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Boumaiza, L., Ammar, S. B., Chesnaux, R., Stotler, R. L., Mayer, B., Huneau, F., et al. (2023). Nitrate sources and transformation processes in groundwater of a coastal area experiencing various environmental stressors. Journal of Environmental Management, 345, 118803.
Abstract: In coastal salinized groundwater systems, contamination from various nitrate (NO3) inputs combined with complex hydrogeochemical processes make it difficult to distinguish NO3 sources and identify potential NO3 transformtation processes. Effective field-based NO3 studies in coastal areas are needed to improve the understanding of NO3 contamination dynamics in groundwater of such complex coastal systems. This study focuses on a typical Mediterranean coastal agricultural area, located in Tunisia, experiencing substantial NO3 contamination from multiple anthropogenic sources. Here, multiple isotopic tracers (δ18OH2O, δ2HH2O, δ15NNO3, δ18ONO3, and δ11B) combined with a Bayesian isotope MixSIAR model are used (i) to identify the major NO3 sources and their contributions, and (ii) to describe the potential NO3 transformation processes. The measured NO3 concentrations in groundwater are above the natural baseline threshold, suggesting anthropogenic influence. The measured isotopic composition of NO3 indicates that manure, soil organic matter, and sewage are the potential sources of NO3, while δ11B values constrain the NO3 contamination to manure; a finding that is supported by the results of MixSIAR model revealing that manure-derived NO3 dominates over other likely sources. Nitrate derived from manure in the study area is attributed to organic fertilizers used to promote crop growth, and livestock that deposit manure directly on the ground surface. Evidence for ongoing denitrification in groundwaters of the study area is supported by an enrichment in both 15N and 18O in the remaining NO3, although isotopic mass balances between the measured and the theoretical δ18ONO3 values also suggest the occurrence of nitrification. The simultaneous occurrence of these biogeochemical processes with heterogeneous distribution across the study area reflect the complexity of interactions within the investigated coastal aquifer. The multiple isotopic tracer approach used here can identify the effect of multiple NO3 anthropogenic activities in coastal environments, which is fundamental for sustainable groundwater resources management.
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Johnson, R. S. H., & Alila, Y. (2023). Nonstationary stochastic paired watershed approach: Investigating forest harvesting effects on floods in two large, nested, and snow-dominated watersheds in British Columbia, Canada. Journal of Hydrology, 625, 129970.
Abstract: Drawing on advances in nonstationary frequency analysis and the science of causation and attribution, this study employs a newly developed nonstationary stochastic paired watershed approach to determine the effect of forest harvesting on snowmelt-generated floods. Moreover, this study furthers the application of stochastic physics to evaluate the environmental controls and drivers of flood response. Physically-based climate and time-varying harvesting data are used as covariates to drive the nonstationary flood frequency distribution parameters to detect, attribute, and quantify the effect of harvesting on floods in the snow-dominated Deadman River (878 km2) and nested Joe Ross Creek (99 km2) watersheds. Harvesting only 21% of the watershed caused a 38% and 84% increase in the mean but no increase in variability around the mean of the frequency distribution in the Deadman River and Joe Ross Creek, respectively. Consequently, the 7-year, 20-year, 50-year, and 100-year flood events became approximately two, four, six, and ten times more frequent in both watersheds. An increase in the mean is posited to occur from an increase in moisture availability following harvest from suppressed snow interception and increased net radiation reaching the snowpack. Variability was not increased because snowmelt synchronization was inhibited by the buffering capacity of abundant lakes, evenly distributed aspects, and widespread spatial distribution of cutblocks in the watersheds, preventing any potential for harvesting to increase the efficiency of runoff delivery to the outlet. Consistent with similar recent studies, the effect of logging on floods is controlled not only by the harvest rate but most importantly the physiographic characteristics of the watershed and the spatial distribution of the cutblocks. Imposed by the probabilistic framework to understanding and predicting the relation between extremes and their environmental controls, commonly used in the general sciences but not forest hydrology, it is the inherent nature of snowmelt-driven flood regimes which cause even modest increases in magnitude, especially in the upper tail of the distribution, to translate into surprisingly large changes in frequency. Contrary to conventional wisdom, harvesting influenced small, medium, and very large flood events, and the sensitivity to harvest increased with increasing flood event size and watershed area.
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Zhao, Y., Li, X., Lei, L., Chen, L., & Luo, Z. (2023). Permeability evolution mechanism and the optimum permeability determination of uranium leaching from low-permeability sandstone treated with low-frequency vibration. Journal of Rock Mechanics and Geotechnical Engineering, 15(10), 2597–2610.
Abstract: Low-frequency vibrations can effectively improve natural sandstone permeability, and higher vibration frequency is associated with larger permeability. However, the optimum permeability and permeability evolution mechanism for uranium leaching and the relationship between permeability and the change of chemical reactive rate affecting uranium leaching have not been determined. To solve the above problems, in this study, identical homogeneous sandstone samples were selected to simulate low-permeability sandstone; a permeability evolution model considering the combined action of vibration stress, pore water pressure, water flow impact force, and chemical erosion was established; and vibration leaching experiments were performed to test the model accuracy. Both the permeability and chemical reactions were found to simultaneously restrict U6+ leaching, and the vibration treatment increased the permeability, causing the U6+ leaching reaction to no longer be diffusion-constrained but to be primarily controlled by the reaction rate. Changes of the model calculation parameters were further analyzed to determine the permeability evolution mechanism under the influence of vibration and chemical erosion, to prove the correctness of the mechanism according to the experimental results, and to develop a new method for determining the optimum permeability in uranium leaching. The uranium leaching was found to primarily follow a process consisting of (1) a permeability control stage, (2) achieving the optimum permeability, (3) a chemical reactive rate control stage, and (4) a channel flow stage. The resolution of these problems is of great significance for facilitating the application and promotion of low-frequency vibration in the CO2 + O2 leaching process.
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Rusli, S. R., Weerts, A. H., Mustafa, S. M. T., Irawan, D. E., Taufiq, A., & Bense, V. F. (2023). Quantifying aquifer interaction using numerical groundwater flow model evaluated by environmental water tracer data: Application to the data-scarce area of the Bandung groundwater basin, West Java, Indonesia. Journal of Hydrology: Regional Studies, 50, 101585.
Abstract: Study Region: Bandung groundwater basin, Indonesia. Study focus: Groundwater abstraction of various magnitudes, pumped out from numerous depths in a multitude of layers of aquifers, stimulates different changes in hydraulic head distribution, including ones under vertical cross-sections. This generates groundwater flow in the vertical direction, where groundwater flows within its storage from the shallow to the underlying confined aquifers. In the Bandung groundwater basin, previous studies have identified such processes, but quantitative evaluations have never been conducted, with data scarcity mainly standing as one of the major challenges. In this study, we utilize the collated (1) environmental water tracer data, including major ion elements (Na+/K+, Ca2＋, Mg2+, Cl−, SO42−,HCO3−), stable isotope data (2H and δ18O), and groundwater age determination (14C), in conjunction with (2) groundwater flow modeling to quantify the aquifer interaction, driven mainly by the multi-layer groundwater abstraction in the Bandung groundwater basin, and demonstrate their correspondence. In addition, we also use the model to quantify the impact of multi-layer groundwater abstraction on the spatial distribution of the groundwater level changes. New hydrological insights for the region: In response to the limited calibration data availability, we expand the typical model calibration that makes use of the groundwater level observations, with in-situ measurement and a novel qualitative approach using the collated environmental water tracers (EWT) data for the model evaluation. The analysis in the study area using EWT data and quantitative methods of numerical groundwater flow modeling is found to collaborate with each other. Both methods show agreement in their assessment of (1) the groundwater recharge spatial distribution, (2) the regional groundwater flow direction, (3) the groundwater age estimates, and (4) the identification of aquifer interaction. On average, the downwelling to the deeper aquifer is quantified at 0.110 m/year, which stands out as a significant component compared to other groundwater fluxes in the system. We also determine the unconfined aquifer storage volume decrease, calculated from the change in the groundwater table, resulting in an average declining rate of 51 Mm3/year. This number shows that the upper aquifer storage is dwindling at a rate disproportionate to its groundwater abstraction, hugely influenced by losses to the deeper aquifer. The outflow to the deeper aquifer contributes to 60.3% of the total groundwater storage lost, despite representing only 32.3% of the total groundwater abstraction. This study shows the possibility of quantification of aquifer interaction and groundwater level change dynamics driven by multi-layer groundwater abstraction in a multi-layer hydrogeological setting, even in a data-scarce environment. Applying such methods can assist in deriving basin-scale groundwater policies and management strategies under the changing anthropogenic and climatic factors, thereby ensuring sustainable groundwater management.
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Petisco-Ferrero, S., Idoeta, R., Rozas, S., Olondo, C., & Herranz, M. (2023). Radiological environmental monitoring of groundwater around NPP: A proposal for its assessment. Heliyon, 9(9), 19470.
Abstract: Whether a nuclear installation has radiological impact and, in that case, its extension, are the questions behind any environmental analysis of the installation along its operational life. This analysis is based on the detailed establishment of the radiological background of the area. Accordingly, the dismantling and decommissioning process (D&D) of a nuclear power plant starts with a radiological monitoring plan, which includes the radiological characterization of the area and of its surroundings. At the completion of the D&D, unrestricted use for the site will be permitted strictly in accordance with results of the radiological survey within the limits established by the local authorities. Groundwater quality is typically included in any radiological analysis since, among other reasons, a significant part of it is highly likely to end up being extracted for domestic use and hence, human consumption. While there is no regulation containing maximum activity concentration or radionuclide guidance values for water that may be destined for uses other than public consumption, if groundwater is considered a “part” of the land, dose criteria for site release can be applied. Therefore, together with the guidance levels to be established for the different radionuclides expected in the groundwater, the detection limits to be employed when performing routine radio analytical characterization procedures in the laboratory should also be provided. In this paper, we first propose a relation of the potential radionuclides to be analyzed in groundwater, together with their detection limits to be achieved when the determinations are performed in a laboratory, and subsequently, we discuss the most suitable analytical methodologies and resources that would be necessary to undertake radiological characterization plans from a practical point of view.
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