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Author Aderemi, B.A.; Olwal, T.O.; Ndambuki, J.M.; Rwanga, S.S. url  openurl
  Title Groundwater levels forecasting using machine learning models: A case study of the groundwater region 10 at Karst Belt, South Africa Type Journal Article
  Year 2023 Publication Systems and Soft Computing Abbreviated Journal  
  Volume 5 Issue Pages (down) 200049  
  Keywords Artificial intelligence, Forecasting model, Groundwater levels, Machine learning, Neural networks, Rainfall, Regression, Temperature, Time series  
  Abstract The crucial role which groundwater resource plays in our environment and the overall well-being of all living things can not be underestimated. Nonetheless, mismanagement of resources, over-exploitation, inadequate supply of surface water and pollution have led to severe drought and an overall drop in groundwater resources’ levels over the past decades. To address this, a groundwater flow model and several mathematical data-driven models have been developed for forecasting groundwater levels. However, there is a problem of unavailability and scarcity of the on-site input data needed by the data-driven models to forecast the groundwater level. Furthermore, as a result of the dynamics and stochastic characteristics of groundwater, there is a need for an appropriate, accurate and reliable forecasting model to solve these challenges. Over the years, the broad application of Machine Learning (ML) and Artificial Intelligence (AI) models are gaining attraction as an alternative solution for forecasting groundwater levels. Against this background, this article provides an overview of forecasting methods for predicting groundwater levels. Also, this article uses ML models such as Regressions Models, Deep Auto-Regressive models, and Nonlinear Autoregressive Neural Networks with External Input (NARX) to forecast groundwater levels using the groundwater region 10 at Karst belt in South Africa as a case study. This was done using Python Mx. Version 1.9.1., and MATLAB R2022a machine learning toolboxes. Moreover, the Coefficient of Determination (R2);, Root Mean Square Error (RMSE), Mutual Information gain, Mean Absolute Percentage Error (MAPE), Mean Squared Error (MSE), Mean Absolute Error (MAE), and the Mean Absolute Scaled Error (MASE)) models were the forecasting statistical performance metrics used to assess the predictive performance of these models. The results obtained showed that NARX and Support Vector Machine (SVM) have higher performance metrics and accuracy compared to other models used in this study.  
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  ISSN 2772-9419 ISBN Medium  
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  Notes Approved no  
  Call Number THL @ christoph.kuells @ Aderemi2023200049 Serial 219  
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Author Pham, H.C.; Alila, Y. url  openurl
  Title Science of forests and floods: The quantum leap forward needed, literally and metaphorically Type Journal Article
  Year 2024 Publication Science of The Total Environment Abbreviated Journal  
  Volume 912 Issue Pages (down) 169646  
  Keywords Hydrological causality, Extreme value analyses, Land use impact, Peakflows, Extreme events epistemology, Experimental design  
  Abstract A century of research has generated considerable disagreement on the effect of forests on floods. Here we call for a causal inference framework to advance the science and management of the effect of any forest or its removal on flood severity and frequency. The causes of floods are multiple and chancy and, hence, can only be investigated via a probabilistic approach. We use the stochastic hydrology literature to infer a blueprint framework which could guide future research on the understanding and prediction of the effects of forests on floods in environments where rain is the dominant form of precipitation. Drawing parallels from other disciplines, we show that the introduction of probability in forest hydrology could stimulate a gestalt switch in the science of forests and floods. In light of increasing flood risk caused by climate change, this probabilistic framework can help policymakers develop robust forest and water management plans based on a defensible and clear understanding of floods.  
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  ISSN 0048-9697 ISBN Medium  
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  Notes Approved no  
  Call Number THL @ christoph.kuells @ Pham2024169646 Serial 244  
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Author Tisherman, R.A.; Rossi, R.J.; Shonkoff, S.B.C.; DiGiulio, D.C. url  openurl
  Title Groundwater uranium contamination from produced water disposal to unlined ponds in the San Joaquin Valley Type Journal Article
  Year 2023 Publication Science of The Total Environment Abbreviated Journal  
  Volume 904 Issue Pages (down) 166937  
  Keywords Groundwater, Oil & gas, Produced water, San Joaquin Valley, Uranium  
  Abstract In the southern San Joaquin Valley (SJV) of California, an agriculturally productive region that relies on groundwater for irrigation and domestic water supply, the infiltration of produced water from oil reservoirs is known to impact groundwater due to percolation from unlined disposal ponds. However, previously documented impacts almost exclusively focus on salinity, while contaminant loadings commonly associated with produced water (e.g., radionuclides) are poorly constrained. For example, the infiltration of bicarbonate-rich produced waters can react with sediment-bound uranium (U), leading to U mobilization and subsequent transport to nearby groundwater. Specifically, produced water infiltration poses a particular concern for SJV groundwater, as valley-fill sediments are well documented to be enriched in geogenic, reduced U. Here, we analyzed monitoring well data from two SJV produced water pond facilities to characterize U mobilization and subsequent groundwater contamination. Groundwater wells installed within 2 km of the facilities contained produced water and elevated levels of uranium. There are \textgreater400 produced water disposal pond facilities in the southern SJV. If our observations occur at even a fraction of these facilities, there is the potential for widespread U contamination in the groundwaters of one of the most productive agricultural regions in the world.  
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  Call Number THL @ christoph.kuells @ tisherman_groundwater_2023 Serial 159  
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Author Musy, S.; Purtschert, R. url  openurl
  Title Reviewing 39Ar and 37Ar underground production in shallow depths with implications for groundwater dating Type Journal Article
  Year 2023 Publication Science of The Total Environment Abbreviated Journal  
  Volume 884 Issue Pages (down) 163868  
  Keywords Subsurface production, Argon-39, Argon-37, Muons, Isotope hydrology, Tracers  
  Abstract Argon-37 (37Ar) and Argon-39 (39Ar) are used for groundwater dating on timescales from weeks to centuries. For both isotopes, the quantification of underground sources is essential to accurately infer water residence times from sampled dissolved activities. Subsurface production resulting from interactions with neutrons from the natural radioactivity in rocks and with primary cosmogenic neutrons has been known for a long time. More recently, the capture of slow negative muons and reactions with muon-induced neutrons were documented for 39Ar subsurface production in the context of underground particle detectors (e.g. for Dark Matter research). However, the contribution from these particles was never considered for groundwater dating applications. Here, we reevaluate the importance of all potential depth-related production channels at depth ranges relevant for 39Ar groundwater dating [0 − 200 meters below the surface (m.b.s)]. The production of radioargon by muon-induced processes is considered in this depth range for the first time. The uncertainty on the total depth-dependent production rate is estimated with Monte Carlo simulations assuming a uniform distribution of the parameter uncertainties. This work aims to provide a comprehensive framework for interpreting 39Ar activities in terms of groundwater residence times and for exposure age dating of rocks. The production of 37Ar is also addressed since this isotope is relevant as a proxy for 39Ar production, for the timing of river-groundwater exchanges, and in the context of on-site inspections (OSI) within the verification framework of the Comprehensive Nuclear-Test-Ban Treaty (CTBT). In this perspective, we provide an interactive web-based application for the calculation of 37Ar and 39Ar production rates in rocks.  
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  Call Number THL @ christoph.kuells @ Musy2023163868 Serial 217  
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Author Liu, Z.; Li, C.; Tan, K.; Li, Y.; Tan, W.; Li, X.; Zhang, C.; Meng, S.; Liu, L. url  openurl
  Title Study of natural attenuation after acid in situ leaching of uranium mines using isotope fractionation and geochemical data Type Journal Article
  Year 2023 Publication Science of The Total Environment Abbreviated Journal  
  Volume 865 Issue Pages (down) 161033  
  Keywords Acid in situ leaching, Geochemical and isotopic tracing, Groundwater contamination, Natural attenuation, Uranium post-mining  
  Abstract Acid in situ leaching (AISL) is a subsurface mining approach suitable for low-grade ores which does not generate tailings, and has been adopted widely in uranium mining. However, this technique causes an extremely high concentration of contaminants at post-mining sites and in the surroundings soon after the mining ceases. As a potential AISL remediation strategy, natural attenuation has not been studied in detail. To address this problem, groundwater collected from 26 wells located within, adjacent, upgradient, and downgradient of a post-mining site were chosen to analyze the fate of U(VI), SO42−, δ34S, and δ238U, to reveal the main mechanisms governing the migration and attenuation of the dominant contaminants and the spatio-temporal evolutions of contaminants in the confined aquifer of the post-mining site. The δ238U values vary from −0.07 ‰ to 0.09 ‰ in the post-mining site and from −1.43 ‰ to 0.03 ‰ around the post-mining site. The δ34S values were found to vary from 3.3 ‰ to 6.2 ‰ in the post-mining site and from 6.0 ‰ to 11.0 ‰ around the post-mining site. Detailed analysis suggests that there are large differences between the range of isotopic composition variation and the range of pollutants concentration distribution, and the estimated Rayleigh isotope fractionation factor is 0.9994–0.9997 for uranium and 1.0032–1.0061 for sulfur. The isotope ratio of uranium and sulfur can be used to deduce the migration history of the contaminants and the irreversibility of the natural attenuation process in the anoxic confined aquifer. Combining the isotopic fractionation data for U and S with the concentrations of uranium and sulfate improved the accuracy of understanding of reducing conditions along the flow path. The study also indicated that as long as the geological conditions are favorable for redox reactions, natural attenuation could be used as a cost-effective remediation scheme.  
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  Notes Approved no  
  Call Number THL @ christoph.kuells @ liu_study_2023 Serial 155  
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