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Li, X.; Shen, K.; Li, Q.; Deng, Y.; Zhu, P.; Wang, D. |
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Title |
Roll-over behavior in current-voltage curve introduced by an energy barrier at the front contact in thin film CdTe solar cell |
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Journal Article |
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2018 |
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Solar Energy |
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165 |
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27-34 |
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AlO HRT layer, Band alignment, CdTe solar cell, Roll-over behavior |
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Abstract |
Roll-over phenomenon in the current–voltage (J–V) curve is often observed in a CdTe thin film solar cell. The roll-over phenomenon, which is occurred near the open-circuit voltage in a light J–V curve, is due to Schottky energy barrier formed at the CdTe/metal interface in a CdTe solar cell back contact. In this study we report a J–V roll-over phenomenon which is induced by an energy barrier at the front contact of a CdTe solar cell. Two kinds of oxides, namely, Al2O3 and SnO2, were deposited as high-resistance transparent (HRT) layer between the window layer CdS and the fluorine doped tin oxide (FTO) front electrode in CdTe solar cells. These two oxides present much different electronic band alignment with FTO and CdS. SnO2 formed almost no energy barrier with CdS, this allowed smooth transport for photo-generated electrons from CdTe to CdS and FTO. However, Al2O3 formed a high energy barrier with CdS. The rather high energy barrier with a value of 3.43 eV at the CdS/Al2O3 interface induced a J–V roll-over phenomenon in a CdTe thin film solar cell, which dramatically led to a quick decrease for the cell device efficiency. The electron transport at the FTO/Al2O3/CdS interface is governed by tunneling effect. The results presented in this study demonstrate that the band structure at the front electrode plays an important role for the performance of a CdTe thin film solar cell. |
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0038-092x |
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THL @ christoph.kuells @ li_roll-over_2018 |
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187 |
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Liesch, T.; Hinrichsen, S.; Goldscheider, N. |
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Title |
Uranium in groundwater — Fertilizers versus geogenic sources |
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Journal Article |
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2015 |
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Science of The Total Environment |
Abbreviated Journal |
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536 |
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981-995 |
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Drinking water, Fertilizer, Geogenic background, Groundwater, Uranium |
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Due to its radiological and toxicological properties even at low concentration levels, uranium is increasingly recognized as relevant contaminant in drinking water from aquifers. Uranium originates from different sources, including natural or geogenic, mining and industrial activities, and fertilizers in agriculture. The goal of this study was to obtain insights into the origin of uranium in groundwater while differentiating between geogenic sources and fertilizers. A literature review concerning the sources and geochemical processes affecting the occurrence and distribution of uranium in the lithosphere, pedosphere and hydrosphere provided the background for the evaluation of data on uranium in groundwater at regional scale. The state of Baden-Württemberg, Germany, was selected for this study, because of its hydrogeological and land-use diversity, and for reasons of data availability. Uranium and other parameters from N=1935 groundwater monitoring sites were analyzed statistically and geospatially. Results show that (i) 1.6% of all water samples exceed the German legal limit for drinking water (10μg/L); (ii) The range and spatial distribution of uranium and occasional peak values seem to be related to geogenic sources; (iii) There is a clear relation between agricultural land-use and low-level uranium concentrations, indicating that fertilizers generate a measurable but low background of uranium in groundwater. |
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0048-9697 |
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THL @ christoph.kuells @ liesch_uranium_2015 |
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145 |
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Lightfoot, D.R. |
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Moroccan khettara: Traditional irrigation and progressive desiccation |
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1996 |
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Geoforum |
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27 |
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2 |
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261-273 |
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A 300 km network of khettara (qanat) subsurface irrigation channels was excavated in the Tafilalt basin beginning in the late 14th century. More than 75 of these chains provided perennial water following the breakup of the ancient city of Sijilmassa. Khettara continued to function for much of the northern oasis until the early 1970s, when new technologies and government policies forced changes. Data on origins, maintenance, and current use were collected from archival sources, aerial photographs, Landsat imagery, and from interviews. Insufficient water resources and unsustainable practices have dramatically lowered the water table, drying up khettara. This has resulted in a loss of local control over water resources, abandonment of a sustainable irrigation system, and progressive desiccation. |
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0016-7185 |
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THL @ christoph.kuells @ Lightfoot1996261 |
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257 |
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Lim, S.; Chase, B.M.; Chevalier, M.; Reimer, P.J. |
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50,000years of vegetation and climate change in the southern Namib Desert, Pella, South Africa |
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Journal Article |
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2016 |
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Palaeogeography, Palaeoclimatology, Palaeoecology |
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451 |
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197-209 |
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Climate reconstruction, Late Quaternary, Namib Desert, Pollen, Rock hyrax middens, South Africa |
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This paper presents the first continuous pollen record from the southern Namib Desert spanning the last 50,000years. Obtained from rock hyrax middens found near the town of Pella, South Africa, these data are used to reconstruct vegetation change and quantitative estimates of temperature and aridity. Results indicate that the last glacial period was characterised by increased water availability at the site relative to the Holocene. Changes in temperature and potential evapotranspiration appear to have played a significant role in determining the hydrologic balance. The record can be considered in two sections: 1) the last glacial period, when low temperatures favoured the development of more mesic Nama-Karoo vegetation at the site, with periods of increased humidity concurrent with increased coastal upwelling, both responding to lower global/regional temperatures; and 2) the Holocene, during which time high temperatures and potential evapotranspiration resulted in increased aridity and an expansion of the Desert Biome. During this latter period, increases in upwelling intensity created drier conditions at the site. Considered in the context of discussions of forcing mechanisms of regional climate change and environmental dynamics, the results from Pella stand in clear contrast with many inferences of terrestrial environmental change derived from regional marine records. Observations of a strong precessional signal and interpretations of increased humidity during phases of high local summer insolation in the marine records are not consistent with the data from Pella. Similarly, while high percentages of Restionaceae pollen has been observed in marine sediments during the last glacial period, they do not exceed 1% of the assemblage from Pella, indicating that no significant expansion of the Fynbos Biome has occurred during the last 50,000years. These findings pose interesting questions regarding the nature of environmental change in southwestern Africa, and the significance of the diverse records that have been obtained from the region. |
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0031-0182 |
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THL @ christoph.kuells @ lim_50000years_2016 |
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107 |
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Lima, G.F.C.; Filho, C.A. de C.; Ferreira, V.G.; Lima, J. da S.D.; Marques, E.D.; Minardi, P.S.P.; Dalmázio, I.; Moreira, R.M. |
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Establishing a water baseline for the unconventional gas industry: A multiple environmental isotopes assessment (18O, 2H, 3H, 13C, and 14C) of surface and groundwater in the São Francisco Basin, Brazil |
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Journal Article |
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2023 |
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Applied Geochemistry |
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159 |
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105818 |
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Fracking, Groundwater dating, Indaiá river, Isotopes assessment, Shale gas, Unconventional hydrocarbons |
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Unconventional hydrocarbon production has become the target of an intensive environmental debate due to the risks it poses to water resources. Fracking, while enabling the extraction of oil and gas from ultra-low permeability reservoirs, also possesses the risk of polluting water systems through failures from hydraulic fracturing and its associated procedures. The need to foster national industrial development with a transitional energy matrix has led Brazil to discuss the environmental suitability before producing its large unconventional reserves. Many studies have highlighted the need for a robust environmental characterization before the development of the unconventional industry. In this sense, multiple environmental isotopes may work as a proxy for identifying water contamination right from the early stages. Environmental isotopes may also be applied to enhance the understanding of the natural geochemical processes intrinsic to a given area. This study presents an environmental isotopes baseline for the groundwater and riverine water systems within the São Francisco Basin, a proven tight gas reservoir in Brazil, in a pre-operational context. δ18O, δ2H, 3H, δ13C, and Δ14C were evaluated in three different seasons in groundwater and surface water samples, along with other auxiliary parameters such as physical-chemical parameters (in situ), major ions, and d-excess. The δ2H and δ18O in surface water shows an upstream → downstream enrichment trend, with some variations suggesting baseflow interactions in the surface water systems. An evaporation line for the study area was defined as δ2H = 4.6903 δ18O + 10.362. δ13C indicates a mutual dissolution of silicates and carbonates in the groundwater system and suggests a group of samples highly related to the recharge areas. Groundwater dating denotes the Serra da Saudade Formation as a modern fractured aquifer with a strong recharge capacity. These findings support stakeholders in environmental monitoring and management of the unconventional gas industry. |
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0883-2927 |
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THL @ christoph.kuells @ lima_establishing_2023 |
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173 |
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