Abstract: Qanat is a passive (unpumped) horizontal well (or a slant well with a very mild inclined angle) that is capable of extracting water from aquifers by gravity. Many qanats are constructed along the radius of the alluvial fan wedge-shaped aquifers. Analytical modeling of such a qanat-aquifer system provides great benefit for quickly screening different designs of qanats and accessing the performance of qanat discharge in the field. The previous analytical modeling of discharge of qanats, however, did not consider the wedge-shaped aquifers. Thus, the goal of this research is to obtain semi-analytical solutions of discharge variations of qanats in alluvial fan aquifers with nearby pumping wells, subjected to areal recharges due to rainfall. The uniform head boundary is considered inside the qanat (because of its enormous permeability in respect to the background aquifer). The influences of the aquifer lateral boundaries on discharge of qanat and its sensitivity to hydraulic and geometric parameters are explored. The influences of the lateral boundaries on the discharge of qanat due to areal recharge and nearby pumping wells discharge are also explored. The results of this study can be utilized for multiple purposes: 1) to predict the discharge of qanat in an alluvial fan aquifer and explore the influences of the areal recharge and nearby pumping well discharge; 2) to estimate the hydraulic parameters of the alluvial fan aquifer depleted by a qanat; 3) to determine the location of the nearby pumping well to minimize its influences on the discharge of a qanat; 4) to calculate the water budgets of aquifers depleted by qanats and pumping wells and replenished by areal recharge among other applications. This paper is an extension to the work presented by Sedghi and Zhan (2020) (which concerns an infinite unconfined aquifer) for an unconfined alluvial fan aquifer setting.

Abstract: Ordinary Portland cement (OPC) is known for its significant contribution to carbon dioxide emissions. Geopolymer has a lower footprint in terms of CO2 emissions and has been considered as an alternative for OPC. A well-developed understanding of the use of fly-ash-based and slag-based geopolymers as separate systems has been reached in the literature, specifically regarding their mechanical properties. However, the microstructural and durability of the combined system after slag addition introduces more interactive gels and complex microstructural formations. The microstructural changes of complex blended systems contribute to significant advances in the durability of fly ash/slag geopolymers. In the present review, the setting time, microstructural properties (gel phase development, permeability properties, shrinkage behavior), and durability (chloride resistance, sulfate attack, and carbonatation), as discussed literature, are studied and summarized to simplify and draw conclusions.

Abstract: The sandstone-hosted uranium mineralization areas in the Sanzhao Sag of the northern Songliao Basin have been newly identified. The target stratum is the Upper Cretaceous Sifangtai Formation and the uranium mineralization mainly occurs in the bottom of Sifangtai Formation, corresponding to channel sand bodies in meandering river system, characterized by medium to fine-grained sandstone. This study proposes the uranium metallogenic model through petrographic observation, whole rock geochemistry, mineralogical study of uranium occurrence form (SEM), organic matter rock–eval pyrolysis analysis (REP) and in-situ sulfur isotope determination of different generations of pyrite by LA-MC-ICP-MS. Compared with the sandstones collected in barren reduction and oxidization zones, the mineralized sandstones show obvious increase in the contents of TOC, total sulfur, Y and U. Petrographic observations indicate that organic matters are mainly inherited from land plants. REP data display that the organic matter (OM) disseminated in the sandstone has very low hydrogen index (HI) from around 0 to 21 mg HC/g TOC and varied oxygen index (OI) from 44 to 115 mg CO2/g TOC, corresponding to Type Ⅳ kerogen (degraded kerogen). There are two types of coffinite with different grain size, micro-particles (μm-sized) and large aggregates (generally up to 100 μm) respectively. The coffinite micro spherules exhibit short rod-like or worm-like morphology occurring in clay matrix and cell cavities in degradofusinite or around subidiomorphic-idiomorphic pyrite. The coarse-grained coffinite contains other mineral facies (e.g. pyrite, quartz) and some of large coffinite aggregates display thrombolite-type microbial structures. The irregular pyrite relict particles in coarse-grained colloidal coffinite have light sulfur isotope compositions characterized by δ34S values from –39.96‰ to –49.89‰. The δ34S values of colloidal pyrite in replacement of OM or of the sub-idiomorphic FeS2 cement filling in the cavities of OM range from –52.77‰ to –13.88‰. Some of sub-idiomorphic pyrite cement and idiomorphic crystal have the heavier signature from – 27.06‰ to + 14.23‰. The light sulfur isotope signature suggests that the sulfur originates from bacterial sulfate reduction (BSR). The OM replacement by pyrite and the highest OI values recorded by REP in uranium mineralized samples are lines of evidence of biodegradation. Bacteria use the organic matter as food source and produce isotopically light reduced sulfur species. Oxygenated uranium-bearing waters infiltrated through the denudated windows at Daqing placanticline into the porous reduced sandstones deposited in the Sanzhao Sag. Uranium was indirectly reduced by BSR-derived iron disulfides or directly reduced by sulfate-reducing bacteria.