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Wang, B.; Luo, Y.; Liu, J.-hui; Li, X.; Zheng, Z.-hong; Chen, Q.-qian; Li, L.-yao; Wu, H.; Fan, Q.-ren |
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Title |
Ion migration in in-situ leaching (ISL) of uranium: Field trial and reactive transport modelling |
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Journal Article |
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Year |
2022 |
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Journal of Hydrology |
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615 |
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128634 |
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Acid in situ leaching, Banyan-Uul uranium deposit, Influence area, Reactive transport, Sensitivity analysis |
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Abstract |
Acid in-situ leaching (ISL) can be used as a mining technique for in situ uranium recover from underground. Acids and oxidants as lixiviants were continuously injected into a sandstone-type uranium deposit in Bayan-Uul (China). It was conducted to facilitate the dissolution of uranium minerals to generate uranyl ions, which could then be extracted for the recovery of uranium resources by the pumping cycle. A reactive transport model based on PHAST was developed to investigate the dynamic reactive migration process of uranium. The simulated results well reproduce the fluid dynamic evolution in the injecting and pumping units, as well as the dynamic release of uranium. The simulated leaching area indicates that the uranium ore leaching area was much larger than the acidification area. In addition, the pollution plume of uranium and acid water was larger than that of the leaching area, which can be used as a reference for uranium mining schemes. Furthermore, the parameter sensitivity analysis indicates the volume fraction of uranium ore and the reaction rate were the main factors affecting uranium leaching efficiency. Without considering the blockage of pores by precipitation, the Fe2+ in the reinjection fluid had a significant negative influence on uranium leaching. |
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0022-1694 |
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THL @ christoph.kuells @ wang_ion_2022 |
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195 |
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Wang, B.; Luo, Y.; Qian, J.-zhong; Liu, J.-hui; Li, X.; Zhang, Y.-hong; Chen, Q.-qian; Li, L.-yao; Liang, D.-ye; Huang, J. |
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Title |
Machine learning–based optimal design of the in-situ leaching process parameter (ISLPP) for the acid in-situ leaching of uranium |
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Journal Article |
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Year |
2023 |
Publication |
Journal of Hydrology |
Abbreviated Journal |
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626 |
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130234 |
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Keywords |
In-situ leaching, Injection rate design, Lixiviant concentration design, Machine learning, Simulation-optimisation, Uncertainty |
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Abstract |
The migration process of leached uranium in the in-situ leaching of uranium is considered a typical reactive transport problem. During this process, the lixiviant concentration and injection rate are important in-situ leaching process parameters (ISLPP) to efficiently recover uranium. However, several uncertain factors affect the outcomes of the ISLPP design. In addition, the repeated use of the reactive transport model (RTM) for investigating the acid in-situ leaching of uranium with the application of the Monte Carlo method leads to a substantial computational load. For this reason, a machine learning (ML)–based surrogate model was developed with the backpropagation neural network (BPNN) method to replace the RTM under the condition of uncertain parameters. Moreover, the simulated annealing optimisation model for ISLPP was created based on the proposed surrogate model. The optimal ISLPP was achieved that generated maximum profits from uranium recovery under different lixiviant prices, uranium prices and exploitation times. The optimal design framework of ISLPP based on the proposed ML algorithm was then applied in the Bayan-Uul sandstone-type uranium deposit in Inner Mongolia, China. From our analysis, it was demonstrated that the ML-based surrogate model exhibited great fitness with the RTM. The optimal results of the ISLPP indicated that the lixiviant concentration and injection rate could be adjusted based on the fluctuations in lixiviant price, uranium price and exploitation time. If the prices of sulphuric acid were high, a specific concentration of hydrogen peroxide could be injected into the injection well to promote the oxidation and dissolution of the uranium ore to increase the income from the uranium recovery. The optimisation model can also use the ISLPP scheme to boost the revenues from different lixiviant prices, uranium prices and exploitation times under the uncertainty of porosity, illustrating the applicability of the ML-based optimal design method of ISLPP in ISL mining. A general framework for developing surrogate models, as well as for conducting uncertainty analyses for a wide range of groundwater models was proposed here yielding valuable insights. |
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0022-1694 |
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THL @ christoph.kuells @ wang_machine_2023 |
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210 |
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Gil-Márquez, J.M.; Sültenfuß, J.; Andreo, B.; Mudarra, M. |
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Groundwater dating tools (3H, 3He, 4He, CFC-12, SF6) coupled with hydrochemistry to evaluate the hydrogeological functioning of complex evaporite-karst settings |
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Journal Article |
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2020 |
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Journal of Hydrology |
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580 |
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124263 |
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Groundwater dating, Evaporite karst, Brine spring, Free-shape models |
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The hydrogeological functioning of four different areas in a complex evaporite-karst unit of predominantly aquitard behavior in S Spain was investigated. Environmental dating tracers (3H, 3He, 4He, CFC-12, SF6) and hydrochemical data were determined from spring samples to identify and characterize groundwater flow components of different residence times in the media. Results show a general geochemical evolution pattern, from higher (recharge areas) to lower positions (discharge areas), in which mineralization rises as well as the value of the rCl−/SO42−, evidencing longer water-rock interaction. Ne values show degassing of most of the samples, favored by the high salinity of groundwater and the development of karstification so that the concentration of all the considered gases were corrected according to the difference between the theoretical and the measured Ne. The presence of modern groundwater in every sample was proved by the detection of 3H and CFC-12. At the opposite, the higher amount of radiogenic 4He in most samples also indicates that they have an old component. The 3H/3He dating method does not give reliable ages as a consequence of degassing and the large uncertainty of the 3He/4He ratios of the sources for the radiogenic Helium. The large SF6 concentrations suggest terrigenic production related to halite and dolomite. Binary Mixing and Free Shape Models were created based on 3H and CFC-12 data to interpret the age distribution of the samples. Two parameters (GA50 and >70%) were proposed as an indicator of that distribution, as they provide further information than the mean age. Particularly, GA50 is derived from the median groundwater age and is presented as a new way of interpreting mixed groundwater age data. A greater fraction of old groundwater (3H and CFC-12 free) was identified in discharge areas, while the proportion and estimated infiltration date of the younger fractions in recharge areas were higher and more recent, respectively. The application of different approaches has been useful to corroborate previous theoretical conceptual model proposed for the study area and to test the applicability of the used environmental tracer in dating brine groundwater and karst springs. |
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0022-1694 |
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THL @ christoph.kuells @ Gilmarquez2020124263 |
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213 |
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Musy, S.; Meyzonnat, G.; Barbecot, F.; Hunkeler, D.; Sültenfuss, J.; Solomon, D.K.; Purtschert, R. |
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In-situ sampling for krypton-85 groundwater dating |
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Journal Article |
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2021 |
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Journal of Hydrology X |
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11 |
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100075 |
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Noble gases, Tracers, Groundwater, Dating, Sampling Methodology |
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Krypton-85 and other radioactive noble gases are widely used for groundwater dating purposes. 85Kr analysis require large volumes of water to reach the analytical requirements. Conventionally, this water is pumped to the surface to be degassed with a gas extraction system. The large pumping rate may disturb the natural flow field and requires substantial field logistics. Hence, we propose a new in-situ degassing method, in which membrane contactors are used to degas the groundwater directly in the well and gas is collected at the surface. This way, field work is facilitated, groundwater system disturbance is minimized, and the gas sample is collected at a specific depth. We demonstrate the tightness of the system regarding atmospheric air contamination for a collection times of 24 h, which is sufficient for both low-level counting and laser-based counting methods for 85Kr. The minimal borehole diameter is 7.5 cm for the prototype presented in this research but can easily be reduced to smaller diameters. In a case study, we compare the results obtained with the new passive method with those from a conventional packer setup sampling. Additionally, 3H/3He samples were collected for both sampling regimes and the dating results were compared with those from 85Kr. A good agreement between tracer ages is demonstrated and the age stratigraphy is consistent with the expected age distribution for a porous unconfined aquifer. In addition, our study emphasizes the differences between the age information sampled with various methods. In conclusion, we demonstrate that the new in situ quasi-passive method provides a more representative age stratigraphy with depth in most cases. |
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2589-9155 |
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THL @ christoph.kuells @ Musy2021100075 |
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215 |
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Rusli, S.R.; Weerts, A.H.; Mustafa, S.M.T.; Irawan, D.E.; Taufiq, A.; Bense, V.F. |
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Quantifying aquifer interaction using numerical groundwater flow model evaluated by environmental water tracer data: Application to the data-scarce area of the Bandung groundwater basin, West Java, Indonesia |
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Journal Article |
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2023 |
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Journal of Hydrology: Regional Studies |
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50 |
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101585 |
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Aquifer interaction, Multi-layer groundwater abstraction, Environmental water tracers, Groundwater flow model, Bandung groundwater basin |
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Study Region: Bandung groundwater basin, Indonesia. Study focus: Groundwater abstraction of various magnitudes, pumped out from numerous depths in a multitude of layers of aquifers, stimulates different changes in hydraulic head distribution, including ones under vertical cross-sections. This generates groundwater flow in the vertical direction, where groundwater flows within its storage from the shallow to the underlying confined aquifers. In the Bandung groundwater basin, previous studies have identified such processes, but quantitative evaluations have never been conducted, with data scarcity mainly standing as one of the major challenges. In this study, we utilize the collated (1) environmental water tracer data, including major ion elements (Na+/K+, Ca2＋, Mg2+, Cl−, SO42−,HCO3−), stable isotope data (2H and δ18O), and groundwater age determination (14C), in conjunction with (2) groundwater flow modeling to quantify the aquifer interaction, driven mainly by the multi-layer groundwater abstraction in the Bandung groundwater basin, and demonstrate their correspondence. In addition, we also use the model to quantify the impact of multi-layer groundwater abstraction on the spatial distribution of the groundwater level changes. New hydrological insights for the region: In response to the limited calibration data availability, we expand the typical model calibration that makes use of the groundwater level observations, with in-situ measurement and a novel qualitative approach using the collated environmental water tracers (EWT) data for the model evaluation. The analysis in the study area using EWT data and quantitative methods of numerical groundwater flow modeling is found to collaborate with each other. Both methods show agreement in their assessment of (1) the groundwater recharge spatial distribution, (2) the regional groundwater flow direction, (3) the groundwater age estimates, and (4) the identification of aquifer interaction. On average, the downwelling to the deeper aquifer is quantified at 0.110 m/year, which stands out as a significant component compared to other groundwater fluxes in the system. We also determine the unconfined aquifer storage volume decrease, calculated from the change in the groundwater table, resulting in an average declining rate of 51 Mm3/year. This number shows that the upper aquifer storage is dwindling at a rate disproportionate to its groundwater abstraction, hugely influenced by losses to the deeper aquifer. The outflow to the deeper aquifer contributes to 60.3% of the total groundwater storage lost, despite representing only 32.3% of the total groundwater abstraction. This study shows the possibility of quantification of aquifer interaction and groundwater level change dynamics driven by multi-layer groundwater abstraction in a multi-layer hydrogeological setting, even in a data-scarce environment. Applying such methods can assist in deriving basin-scale groundwater policies and management strategies under the changing anthropogenic and climatic factors, thereby ensuring sustainable groundwater management. |
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2214-5818 |
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THL @ christoph.kuells @ Rusli2023101585 |
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222 |
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