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Author Wang, B.; Luo, Y.; Qian, J.-zhong; Liu, J.-hui; Li, X.; Zhang, Y.-hong; Chen, Q.-qian; Li, L.-yao; Liang, D.-ye; Huang, J. url  openurl
  Title (down) Machine learning–based optimal design of the in-situ leaching process parameter (ISLPP) for the acid in-situ leaching of uranium Type Journal Article
  Year 2023 Publication Journal of Hydrology Abbreviated Journal  
  Volume 626 Issue Pages 130234  
  Keywords In-situ leaching, Injection rate design, Lixiviant concentration design, Machine learning, Simulation-optimisation, Uncertainty  
  Abstract The migration process of leached uranium in the in-situ leaching of uranium is considered a typical reactive transport problem. During this process, the lixiviant concentration and injection rate are important in-situ leaching process parameters (ISLPP) to efficiently recover uranium. However, several uncertain factors affect the outcomes of the ISLPP design. In addition, the repeated use of the reactive transport model (RTM) for investigating the acid in-situ leaching of uranium with the application of the Monte Carlo method leads to a substantial computational load. For this reason, a machine learning (ML)–based surrogate model was developed with the backpropagation neural network (BPNN) method to replace the RTM under the condition of uncertain parameters. Moreover, the simulated annealing optimisation model for ISLPP was created based on the proposed surrogate model. The optimal ISLPP was achieved that generated maximum profits from uranium recovery under different lixiviant prices, uranium prices and exploitation times. The optimal design framework of ISLPP based on the proposed ML algorithm was then applied in the Bayan-Uul sandstone-type uranium deposit in Inner Mongolia, China. From our analysis, it was demonstrated that the ML-based surrogate model exhibited great fitness with the RTM. The optimal results of the ISLPP indicated that the lixiviant concentration and injection rate could be adjusted based on the fluctuations in lixiviant price, uranium price and exploitation time. If the prices of sulphuric acid were high, a specific concentration of hydrogen peroxide could be injected into the injection well to promote the oxidation and dissolution of the uranium ore to increase the income from the uranium recovery. The optimisation model can also use the ISLPP scheme to boost the revenues from different lixiviant prices, uranium prices and exploitation times under the uncertainty of porosity, illustrating the applicability of the ML-based optimal design method of ISLPP in ISL mining. A general framework for developing surrogate models, as well as for conducting uncertainty analyses for a wide range of groundwater models was proposed here yielding valuable insights.  
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  ISSN 0022-1694 ISBN Medium  
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  Notes Approved no  
  Call Number THL @ christoph.kuells @ wang_machine_2023 Serial 210  
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Author Merembayev, T.; Yunussov, R.; Yedilkhan, A. url  openurl
  Title (down) Machine Learning Algorithms for Stratigraphy Classification on Uranium Deposits Type Journal Article
  Year 2019 Publication Procedia Computer Science Abbreviated Journal  
  Volume 150 Issue Pages 46-52  
  Keywords classification, geophysics logging data, machine learning, stratigraphy, uranium deposit  
  Abstract Machine learning today becomes more and more effective instrument to solve many particular problems, where there are difficulties to apply well known and described math model. In other words – it is a great tool to describe non-linear phenomena. We tried to use this technique to improve existing process of stratigraphy, and reduce costs on site by applying computer leaded predictions on the basis of existing on-field collected data. Article describes usage of machine learning algorithms for stratigraphy boundaries classification based on geophysics logging data for uranium deposit in Kazakhstan. Correct marking of stratigraphy from geophysics logging data is complex non-linear task. To solve this task we applied several algorithms of machine learning: random forest, logistic regression, gradient boosting, k nearest neighbour and XGBoost.  
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  ISSN 1877-0509 ISBN Medium  
  Area Expedition Conference  
  Notes Approved no  
  Call Number THL @ christoph.kuells @ merembayev_machine_2019 Serial 113  
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Author Lawrinenko, M.; Kurwadkar, S.; Wilkin, R.T. url  openurl
  Title (down) Long-term performance evaluation of zero-valent iron amended permeable reactive barriers for groundwater remediation – A mechanistic approach Type Journal Article
  Year 2023 Publication Geoscience Frontiers Abbreviated Journal  
  Volume 14 Issue 2 Pages 101494  
  Keywords Geochemistry, Iron, Permeable reactive barrier, Plating reactions, Reduction potential, Surface passivation  
  Abstract Permeable reactive barriers (PRBs) are used for groundwater remediation at contaminated sites worldwide. This technology has been efficient at appropriate sites for treating organic and inorganic contaminants using zero-valent iron (ZVI) as a reductant and as a reactive material. Continued development of the technology over the years suggests that a robust understanding of PRB performance and the mechanisms involved is still lacking. Conflicting information in the scientific literature downplays the critical role of ZVI corrosion in the remediation of various organic and inorganic pollutants. Additionally, there is a lack of information on how different mechanisms act in tandem to affect ZVI-groundwater systems through time. In this review paper, we describe the underlying mechanisms of PRB performance and remove isolated misconceptions. We discuss the primary mechanisms of ZVI transformation and aging in PRBs and the role of iron corrosion products. We review numerous sites to reinforce our understanding of the interactions between groundwater contaminants and ZVI and the authigenic minerals that form within PRBs. Our findings show that ZVI corrosion products and mineral precipitates play critical roles in the long-term performance of PRBs by influencing the reactivity of ZVI. Pore occlusion by mineral precipitates occurs at the influent side of PRBs and is enhanced by dissolved oxygen and groundwater rich in dissolved solids and high alkalinity, which negatively impacts hydraulic conductivity, allowing contaminants to potentially bypass the treatment zone. Further development of site characterization tools and models is needed to support effective PRB designs for groundwater remediation.  
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  ISSN 1674-9871 ISBN Medium  
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  Notes Approved no  
  Call Number THL @ christoph.kuells @ lawrinenko_long-term_2023 Serial 143  
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Author Burchi, S. url  openurl
  Title (down) Legal frameworks for the governance of international transboundary aquifers: Pre- and post-ISARM experience Type Journal Article
  Year 2018 Publication Journal of Hydrology: Regional Studies Abbreviated Journal  
  Volume 20 Issue Pages 15-20  
  Keywords International aquifers, International aquifers agreements, International groundwater law, UN draft articles on the law of transboundary aquifers  
  Abstract Study region Africa, Latin America, Europe. Study focus Through the extensive study and mapping of the world’s aquifers that lie astride the international boundary lines of sovereign States, ISARM has awakened concerned States to the existence of aquifers stretching beyond their borders, and precipitated cooperation in generating a body of knowledge that facilitated cooperation in governance arrangements for such aquifers. In parallel, ISARM influenced the shape and direction of the United Nations “Draft articles on the law of transboundary aquifers” appended to UN Resolution 63/124 of 2008. Both stimulated cooperation among concerned States, and provided a frame of reference for the legal grounding of such cooperation in aquifer-specific agreements. New hydrological insights Through this synergistic paradigm, ISARM has made an impact on the shape and direction of cooperation in the Guaraní Aquifer in South America, and in the Iullemeden and Taoudeni/Tanezrouft Aquifer Systems (ITAS) in the Sahel region of Africa. It is having an influence on the shape and direction of cooperation being negotiated on the Stampriet Aquifer System in Southern Africa, and on the Ocotepeque-Citalá Aquifer in Central America. The link of ISARM to other international aquifer agreements on record is tenuous, and ISARM’s influence on their generation speculative. The visibility of ISARM has faded since 2012, however its legacy is lasting.  
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  Series Volume Series Issue Edition  
  ISSN 2214-5818 ISBN Medium  
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  Notes Approved no  
  Call Number THL @ christoph.kuells @ burchi_legal_2018 Serial 100  
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Author Xie, T.; Lian, B.; Chen, C.; Qian, T.; Liu, X.; Shang, Z.; Li, T.; Wang, R.; Wang, Z.; Zhang, A.; Zhu, J. url  openurl
  Title (down) Leaching behaviour and mechanism of U, 226Ra and 210Pb from uranium tailings at different pH conditions Type Journal Article
  Year 2023 Publication Journal of Environmental Radioactivity Abbreviated Journal  
  Volume 270 Issue Pages 107300  
  Keywords Leaching experiments, Pb, Ra, U, Uranium tailings  
  Abstract A large number of radionuclides remain in uranium tailings, and U, 226Ra and 210Pb leach out with water chemistry, causing potential radioactive contamination to the surrounding environment. In this paper, uranium tailings from a uranium tailings pond in southern China were collected at different depths by means of borehole sampling, mixed and homogenised, and analysed for mineral and chemical composition, microscopic morphology, U, 226Ra and 210Pb fugacity, static leaching and dynamic leaching of U, 226Ra and 210Pb in uranium tailings at different pH conditions. The variation of U, 226Ra and 210Pb concentrations in the leachate under different pH conditions with time was obtained, and the leaching mechanism was analysed. The results showed that the uranium tailings were dominated by quartz, plagioclase and other minerals, of which SiO2 and Al2O3 accounted for 65.45% and 13.32% respectively, and U, 226Ra and 210Pb were mainly present in the residue form. The results of the static leaching experiments show that pH mainly influences the leaching of U, 226Ra and 210Pb by changing their chemical forms and the particle properties of the tailings, and that the lower the pH the more favourable the leaching. The results of dynamic leaching experiments during the experimental cycle showed that the leaching concentration and cumulative release of U, 226Ra and 210Pb in the leach solution were greater at lower pH conditions than at higher pH conditions, and the leaching of U, 226Ra and 210Pb at different pH conditions was mainly from the water-soluble and exchangeable states. The present research results are of great significance for the environmental risk management and control of radioactive contamination in existing uranium tailings ponds, and are conducive to ensuring the long-term safety, stability and sustainability of uranium mining sites.  
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  ISSN 0265-931x ISBN Medium  
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  Notes Approved no  
  Call Number THL @ christoph.kuells @ xie_leaching_2023 Serial 200  
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