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| Author |
Lawrinenko, M.; Kurwadkar, S.; Wilkin, R.T. |
| Title |
Long-term performance evaluation of zero-valent iron amended permeable reactive barriers for groundwater remediation – A mechanistic approach |
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Journal Article |
| Year |
2023 |
Publication |
Geoscience Frontiers |
Abbreviated Journal |
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| Volume |
14 |
Issue  |
2 |
Pages |
101494 |
| Keywords |
Geochemistry, Iron, Permeable reactive barrier, Plating reactions, Reduction potential, Surface passivation |
| Abstract |
Permeable reactive barriers (PRBs) are used for groundwater remediation at contaminated sites worldwide. This technology has been efficient at appropriate sites for treating organic and inorganic contaminants using zero-valent iron (ZVI) as a reductant and as a reactive material. Continued development of the technology over the years suggests that a robust understanding of PRB performance and the mechanisms involved is still lacking. Conflicting information in the scientific literature downplays the critical role of ZVI corrosion in the remediation of various organic and inorganic pollutants. Additionally, there is a lack of information on how different mechanisms act in tandem to affect ZVI-groundwater systems through time. In this review paper, we describe the underlying mechanisms of PRB performance and remove isolated misconceptions. We discuss the primary mechanisms of ZVI transformation and aging in PRBs and the role of iron corrosion products. We review numerous sites to reinforce our understanding of the interactions between groundwater contaminants and ZVI and the authigenic minerals that form within PRBs. Our findings show that ZVI corrosion products and mineral precipitates play critical roles in the long-term performance of PRBs by influencing the reactivity of ZVI. Pore occlusion by mineral precipitates occurs at the influent side of PRBs and is enhanced by dissolved oxygen and groundwater rich in dissolved solids and high alkalinity, which negatively impacts hydraulic conductivity, allowing contaminants to potentially bypass the treatment zone. Further development of site characterization tools and models is needed to support effective PRB designs for groundwater remediation. |
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1674-9871 |
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THL @ christoph.kuells @ lawrinenko_long-term_2023 |
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143 |
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Zeng, S.; Song, J.; Sun, B.; Wang, F.; Ye, W.; Shen, Y.; Li, H. |
| Title |
Seepage characteristics of the leaching solution during in situ leaching of uranium |
Type |
Journal Article |
| Year |
2023 |
Publication |
Nuclear Engineering and Technology |
Abbreviated Journal |
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| Volume |
55 |
Issue |
2 |
Pages |
566-574 |
| Keywords |
In situ leaching, Leaching solution viscosity, Seepage characteristics, Seepage pressure, Uranium-bearing sandstone |
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Investigating the seepage characteristics of the leaching solution in the ore-bearing layer during the in situ leaching process can be useful for designing the process parameters for the uranium mining well. We prepared leaching solutions of four different viscosities and conducted experiments using a self-developed multifunctional uranium ore seepage test device. The effects of different viscosities of leaching solutions on the seepage characteristics of uranium-bearing sandstones were examined using seepage mechanics, physicochemical seepage theory, and dissolution erosion mechanism. Results indicated that while the seepage characteristics of various viscosities of leaching solutions were the same in rock samples with similar internal pore architectures, there were regular differences between the saturated and the unsaturated stages. In addition, the time required for the specimen to reach saturation varied with the viscosity of the leaching solution. The higher the viscosity of the solution, the slower the seepage flow from the unsaturated stage to the saturated stage. Furthermore, during the saturation stage, the seepage pressure of a leaching solution with a high viscosity was greater than that of a leaching solution with a low viscosity. However, the permeability coefficient of the high viscosity leaching solution was less than that of a low viscosity leaching solution. |
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1738-5733 |
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THL @ christoph.kuells @ zeng_seepage_2023 |
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211 |
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Akter, A.; Tanim, A.H.; Islam, M.K. |
| Title |
Possibilities of urban flood reduction through distributed-scale rainwater harvesting |
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Journal Article |
| Year |
2020 |
Publication |
Water Science and Engineering |
Abbreviated Journal |
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13 |
Issue |
2 |
Pages |
95-105 |
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Low-impact development (LID), SWMM, HEC-RAS, Remote sensing, Urban flooding, Inundation depth |
| Abstract |
Urban flooding in Chittagong City usually occurs during the monsoon season and a rainwater harvesting (RWH) system can be used as a remedial measure. This study examines the feasibility of rain barrel RWH system at a distributed scale within an urbanized area located in the northwestern part of Chittagong City that experiences flash flooding on a regular basis. For flood modeling, the storm water management model (SWMM) was employed with rain barrel low-impact development (LID) as a flood reduction measure. The Hydrologic Engineering Center’s River Analysis System (HEC-RAS) inundation model was coupled with SWMM to observe the detailed and spatial extent of flood reduction. Compared to SWMM simulated floods, the simulated inundation depth using remote sensing data and the HEC-RAS showed a reasonable match, i.e., the correlation coefficients were found to be 0.70 and 0.98, respectively. Finally, using LID, i.e., RWH, a reduction of 28.66% could be achieved for reducing flood extent. Moreover, the study showed that 10%–60% imperviousness of the subcatchment area can yield a monthly RWH potential of 0.04–0.45 m3 from a square meter of rooftop area. The model can be used for necessary decision making for flood reduction and to establish a distributed RWH system in the study area. |
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1674-2370 |
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THL @ christoph.kuells @ Akter202095 |
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247 |
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| Author |
Lightfoot, D.R. |
| Title |
Moroccan khettara: Traditional irrigation and progressive desiccation |
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Journal Article |
| Year |
1996 |
Publication |
Geoforum |
Abbreviated Journal |
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| Volume |
27 |
Issue |
2 |
Pages |
261-273 |
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A 300 km network of khettara (qanat) subsurface irrigation channels was excavated in the Tafilalt basin beginning in the late 14th century. More than 75 of these chains provided perennial water following the breakup of the ancient city of Sijilmassa. Khettara continued to function for much of the northern oasis until the early 1970s, when new technologies and government policies forced changes. Data on origins, maintenance, and current use were collected from archival sources, aerial photographs, Landsat imagery, and from interviews. Insufficient water resources and unsustainable practices have dramatically lowered the water table, drying up khettara. This has resulted in a loss of local control over water resources, abandonment of a sustainable irrigation system, and progressive desiccation. |
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0016-7185 |
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THL @ christoph.kuells @ Lightfoot1996261 |
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257 |
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Ubierna, J.A.J. |
| Title |
Tunnel heritage in Spain: Roots of the underground |
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Journal Article |
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1998 |
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Tunnelling and Underground Space Technology |
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13 |
Issue |
2 |
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131-141 |
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Spain has deep roots in the underground. The territory of myth and legend, of cave and tunnel, has existed in Spain since that ancient time overwhelmed with shreds of fog, where all was myth around heros like Túbal Hércules, Gárgoris and Abidis. The underground evokes strong links with life and death, light and darkness, and has served as a source of inspiration for art through the centuries. The history of tunnels in Spain reflects the mosaic of cultures that have inhabited Iberia from prehistoric times till today. This contribution on the subterranean History of Spain traces the country’s heritage in the form of natural caves, troglodyte dwellings, mining, crypts, galleries in fortresses and castles, aqueducts, qanats, cellars, and other landmarks. |
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0886-7798 |
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THL @ christoph.kuells @ Ubierna1998131 |
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260 |
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