Abstract: Permeable reactive barriers (PRBs) are used for groundwater remediation at contaminated sites worldwide. This technology has been efficient at appropriate sites for treating organic and inorganic contaminants using zero-valent iron (ZVI) as a reductant and as a reactive material. Continued development of the technology over the years suggests that a robust understanding of PRB performance and the mechanisms involved is still lacking. Conflicting information in the scientific literature downplays the critical role of ZVI corrosion in the remediation of various organic and inorganic pollutants. Additionally, there is a lack of information on how different mechanisms act in tandem to affect ZVI-groundwater systems through time. In this review paper, we describe the underlying mechanisms of PRB performance and remove isolated misconceptions. We discuss the primary mechanisms of ZVI transformation and aging in PRBs and the role of iron corrosion products. We review numerous sites to reinforce our understanding of the interactions between groundwater contaminants and ZVI and the authigenic minerals that form within PRBs. Our findings show that ZVI corrosion products and mineral precipitates play critical roles in the long-term performance of PRBs by influencing the reactivity of ZVI. Pore occlusion by mineral precipitates occurs at the influent side of PRBs and is enhanced by dissolved oxygen and groundwater rich in dissolved solids and high alkalinity, which negatively impacts hydraulic conductivity, allowing contaminants to potentially bypass the treatment zone. Further development of site characterization tools and models is needed to support effective PRB designs for groundwater remediation.

Abstract: As an ancient underground hydraulic engineering facility, the Qanat system has been used to draw groundwater from arid regions. A qanat is a horizontal tunnel with a slight incline that draws groundwater from a higher location and delivers it to lower agricultural land. During long-term water delivery, the qanat tunnel has experienced different degrees of aging and collapse, which may result in the significant ground settlement and even disasters. This paper developed a two-dimensional laboratory system to investigate the influence of progressive failure on the stability of deeply buried qanat tunnels. The developed system is fully instrumented with a particle image velocimetry (PIV) system and earth pressure and displacement monitoring. A special cylindrical membrane tube is designed and connected to an advanced pressure–volume controller to simulate the step-wise failure process of the tunnel. Three model tests were conducted on a dry sand considering the buried qanat tunnels at three different depths. Experimental results clearly show the progressive evolution of soil arching effect in the dry sand associated with the progressive failure of the tunnels. The failure of the Qanat ground starts from the vault and develops upwards, which is closely related to the evolution of stress contour at three consecutive stages. Ground surface settlement and volume loss corresponding to three burial depths were compared. A deeply buried qanat tunnel has a small effect on surface settlement. Earth pressure evolution on the 2D plane shows the load redistribution when the qanat collapses. The maximum arch and the initial point of the limit state correspond to a volume loss of 12.5 % and 50 %, respectively. For the collapse of the deep buried qanat tunnel, ground earth pressure evolution can be divided into a stress-increasing region, stress-decreasing region, and no redistribution region. Furthermore, a multi trap-door model considering soil expansion is proposed to describe the progressive failure behavior and its effects.

Abstract: Floods are one of the most common natural disasters, resulting in the extensive destruction of infrastructure, property, and human life. The destructive potential of a flood depends on numerous factors, including the size of the flood, the rate of flooding, the time it takes for the water to move through a given area, the river’s planform and cross-section geometry, and other similar factors. The present study is a unique analysis of flood mapping that was accomplished with the help of the Analytical Hierarchy Process (AHP), Frequency Ratio (FR), and hydrogeomorphic response to floods by integrating geospatial analysis and unit stream power modeling. The Indus catchment region of Pakistan is where the subject topic is put into practice. According to the hydrologic analysis of the yearly peak discharge, the hydro-station in Gilgit-Baltistan can move boulders measuring up to 0.5 m in height during significant flooding. On the other hand, there will be no change to the geometry of the cross-section throughout 1980–2020 in Gilgit-Baltistan. The flood susceptibility map is constructed using data from twelve influencing parameters, including elevation, proximity to the drainage network, slope, drainage density, geomorphology, rainfall, the curvature of the topography, flow accumulation, geology, land use, Topographic Wetness Index (TWI), and Stream Power Index (SPI). The area under the curve (AUC) approach, which demonstrates a substantial degree of accuracy (85% and 83%), is utilized to evaluate the effectiveness of the AHP and FR. The current study fills the gaps between the geospatial approach and the hydrogeomorphic assessment of flood to determine flood susceptibility.