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Author Edmunds, W.M.; Shand, P.; Hart, P.; Ward, R.S.
Title The natural (baseline) quality of groundwater: a UK pilot study Type Journal Article
Year (up) 2003 Publication Science of The Total Environment Abbreviated Journal
Volume 310 Issue 1 Pages 25-35
Keywords Baseline quality, Groundwater, Hydrogeochemistry, Monitoring, Water Policy
Abstract Knowledge of the natural baseline quality of groundwaters is an essential prerequisite for understanding pollution and for imposing regulatory limits. The natural baseline of groundwaters may show a range of concentrations depending on aquifer mineralogy, facies changes, flow paths and residence time. The geochemical controls on natural concentrations are discussed and an approach to defining baseline concentrations using geochemical and statistical tools is proposed. The approach is illustrated using a flowline from the Chalk aquifer in Berkshire, UK where aerobic and anaerobic sections of the aquifer are separately considered. The baseline concentrations for some elements are close to atmospheric values whereas others evolve through time-dependent water–rock interaction. Certain solutes (K, NH4+), often considered contaminants, reach naturally high concentrations due to geochemical controls; transition metal concentrations are generally low, although their concentrations may be modified by redox controls. It is recommended that the baseline approach be incorporated into future management strategies, notably monitoring.
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ISSN 0048-9697 ISBN Medium
Area Expedition Conference
Notes Approved no
Call Number THL @ christoph.kuells @ edmunds_natural_2003 Serial 166
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Author Tröger, U.; Dias, C.L.; Guillaumon, J.R.; Iritani, M.A.; Külls, C.; Schuler, G.
Title Remarks and new data about the recharge of the Guarani Aquifer System Type Conference Article
Year (up) 2004 Publication XXXIII IAH Congress, Abstracts, IAH, Mexico Abbreviated Journal
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Notes Approved no
Call Number THL @ christoph.kuells @ Troeger2004remarks Serial 59
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Author Külls, C.
Title Demonstration des Potentials der Nitrat-Isotopenanalytik für die Strategieentwicklung der Sanierung Nitrat-belasteter Brunnen Type Report
Year (up) 2004 Publication Umweltbundesamt Abbreviated Journal
Volume Issue Pages
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Abstract Demonstration des Potentials der Nitrat-Isotopenanalytik für die Strategieentwicklung der Sanierung Nitrat-belasteter Brunnen
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Notes Approved no
Call Number THL @ christoph.kuells @ Serial 75
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Author Orloff, K.G.; Mistry, K.; Charp, P.; Metcalf, S.; Marino, R.; Shelly, T.; Melaro, E.; Donohoe, A.M.; Jones, R.L.
Title Human exposure to uranium in groundwater Type Journal Article
Year (up) 2004 Publication Environmental Research Abbreviated Journal
Volume 94 Issue 3 Pages 319-326
Keywords Groundwater, Human exposure, Uranium, Urine
Abstract High concentrations of uranium (mean=620μg/L) were detected in water samples collected from private wells in a residential community. Based on isotopic analyses, the source of the uranium contamination appeared to be from naturally occurring geological deposits. In homes where well water concentrations of uranium exceeded the drinking water standard, the residents were advised to use an alternate water source for potable purposes. Several months after the residents had stopped drinking the water, urine samples were collected and tested for uranium. Elevated concentrations of uranium (mean=0.40μg/g creatinine) were detected in urine samples, and 85 percent of the urine uranium concentrations exceeded the 95th percentile concentration of a national reference population. Urine uranium concentrations were positively correlated with water uranium concentrations, but not with the participants’ ages or how long they had been drinking the water. Six months later, a second urine sample was collected and tested for uranium. Urine uranium concentrations decreased in most (63 percent) of the people. In those people with the highest initial urine uranium concentrations, the urine levels decreased an average of 78 percent. However, urine uranium concentrations remained elevated (mean=0.27μg/g), and 87 percent of the urine uranium concentrations exceeded the 95th percentile concentration of the reference population. The results of this investigation demonstrated that after long-term ingestion of uranium in drinking water, elevated concentrations of uranium in urine could be detected up to 10 months after exposure had stopped.
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ISSN 0013-9351 ISBN Medium
Area Expedition Conference
Notes Approved no
Call Number THL @ christoph.kuells @ orloff_human_2004 Serial 136
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Author Rehm-Berbenni, C.; Druta A.; Åberg, G.; Neguer J.; Külls, C.; Patrizi, G.; Pacha, T.; Kienzle, P.; Bugini, R.; Fiore, M.G.
Title Isotope Technologies Applied to the Analysis of Ancient Roman Mortars Type Book Whole
Year (up) 2005 Publication European Commission Abbreviated Journal
Volume Issue Pages
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Abstract Results of the CRAFT Project EVK4 CT-2001-30004
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Notes Approved no
Call Number THL @ christoph.kuells @ Serial 73
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Author Min, M.; Chen, J.; Wang, J.; Wei, G.; Fayek, M.
Title Mineral paragenesis and textures associated with sandstone-hosted roll-front uranium deposits, NW China Type Journal Article
Year (up) 2005 Publication Ore Geology Reviews Abbreviated Journal
Volume 26 Issue 1 Pages 51-69
Keywords China, Mineralogy, Paragenesis, Sandstone-hosted roll-type uranium deposit
Abstract We present a first paragenetic study of the Wuyier, Wuyisan, Wuyiyi and Shihongtan sandstone-hosted roll-front uranium deposits, northwest China. The mineralization is hosted by Lower–Middle Jurassic coarse- to medium-grained sandstones, which are dark-gray to black due to a mixture of ore minerals and carbonaceous debris. The sandstone is alluvial fan-braided river facies. Minerals associated with these deposits can be broadly categorized as detrital, authigenic, and ore-stage mineralization. Ore minerals consist of uraninite and coffinite. This is the first noted occurrence of coffinite in this type of deposit in China. Sulfide minerals associated with the uranium minerals are pyrite, marcasite, and less commonly, sphalerite and galena. The sulfide minerals are largely in textural equilibrium with the uranium minerals. However, these sulfide minerals occasionally appear to predate, as well as postdate, the uranium minerals. This implies that there are multiple generations of sulfides associated with these deposits. The ore minerals occur interstitially between fossilized wood cells in the sandstones as well as replace fossilized wood and biotite. The deposits are generally low-grade. Primary uranium minerals associated with the low-grade deposits are generally too small, ranging from 0.2 to 0.3 μm in diameter, to be observed by optical microscopy and are only observed by electron microscopy. Mineral paragenesis and textures indicate that these deposits formed under low temperature (30–50 °C) conditions.
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Series Editor Series Title Abbreviated Series Title
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ISSN 0169-1368 ISBN Medium
Area Expedition Conference
Notes Approved no
Call Number THL @ christoph.kuells @ min_mineral_2005 Serial 175
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Author Min, M.; Xu, H.; Chen, J.; Fayek, M.
Title Evidence of uranium biomineralization in sandstone-hosted roll-front uranium deposits, northwestern China Type Journal Article
Year (up) 2005 Publication Ore Geology Reviews Abbreviated Journal
Volume 26 Issue 3 Pages 198-206
Keywords Biomineralization, China, Roll-front uranium deposit, Sandstone
Abstract We show evidence that the primary uranium minerals, uraninite and coffinite, from high-grade ore samples (U3O8\textgreater0.3%) in the Wuyiyi, Wuyier, and Wuyisan sandstone-hosted roll-front uranium deposits, Xinjiang, northwestern China were biogenically precipitated and psuedomorphically replace fungi and bacteria. Uranium (VI), which was the sole electron acceptor, was likely to have been enzymically reduced. Post-mortem accumulation of uranium may have also occurred through physio-chemical interaction between uranium and negatively-charged cellular sites, and inorganic adsorption or precipitation reactions. These results suggest that microorganisms may have played a key role in formation of the sandstone- or roll-type uranium deposits, which are among the most economically significant uranium deposits in the world.
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ISSN 0169-1368 ISBN Medium
Area Expedition Conference
Notes Approved no
Call Number THL @ christoph.kuells @ min_evidence_2005 Serial 186
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Author Schwiede, M.; Duijnisveld, W.H.M.; Böttcher, J.
Title Investigation of processes leading to nitrate enrichment in soils in the Kalahari Region, Botswana Type Journal Article
Year (up) 2005 Publication Physics and Chemistry of the Earth, Parts A/B/C Abbreviated Journal
Volume 30 Issue 11 Pages 712-716
Keywords Nitrate, Arenosol soils, Semi-arid, Kalahari, Cattle, Chloride, Travel time
Abstract In Southern Africa elevated nitrate concentrations are observed in mostly uninhabited semi-arid areas. In the Kalahari of Botswana groundwater locally exhibits concentrations up to 600mg/l. It is assumed, that nitrate found in the groundwater originates mainly from nitrogen input and transformations in the soils. Our investigations in the Kalahari between Serowe and Orapa show that cattle raising is an important source for enhanced nitrate concentrations in the soils (Arenosols). But also in termite mounds very high nitrate stocks were found, and under natural vegetation (acacia trees and shrubs) nitrate concentrations were mostly unexpectedly high. This nitrate enrichment in the soils poses a serious threat to the groundwater quality. However, calculated soil water age distributions in the unsaturated zone clearly show that today’s nitrate pollution of the groundwater below the investigation area could originate from natural sources, but cannot be caused by the current land use for cattle raising.
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ISSN 1474-7065 ISBN Medium
Area Expedition Conference
Notes Integrated Water Resources Management (IWRM) and the Millennium Development Goals: Managing Water for Peace and Prosperity Approved no
Call Number THL @ christoph.kuells @ Schwiede2005712 Serial 276
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Author Udluft, P.; Dünkeloh, A.; Mederer, J.; Külls, C.; Schaller, J.
Title Re-evaluation of the groundwater resources of Cyprus Type Report
Year (up) 2006 Publication Abbreviated Journal
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Publisher Lefkosia Place of Publication Editor
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Notes Approved no
Call Number THL @ christoph.kuells @ Udluft2006re Serial 66
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Author Gunkel, A. Külls, C.
Title Towards agent-based modelling of stakeholder behaviour – a pilot study on drought vulnerability of decentral water supply in NE Brazil Type Journal Article
Year (up) 2006 Publication International Congress on Environmental Modelling and Sofware Abbreviated Journal
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Abstract 3rd International Congress on Environmental Modelling and Sofware – Burlington, Vermont
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Notes Approved no
Call Number THL @ christoph.kuells @ Serial 74
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