Records |
Author |
Musy, S.; Meyzonnat, G.; Barbecot, F.; Hunkeler, D.; Sültenfuss, J.; Solomon, D.K.; Purtschert, R. |
Title |
In-situ sampling for krypton-85 groundwater dating |
Type |
Journal Article |
Year |
2021 |
Publication |
Journal of Hydrology X |
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Volume |
11 |
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100075 |
Keywords |
Noble gases, Tracers, Groundwater, Dating, Sampling Methodology |
Abstract |
Krypton-85 and other radioactive noble gases are widely used for groundwater dating purposes. 85Kr analysis require large volumes of water to reach the analytical requirements. Conventionally, this water is pumped to the surface to be degassed with a gas extraction system. The large pumping rate may disturb the natural flow field and requires substantial field logistics. Hence, we propose a new in-situ degassing method, in which membrane contactors are used to degas the groundwater directly in the well and gas is collected at the surface. This way, field work is facilitated, groundwater system disturbance is minimized, and the gas sample is collected at a specific depth. We demonstrate the tightness of the system regarding atmospheric air contamination for a collection times of 24 h, which is sufficient for both low-level counting and laser-based counting methods for 85Kr. The minimal borehole diameter is 7.5 cm for the prototype presented in this research but can easily be reduced to smaller diameters. In a case study, we compare the results obtained with the new passive method with those from a conventional packer setup sampling. Additionally, 3H/3He samples were collected for both sampling regimes and the dating results were compared with those from 85Kr. A good agreement between tracer ages is demonstrated and the age stratigraphy is consistent with the expected age distribution for a porous unconfined aquifer. In addition, our study emphasizes the differences between the age information sampled with various methods. In conclusion, we demonstrate that the new in situ quasi-passive method provides a more representative age stratigraphy with depth in most cases. |
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2589-9155 |
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THL @ christoph.kuells @ Musy2021100075 |
Serial |
215 |
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Author |
Müller, M.; Alaoui, A.; Külls, C.; Leistert, H.; Meusburger, K.; Stumpp, C.; Weiler, M.; Alewell, C. |
Title |
Tracking water pathways in steep hillslopes by δ18O depth profiles of soil water |
Type |
Journal Article |
Year |
2014 |
Publication |
Journal of hydrology |
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Volume |
519 |
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340-352 |
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Elsevier |
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THL @ christoph.kuells @ Mueller2014tracking |
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20 |
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Author |
Frumkin, A.; Gvirtzman, H. |
Title |
Cross-formational rising groundwater at an artesian karstic basin: the Ayalon Saline Anomaly, Israel |
Type |
Journal Article |
Year |
2006 |
Publication |
Journal of Hydrology |
Abbreviated Journal |
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Volume |
318 |
Issue |
1 |
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316-333 |
Keywords |
Confined karst, Groundwater, HS, Maze caves, Rising water, Yarkon–Taninim aquifer |
Abstract |
It is proposed that a geothermal artesian karstic system at the central part of the Yarkon–Taninim aquifer creates the ‘Ayalon Saline Anomaly’ (ASA), whose mechanism has been under debate for several decades. A 4-year-long detailed groundwater monitoring was carried out at 68 new shallow boreholes in the Ayalon region, accompanied by a comprehensive survey of karstic voids. Results indicate the rising of warm-brackish groundwater through highly permeable swarms of karstic shafts, serving as an outflow of the artesian geothermal system. The ASA area contains ‘hot spots’, where groundwater contrasts with ‘normal’ water hundreds of meters away. The ASA temperature reaches 30°C (∼5°C warmer than its surroundings), chloride concentration reaches 528mg/l (50–100mg/l in the surrounding), H2S concentration reaches 5.6mg/l (zero all around) and pH value is 7.0 (compared with 7.8 around). Subsequently, the hydrothermal water flows laterally of at the watertable horizon through horizontal conduits, mixing with ‘normal’ fresh water which had circulated at shallow depth. Following rainy seasons, maximal watertable rise is observed in the ASA compared to its surroundings. Regional hydrogeology considerations suggest that the replenishment area for the ASA water is at the Samaria Mountains, east of the ASA. The water circulates to a great depth while flowing westward, and a cross-formational upward flow is then favored close the upper sub-aquifer’s confinement border. |
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0022-1694 |
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THL @ christoph.kuells @ frumkin_cross-formational_2006 |
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117 |
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Author |
Klaus, J.; Külls, C.; Dahan, O. |
Title |
Evaluating the recharge mechanism of the Lower Kuiseb Dune area using mixing cell modeling and residence time data |
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Journal Article |
Year |
2008 |
Publication |
Journal of Hydrology |
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358 |
Issue |
3-4 |
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304-316 |
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Elsevier |
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THL @ christoph.kuells @ Klaus2008evaluating |
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28 |
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Author |
Morin, E.; Grodek, T.; Dahan, O.; Benito, G.; Külls, C.; Jacoby, Y.; Van Langenhove, G.; Seely, M.; Enzel, Y. |
Title |
Flood routing and alluvial aquifer recharge along the ephemeral arid Kuiseb River, Namibia |
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Journal Article |
Year |
2009 |
Publication |
Journal of Hydrology |
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368 |
Issue |
1-4 |
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262-275 |
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Elsevier |
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THL @ christoph.kuells @ Morin2009flood |
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26 |
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Author |
Heaton, T.H.E. |
Title |
Sources of the nitrate in phreatic groundwater in the western Kalahari |
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Journal Article |
Year |
1984 |
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Journal of Hydrology |
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67 |
Issue |
1 |
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249-259 |
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Elevated levels of nitrate occur in phreatic groundwater in the western Kalahari, Namibia. Nitrate in water containing 0.4–3.1 meq NO−3l−1, of widespread occurrence, has δ15N values in the range +4.9 to +8.0‰, suggesting natural derivation from the soil. The sporadic occurrence of very high levels of nitrate (> 4 meq NO−3l−1), which has δ15N between +9.3 to +18.7‰, reflects pollution derived from animal waste. The importance of considering the possible isotopic effects of denitrification, and the significance of leaching in the nitrogen budget of the Kalahari soil, are also discussed. |
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0022-1694 |
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THL @ christoph.kuells @ Heaton1984249 |
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278 |
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Author |
Heaton, T.H.E.; Talma, A.S.; Vogel, J.C. |
Title |
Origin and history of nitrate in confined groundwater in the western Kalahari |
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Journal Article |
Year |
1983 |
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Journal of Hydrology |
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62 |
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1 |
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243-262 |
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Data are presented for nitrate, dinitrogen and argon concentrations and 15N14N ratios in groundwater, with radiocarbon ages up to 40,000 yr. for three confined sandstone aquifers in the western Kalahari of South West Africa/Namibia. The nitrate is probably generated within the soil of the recharge areas, and its production rate during the period 3000-40,000 B.P. has remained between 0.5 and 1.6 meq NO−3l−1 of recharge water, with ° 15N between + 4 and + 8‰. Variations in the amount of nitrate and of “excess air” in groundwater recharge are found, and can only reflect changes in the environmental conditions during recharge. They must therefore be caused by the climatic changes that have taken place during the past 25,000 yr. |
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0022-1694 |
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THL @ christoph.kuells @ heaton_origin_1983 |
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95 |
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Author |
Heaton, T.H.E.; Talma, A.S.; Vogel, J.C. |
Title |
Origin and history of nitrate in confined groundwater in the western Kalahari |
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Journal Article |
Year |
1983 |
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Journal of Hydrology |
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62 |
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1 |
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243-262 |
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Abstract |
Data are presented for nitrate, dinitrogen and argon concentrations and 15N14N ratios in groundwater, with radiocarbon ages up to 40,000 yr. for three confined sandstone aquifers in the western Kalahari of South West Africa/Namibia. The nitrate is probably generated within the soil of the recharge areas, and its production rate during the period 3000-40,000 B.P. has remained between 0.5 and 1.6 meq NO−3l−1 of recharge water, with ° 15N between + 4 and + 8‰. Variations in the amount of nitrate and of “excess air” in groundwater recharge are found, and can only reflect changes in the environmental conditions during recharge. They must therefore be caused by the climatic changes that have taken place during the past 25,000 yr. |
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0022-1694 |
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THL @ christoph.kuells @ Heaton1983243 |
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282 |
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Author |
Vogel, J.C.; Talma, A.S.; Heaton, T.H.E. |
Title |
Gaseous nitrogen as evidence for denitrification in groundwater |
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Journal Article |
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1981 |
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Journal of Hydrology |
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50 |
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191-200 |
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By investigating the nitrate, oxygen, nitrogen and argon concentrations and 15N14N ratios in artesian groundwater with radiocarbon ages ranging up to 27,000 yr. a process of very slow denitrification in a confined aquifer is demonstrated. The calculated nitrogenisotope fractionation factor associated with this reaction is comparable to that reported for bacterial cultures in vitro and in vivo. |
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0022-1694 |
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THL @ christoph.kuells @ Vogel1981191 |
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280 |
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Pavelic, P.; Srisuk, K.; Saraphirom, P.; Nadee, S.; Pholkern, K.; Chusanathas, S.; Munyou, S.; Tangsutthinon, T.; Intarasut, T.; Smakhtin, V. |
Title |
Balancing-out floods and droughts: Opportunities to utilize floodwater harvesting and groundwater storage for agricultural development in Thailand |
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Journal Article |
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2012 |
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Journal of Hydrology |
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470-471 |
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55-64 |
Keywords |
Water scarcity, Flooding, Drought, Managed aquifer recharge, Floodwater harvesting, Chao Phraya River Basin |
Abstract |
Summary Thailand’s naturally high seasonal endowment of water resources brings with it the regularly experienced problems associated with floods during the wet season and droughts during the dry season. Downstream-focused engineering solutions that address flooding are vital, but do not necessarily capture the potential for basin-scale improvements to water security, food production and livelihood enhancement. Managed aquifer recharge, typically applied to annual harvesting of wet season flows in dry climates, can also be applied to capture, store and recover episodic extreme flood events in humid environments. In the Chao Phraya River Basin it is estimated that surplus flows recorded downstream above a critical threshold could be harvested and recharged within the shallow alluvial aquifers in a distributed manner upstream of flood prone areas without significantly impacting existing large-medium storages or the Gulf and deltaic ecosystems. Capturing peak flows approximately 1year in four by dedicating around 200km2 of land to groundwater recharge would reduce the magnitude of flooding and socio-economic impacts and generate around USD 250M/year in export earnings for smallholder rainfed farmers through dry season cash cropping without unduly compromising the demands of existing water users. It is proposed that farmers in upstream riparian zones be co-opted as flood harvesters and thus contribute to improved floodwater management through simple water management technologies that enable agricultural lands to be put to higher productive use. Local-scale site suitability and technical performance assessments along with revised governance structures would be required. It is expected that such an approach would also be applicable to other coastal-discharging basins in Thailand and potentially throughout the Asia region. |
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0022-1694 |
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THL @ christoph.kuells @ Pavelic201255 |
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246 |
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