Abstract: Data are presented for nitrate, dinitrogen and argon concentrations and 15N14N ratios in groundwater, with radiocarbon ages up to 40,000 yr. for three confined sandstone aquifers in the western Kalahari of South West Africa/Namibia. The nitrate is probably generated within the soil of the recharge areas, and its production rate during the period 3000-40,000 B.P. has remained between 0.5 and 1.6 meq NO−3l−1 of recharge water, with ° 15N between + 4 and + 8‰. Variations in the amount of nitrate and of “excess air” in groundwater recharge are found, and can only reflect changes in the environmental conditions during recharge. They must therefore be caused by the climatic changes that have taken place during the past 25,000 yr.

Abstract: As an ancient underground hydraulic engineering facility, the Qanat system has been used to draw groundwater from arid regions. A qanat is a horizontal tunnel with a slight incline that draws groundwater from a higher location and delivers it to lower agricultural land. During long-term water delivery, the qanat tunnel has experienced different degrees of aging and collapse, which may result in the significant ground settlement and even disasters. This paper developed a two-dimensional laboratory system to investigate the influence of progressive failure on the stability of deeply buried qanat tunnels. The developed system is fully instrumented with a particle image velocimetry (PIV) system and earth pressure and displacement monitoring. A special cylindrical membrane tube is designed and connected to an advanced pressure–volume controller to simulate the step-wise failure process of the tunnel. Three model tests were conducted on a dry sand considering the buried qanat tunnels at three different depths. Experimental results clearly show the progressive evolution of soil arching effect in the dry sand associated with the progressive failure of the tunnels. The failure of the Qanat ground starts from the vault and develops upwards, which is closely related to the evolution of stress contour at three consecutive stages. Ground surface settlement and volume loss corresponding to three burial depths were compared. A deeply buried qanat tunnel has a small effect on surface settlement. Earth pressure evolution on the 2D plane shows the load redistribution when the qanat collapses. The maximum arch and the initial point of the limit state correspond to a volume loss of 12.5 % and 50 %, respectively. For the collapse of the deep buried qanat tunnel, ground earth pressure evolution can be divided into a stress-increasing region, stress-decreasing region, and no redistribution region. Furthermore, a multi trap-door model considering soil expansion is proposed to describe the progressive failure behavior and its effects.

Abstract: Elevated levels of nitrate occur in phreatic groundwater in the western Kalahari, Namibia. Nitrate in water containing 0.4–3.1 meq NO−3l−1, of widespread occurrence, has δ15N values in the range +4.9 to +8.0‰, suggesting natural derivation from the soil. The sporadic occurrence of very high levels of nitrate (> 4 meq NO−3l−1), which has δ15N between +9.3 to +18.7‰, reflects pollution derived from animal waste. The importance of considering the possible isotopic effects of denitrification, and the significance of leaching in the nitrogen budget of the Kalahari soil, are also discussed.