even if water-related SDGs will have been achieved across the world, it would contribute precious little to meaningful enhancement of governance of transboundary aquifers, unless they have been explicitly addressed in terms that are tangible to decision makers, such as the impact of disregarding them on the current or future national GDP. The onset of a “new socioeconomic normal” in the aftermath of COVID-19 could further defer meaningful progress, taking the example of Latin America, where a 5% decline has been forecast for 2020. With such declines in the finances of governments, attention to shared aquifer resources may well decline even further. Urgent wise reaction to this possibility must be a priority for the professional science-policy community. |
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Elsevier |
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Mukherjee, A.; Scanlon, B.R.; Aureli, A.; Langan, S.; Guo, H.; McKenzie, A.A. |
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978-0-12-818172-0 |
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THL @ christoph.kuells @ mukherjee_chapter_2021 |
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106 |
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