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Author Romeo, N.; Mabry, J.; Hillegonds, D.; Kainz, G.; Jaklitsch, M.; Matsumoto, T.
Title Developments of a field gas extraction device and krypton purification system for groundwater radio-krypton dating at the IAEA Type Journal Article
Year 2022 Publication Applied Radiation and Isotopes Abbreviated Journal
Volume 189 Issue Pages 110450
Keywords
Abstract The long-lived radio-krypton isotope 81Kr (t1/2 = 2.29 × 105 yr) is an ideal tracer for old groundwater age dating in the range of 105–106 years which goes beyond the reach of radio-carbon (14C) age dating. Analytical breakthrough made over the last two decades in Atom Trap Trace Analysis (ATTA) has enabled the use of this isotope with extremely low abundance (81Kr/Kr = 6 × 10−13) to be used as a practical dating tool for very old groundwater. The International Atomic Energy Agency aims to provide this new isotope tool for better groundwater resource management of Member States and developed a field sampling device to collect dissolved gas samples from groundwater and a system to separate and purify trace amounts of krypton from the gas samples for the ATTA analysis. The design, setup and performances of our sampling and purification systems are described here. Our system can produce a high purity aliquot of about 5 μL of krypton from 5 L of air sample (recovery yield of >90%). The samples made by our system were confirmed to be acceptable for the ATTA analysis.
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ISSN (down) 0969-8043 ISBN Medium
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Notes Approved no
Call Number THL @ christoph.kuells @ Romeo2022110450 Serial 214
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Author Haque, N.; Norgate, T.
Title The greenhouse gas footprint of in-situ leaching of uranium, gold and copper in Australia Type Journal Article
Year 2014 Publication Journal of Cleaner Production Abbreviated Journal
Volume 84 Issue Pages 382-390
Keywords Copper, GHG emission, Gold, In-situ leaching, LCA, Uranium
Abstract In-situ leaching (ISL) is a chemical method for recovering useful minerals and metals directly from underground ore bodies which is also referred to as ‘solution mining’. ISL is commonly used for uranium mining, accounting for about 45% of global production. The main benefits are claimed to be a lower environmental impact in terms of visual disturbances, emissions, lower energy use, cost compared with conventional open-cut or underground mining methods, and potential utilisation of lower grade resources. However, there is a lack of reported studies on the assessment of the environmental impacts of ISL, particularly greenhouse gas (GHG) emissions using life cycle assessment (LCA) methodology. The SimaPro LCA software was used to estimate the GHG footprint of the ISL of uranium, gold and copper. The total GHG emissions were estimated to be 38.0 kg CO2-e/kg U3O8 concentrate (yellowcake), 29 t CO2-e/kg gold, and 4.78 kg CO2-e/kg Cu. The GHG footprint of ISL uranium was significantly lower than that of conventional mining, however, the footprints of copper and gold were not much less compared with conventional mining methods. This is due to the lower ore grade of ISL deposits and recovery compared with high ore grades and recovery of conventional technology. Additionally, the use of large amount of electricity for pumping in case of ISL contributes to this result. The electricity consumed in pumping leaching solutions was by far the greatest contributor to the well-field related activities associated with ISL of uranium, gold and copper. The main strategy to reduce the GHG footprint of ISL mining should be to use electricity derived from low emission sources. In particular, renewable sources such as solar would be suitable for ISL as these operations are typically in remote locations with smaller deposits compared with conventional mining sites.
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ISSN (down) 0959-6526 ISBN Medium
Area Expedition Conference
Notes Approved no
Call Number THL @ christoph.kuells @ haque_greenhouse_2014 Serial 208
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Author Singh, A.; Patel, S.; Bhadani, V.; Kumar, V.; Gaurav, K.
Title AutoML-GWL: Automated machine learning model for the prediction of groundwater level Type Journal Article
Year 2024 Publication Engineering Applications of Artificial Intelligence Abbreviated Journal
Volume 127 Issue Pages 107405
Keywords AutoML, Bayesian optimisation, Groundwater, Machine learning
Abstract Predicting groundwater levels is pivotal in curbing overexploitation and ensuring effective water resource governance. However, groundwater level prediction is intricate, driven by dynamic nonlinear factors. To comprehend the dynamic interaction among these drivers, leveraging machine learning models can provide valuable insights. The drastic increase in computational capabilities has catalysed a substantial surge in the utilisation of machine learning-based solutions for effective groundwater management. The performance of these models highly depends on the selection of hyperparameters. The optimisation of hyperparameters is a complex process that often requires application-specific expertise for a skillful prediction. To mitigate the challenge posed by hyperparameter tuning’s problem-specific nature, we present an innovative approach by introducing the automated machine learning (AutoML-GWL) framework. This framework is specifically designed for precise groundwater level mapping. It seamlessly integrates the selection of best machine learning model and adeptly fine-tunes its hyperparameters by using Bayesian optimisation. We used long time series (1997-2018) data of precipitation, temperature, evaporation, soil type, relative humidity, and lag of groundwater level as input features to train the AutoML-GWL model while considering the influence of Land Use Land Cover (LULC) as a contextual factor. Among these input features, the lag of groundwater level emerged as the most relevant input feature. Once the model is trained, it performs well over the unseen data with a strong correlation of coefficient (R = 0.90), low root mean square error (RMSE = 1.22), and minimal bias = 0.23. Further, we compared the performance of the proposed AutoML-GWL with sixteen benchmark algorithms comprising baseline and novel algorithms. The AutoML-GWL outperforms all the benchmark algorithms. Furthermore, the proposed algorithm ranked first in Friedman’s statistical test, confirming its reliability. Moreover, we conducted a spatial distribution and uncertainty analysis for the proposed algorithm. The outcomes of this analysis affirmed that the AutoML-GWL can effectively manage data with spatial variations and demonstrates remarkable stability when faced with small uncertainties in the input parameters. This study holds significant promise in revolutionising groundwater management practices by establishing an automated framework for simulating groundwater levels for sustainable water resource management.
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ISSN (down) 0952-1976 ISBN Medium
Area Expedition Conference
Notes Approved no
Call Number THL @ christoph.kuells @ singh_automl-gwl_2024 Serial 168
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Author Emparanza, A.R.; Kampmann, R.; Caso, F.D.; Morales, C.; Nanni, A.
Title Durability assessment of GFRP rebars in marine environments Type Journal Article
Year 2022 Publication Construction and Building Materials Abbreviated Journal
Volume 329 Issue Pages 127028
Keywords Composite FRP rebar, Durability, Service life, Marine structures, Reinforced concrete
Abstract Technologies developed over the last two decades have facilitated the use of glass fiber reinforced polymer (GFRP) bars as internal reinforcement for concrete structures, specially in coastal environments, mainly due to their corrosion resistance. To-date, most durability studies have focused on a single mechanical parameter (tensile strength) and a single aging environment (exposure to high alkalinity). However, knowledge gaps exists in understanding how other mechanical parameters and relevant conditioning environments may affect the durability of GFRP bars. To this end, this study assesses the durability for different physio-mechanical properties of GFRP rebars, post exposure to accelerated conditioning in seawater. Six different GFRP rebar types were submerged in seawater tanks, at various temperatures (23°C, 40°C and 60°C) for different time periods (60, 120, 210 and 365 days). In total six different physio-mechanical properties were assessed, including: tensile strength, E-modulus, transverse and horizontal shear strength, micro-structural composition and lastly, bond strength. It was inferred that rebars with high moisture absorption resulted in poor durability, in that it affected mainly the tensile strength. Based on the Arrhenius model, at 23°C all the rebars that met the acceptance criteria by ASTM D7957 are expected to retain 85% of the tensile strength capacity.
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Language Summary Language Original Title
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ISSN (down) 0950-0618 ISBN Medium
Area Expedition Conference
Notes Approved no
Call Number THL @ christoph.kuells @ Ruizemparanza2022127028 Serial 83
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Author Marteleto, T. de P.; Abreu, A.E.S. de; Barbosa, M.B.; Yoshinaga-Pereira, S.; Bertolo, R.A.; Enzweiler, J.
Title Groundwater apparent ages and isotopic composition in Crystalline, Diabase and Tubarão aquifers contact area in Campinas, Southeastern Brazil Type Journal Article
Year 2024 Publication Journal of South American Earth Sciences Abbreviated Journal
Volume 135 Issue Pages 104783
Keywords Fractured aquifer, Groundwater mixing, Isotopes, Water management
Abstract This study refines the hydrogeological conceptual model of an area with three interconnected aquifers, namely the Crystalline Aquifer System (CAS – igneous and metamorphic rocks), which is in contact with the Tubarão Aquifer System (TAS – sedimentary rocks) and the Diabase Aquifer System (DAS – diabase rocks). The detailed investigation involved geophysical logging and hydraulic and hydrodynamic characterization with straddle packers in a local tubular well, in which groundwater presents high uranium concentrations. Hydrogeochemical and isotope (δ2H, δ18O, 3H, δ13C, 14C) analysis in this well and in other three neighboring wells, with lower U concentrations, showed that ancient and modern waters (3H from <0.8 to 1.12 TU, 14C from 69.43 to 78.72 pMC) mix within the aquifer. During groundwater pumping, vertical fractures in the diabase aquifer possibly induce water mixing and recharge of the deeper levels of the aquifers from shallow layers. The high [U] are related to ancient waters from a confined aquifer hosted in CAS that reaches the wells through hydraulically active fractures located deeper than 159 m depth. Groundwater apparent ages do not increase systematically with depth, revealing a complex circulation model for CAS. The results obtained from the other wells, which are all located on drainage lineaments, reveal that one extracts modern water from DAS and TAS, another one extracts modern and ancient water from DAS and CAS, and the third extracts only ancient water from CAS, confirming the complexity of the local hydrogeology. Regarding regional groundwater management, the study revealed the need to characterize the sources of groundwater in each well, in order to protect modern waters from anthropogenic contamination and to protect ancient groundwater from overexploitation, as CAS hosts groundwaters recharged thousands of years ago or more.
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Language Summary Language Original Title
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ISSN (down) 0895-9811 ISBN Medium
Area Expedition Conference
Notes Approved no
Call Number THL @ christoph.kuells @ Depaulamarteleto2024104783 Serial 221
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