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| Author |
Bonnetti, C.; Zhou, L.; Riegler, T.; Brugger, J.; Fairclough, M. |
| Title |
Large S isotope and trace element fractionations in pyrite of uranium roll front systems result from internally-driven biogeochemical cycle |
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Journal Article |
| Year |
2020 |
Publication  |
Geochimica et Cosmochimica Acta |
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| Volume |
282 |
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113-132 |
| Keywords |
Activity cycle, Pyrite composition, Roll front uranium deposits, S isotope and trace element fractionation |
| Abstract |
Complex pyrite textures associated with large changes in isotopic and trace element compositions are routinely assumed to be indicative of multi-faceted processes involving multiple fluid and sulfur sources. We propose that the features of ore-stage pyrite from roll front deposits across the world, revealed in exquisite detail via high-resolution trace element mapping by LA-ICP-MS, reflect the dynamic internal evolution of the biogeochemical processes responsible for sulfate reduction, rather than externally driven changes in fluid or sulfur sources through time. Upon percolation of oxidizing fluids into the reduced host-sandstones, roll front systems become self-organized, with a systematic reset of their activity cycle after each translation stage of the redox interface down dip of the aquifer. Dominantly reducing conditions at the redox interface favor the formation of biogenic framboidal pyrite (δ34S from −30.5 to −12.5‰) by bacterial sulfate reduction and the genesis of the U mineralization. As the oxidation front advances, oxidation of reduced sulfur minerals induces an increased supply of sulfate and metals in solution to the bacterial sulfate reduction zone that has similarly advanced down the flow gradient. Hence, this stage is marked by increased rates of the bacterial sulfate reduction associated with the crystallization of variably As-Co-Ni-Mo-enriched concentric pyrite (up to 10,000′s of ppm total trace contents) with moderately negative δ34S values (from −13.7 to −7.5‰). A final stage of pyrite cement with low trace element contents and heavier δ34S signature (from −6.9 to +18.8‰) marks the end of the roll front activity cycle and the transition from an open to a predominantly closed system behavior (negligible advection of fresh sulfate). Blocky pyrite cement is formed using the remaining sulfate, which now becomes quickly heavy according to a Rayleigh isotope fractionation process. This ends the cycle by depleting the nutrient supplies for the sulfate-reducing bacteria and cementing pore spaces within the host sandstone, effectively restricting fluid infiltration. This internally-driven roll front activity cycle results in systematic, large S isotope and trace element fractionation. Ultimately, the long-time evolution of the basin and fluid sources control the metal endowment and evolution of the system; these events, however, are unlikely to be preserved by the roll front, as a direct result of its hydrodynamic nature. |
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0016-7037 |
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THL @ christoph.kuells @ bonnetti_large_2020 |
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185 |
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Sahoo, S.K.; Jha, V.N.; Patra, A.C.; Jha, S.K.; Kulkarni, M.S. |
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Scientific background and methodology adopted on derivation of regulatory limit for uranium in drinking water – A global perspective |
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Journal Article |
| Year |
2020 |
Publication |
Environmental Advances |
Abbreviated Journal |
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2 |
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100020 |
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Drinking water, Global policy, Regulatory limits, Toxicity, Uranium |
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Guideline values are prescribed for drinking water to ensure long term protection of the public against anticipated potential adverse effects. There is a great public and regulatory agencies interest in the guideline values of uranium due to its complex behavior in natural aquatic system and divergent guideline values across the countries. Wide variability in guideline values of uranium in drinking water may be attributed to toxicity reference point, variation in threshold values, uncertainty within intraspecies and interspecies, resource availability, socio-economic condition, variation in ingestion rate, etc. Although guideline values vary to a great extent, reasonable scientific basis and technical judgments are essential before it could be implemented. Globally guideline values are derived considering its radiological or chemical toxicity. Minimal or no adverse effect criterions are normally chosen as the basis for deriving the guideline values of uranium. In India, the drinking water limit of 60 µg/L has been estimated on the premise of its radiological concern. A guideline concentration of 2 µg/L is recommended in Japan while 1700 µg/L in Russia. The relative merit of different experimental assumption, scientific approach and its methodology adopted for derivation of guideline value of uranium in drinking water in India and other countries is discussed in the paper. |
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2666-7657 |
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THL @ christoph.kuells @ sahoo_scientific_2020 |
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127 |
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Doulgeris, C.; Tziritis, E.; Pisinaras, V.; Panagopoulos, A.; Külls, C. |
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Prediction of seawater intrusion to coastal aquifers based on non-dimensional diagrams |
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2020 |
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EGU Geophysical Abstracts |
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4073 |
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THL @ christoph.kuells @ Doulgeris2020prediction |
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41 |
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Krüger, N.; Külls, C.; Bruggeman, A.; Eliades, M.; Christophi, C.; Rigas, M.; Eracleous, T. |
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Groundwater recharge estimates with soil isotope profiles-is there a bias on coarse-grained hillslopes? |
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2020 |
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EGU General Assembly Conference Abstracts |
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9840 |
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THL @ christoph.kuells @ Krueger2020groundwater |
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42 |
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Tziritis, E.; Aschonitis, V.; Balacco, G.; Daras, P.; Doulgeris, C.; Fidelibus, M.D.; Gaubi, E.; Gueddari, M.; Güler, C.; Hamzaoui, F.; others |
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MEDSAL Project-Salinization of critical groundwater reserves in coastal Mediterranean areas: Identification, risk assessment and sustainable management with the use of integrated modelling and smart ICT tools |
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2020 |
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EGU General Assembly Conference Abstracts |
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2326 |
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THL @ christoph.kuells @ Tziritis2020medsal |
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43 |
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