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Qiu, W.; Yang, Y.; Song, J.; Que, W.; Liu, Z.; Weng, H.; Wu, J.; Wu, J. |
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What chemical reaction dominates the CO2 and O2 in-situ uranium leaching?: Insights from a three-dimensional multicomponent reactive transport model at the field scale |
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Year |
2023 |
Publication |
Applied Geochemistry |
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148 |
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105522 |
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Keywords |
Carbonate minerals, In-situ leaching (ISL) of uranium, Pyrite oxidation, Reactive transport modeling (RTM) |
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Abstract |
The complex behavior of uranium in recovery is mostly driven by water-rock interactions following lixiviant injection into ore-bearing aquifers. Significant challenges exist in exploring the geochemical processes responsible for uranium release and mobilization. Herein this study provides an illustration of a ten-year field scale CO2 and O2 in-situ leaching (ISL) process at a typical sandstone-hosted uranium deposit in northern China. We also conducte a three-dimensional (3-D) multicomponent reactive transport model to assess the effects of potential chemical reactions on uranium recovery, in particular, to focus on the role of sulfide mineral pyrite (FeS2). Numerical simulations are performed considering three potential ISL reaction pathways to determine the relative contributions to uranium release, and the results indicate that bicarbonate promotes the oxidative dissolution of uranium-bearing minerals and further accelerates the uranium leaching in a neutral geochemical system. Moreover, the presence of FeS2 exerts a strong competitive role in the uranium-bearing mineral dissolution by increasing oxygen consumption, favoring the formation of iron oxyhydroxide, and therefore causing an associated decrease in uranium recovery rates. The simulation model demonstrates that dissolution of carbonate neutralizes acidic water generated from pyrite oxidation and aqueous CO2 dissociation. In addition, the cation concentrations (i.e., Ca and Mg) are increasing in the pregnant solutions, showing that the recycling of lixiviants and kinetic dissolution of carbonate generates a larger number of dissolved Ca and Mg and inevitably triggers the secondary dolomite mineral precipitation. The findings improve our fundamental understanding of the geochemical processes in a long-term uranium ISL system and provide important environmental implications for the optimal design of uranium recovery, remediation, and risk exposure assessment. |
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0883-2927 |
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THL @ christoph.kuells @ qiu_what_2023 |
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207 |
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YI, Z.-ji; LIAN, B.; YANG, Y.-qun; ZOU, J.-ling |
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Title |
Treatment of simulated wastewater from in situ leaching uranium mining by zerovalent iron and sulfate reducing bacteria |
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Journal Article |
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2009 |
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Transactions of Nonferrous Metals Society of China |
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19 |
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840 |
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basification, sulfate, sulfate reducing bacteria (SRB), uranium, wastewater, zerovalent iron (ZVI) |
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Batch and column experiments were conducted to determine whether zerovalent iron (ZVI) and sulfate reducing bacteria (SRB) can function synergistically and accelerate pollutant removal. Batch experiments suggest that combining ZVI with SRB can enhance the removal of U(?) synergistically. The removal rate of U(?) in the ZVI+SRB combining system is obviously higher than the total rate of ZVI system and SRB system with a difference of 13.4% at t=2 h and 29.9% at t=4 h. Column experiments indicate that the reactor filled with both ZVI and SRB biofilms is of better performance than the SRB bioreactor in wastewater basification, desulfurization and U(?) fixation. The results imply that the ZVI+SRB permeable reactive barrier may be a promising method for treating subsurface uranium contamination. |
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1003-6326 |
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THL @ christoph.kuells @ yi_treatment_2009 |
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206 |
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