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Author Li, X.; Shen, K.; Li, Q.; Deng, Y.; Zhu, P.; Wang, D. url  openurl
  Title Roll-over behavior in current-voltage curve introduced by an energy barrier at the front contact in thin film CdTe solar cell Type Journal Article
  Year 2018 Publication Solar Energy Abbreviated Journal  
  Volume 165 Issue (up) Pages 27-34  
  Keywords AlO HRT layer, Band alignment, CdTe solar cell, Roll-over behavior  
  Abstract Roll-over phenomenon in the current–voltage (J–V) curve is often observed in a CdTe thin film solar cell. The roll-over phenomenon, which is occurred near the open-circuit voltage in a light J–V curve, is due to Schottky energy barrier formed at the CdTe/metal interface in a CdTe solar cell back contact. In this study we report a J–V roll-over phenomenon which is induced by an energy barrier at the front contact of a CdTe solar cell. Two kinds of oxides, namely, Al2O3 and SnO2, were deposited as high-resistance transparent (HRT) layer between the window layer CdS and the fluorine doped tin oxide (FTO) front electrode in CdTe solar cells. These two oxides present much different electronic band alignment with FTO and CdS. SnO2 formed almost no energy barrier with CdS, this allowed smooth transport for photo-generated electrons from CdTe to CdS and FTO. However, Al2O3 formed a high energy barrier with CdS. The rather high energy barrier with a value of 3.43 eV at the CdS/Al2O3 interface induced a J–V roll-over phenomenon in a CdTe thin film solar cell, which dramatically led to a quick decrease for the cell device efficiency. The electron transport at the FTO/Al2O3/CdS interface is governed by tunneling effect. The results presented in this study demonstrate that the band structure at the front electrode plays an important role for the performance of a CdTe thin film solar cell.  
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  Series Volume Series Issue Edition  
  ISSN 0038-092x ISBN Medium  
  Area Expedition Conference  
  Notes Approved no  
  Call Number THL @ christoph.kuells @ li_roll-over_2018 Serial 187  
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Author Ingham, E.S.; Cook, N.J.; Cliff, J.; Ciobanu, C.L.; Huddleston, A. url  openurl
  Title A combined chemical, isotopic and microstructural study of pyrite from roll-front uranium deposits, Lake Eyre Basin, South Australia Type Journal Article
  Year 2014 Publication Geochimica et Cosmochimica Acta Abbreviated Journal  
  Volume 125 Issue (up) Pages 440-465  
  Keywords  
  Abstract The common sulfide mineral pyrite is abundant throughout sedimentary uranium systems at Pepegoona, Pepegoona West and Pannikan, Lake Eyre Basin, South Australia. Combined chemical, isotopic and microstructural analysis of pyrite indicates variation in fluid composition, sulfur source and precipitation conditions during a protracted mineralization event. The results show the significant role played by pyrite as a metal scavenger and monitor of fluid changes in low-temperature hydrothermal systems. In-situ micrometer-scale sulfur isotope analyses of pyrite demonstrated broad-scale isotopic heterogeneity (δ34S=−43.9 to +32.4‰VCDT), indicative of complex, multi-faceted pyrite evolution, and sulfur derived from more than a single source. Preserved textures support this assertion and indicate a genetic model involving more than one phase of pyrite formation. Authigenic pyrite underwent prolonged evolution and recrystallization, evidenced by a genetic relationship between archetypal framboidal aggregates and pyrite euhedra. Secondary hydrothermal pyrite commonly displays hyper-enrichment of several trace elements (Mn, Co, Ni, As, Se, Mo, Sb, W and Tl) in ore-bearing horizons. Hydrothermal fluids of magmatic and meteoric origins supplied metals to the system but the geochemical signature of pyrite suggests a dominantly granitic source and also the influence of mafic rock types. Irregular variation in δ34S, coupled with oscillatory trace element zonation in secondary pyrite, is interpreted in terms of continuous variations in fluid composition and cycles of diagenetic recrystallization. A late-stage oxidizing fluid may have mobilized selenium from pre-existing pyrite. Subsequent restoration of reduced conditions within the aquifer caused ongoing pyrite re-crystallization and precipitation of selenium as native selenium. These results provide the first qualitative constraints on the formation mechanisms of the uranium deposits at Beverley North. Insights into depositional conditions and sources of both sulfide and uranium mineralization and an improved understanding of pyrite geochemistry can also underpin an effective vector for uranium exploration at Beverley North and other sedimentary systems of the Lake Eyre Basin, as well as in comparable geological environments elsewhere.  
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  Series Volume Series Issue Edition  
  ISSN 0016-7037 ISBN Medium  
  Area Expedition Conference  
  Notes Approved no  
  Call Number THL @ christoph.kuells @ ingham_combined_2014 Serial 188  
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Author Bullock, L.A.; Parnell, J. url  openurl
  Title Selenium and molybdenum enrichment in uranium roll-front deposits of Wyoming and Colorado, USA Type Journal Article
  Year 2017 Publication Journal of Geochemical Exploration Abbreviated Journal  
  Volume 180 Issue (up) Pages 101-112  
  Keywords Molybdenum, Roll-fronts, Selenium, Tellurium, Uranium, Wyoming  
  Abstract Sandstone uranium (U) roll-front deposits of Wyoming and Colorado (USA) are important U resources, and may provide a terrestrial source for critical accessory elements, such as selenium (Se), molybdenum (Mo), and tellurium (Te). Due to their associated toxicity, MoSeTe occurrences in roll-fronts should also be carefully monitored during U leaching and ore processing. While elevated MoSe concentrations in roll-fronts are well established, very little is known about Te occurrence in such deposits. This study aims to establish MoSeTe concentrations in Wyoming and Colorado roll-fronts, and assess the significance of these deposits in an environmental and mineral exploration context. Sampled roll-front deposits, produced by oxidized groundwater transportation through a sandstone, show high MoSe content in specific redox zones, and low Te, relative to crustal means. High Se concentrations (up to 168ppm) are restricted to a narrow band of alteration at the redox front. High Mo content (up to 115ppm) is typically associated with the reduced mineralized nose and seepage zones of the roll-front, ahead of the U orebody. Elevated trace element concentrations are likely sourced from proximal granitic intrusions, tuffaceous deposits, and local pyritic mudstones. Elevated MoSe content in the sampled roll fronts may be regarded as a contaminant in U in-situ recovery and leaching processing, and may pose an environmental threat in groundwaters and soils, so extraction should be carefully monitored. The identification of peak concentrations of MoSe can also act as a pathfinder for the redox front of a roll-front, and help to isolate the U orebody, particularly in the absence of gamma signatures.  
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  ISSN 0375-6742 ISBN Medium  
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  Notes Approved no  
  Call Number THL @ christoph.kuells @ bullock_selenium_2017 Serial 189  
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Author Kurmanseiit, M.B.; Tungatarova, M.S.; Royer, J.-J.; Aizhulov, D.Y.; Shayakhmetov, N.M.; Kaltayev, A. url  openurl
  Title Streamline-based reactive transport modeling of uranium mining during in-situ leaching: Advantages and drawbacks Type Journal Article
  Year 2023 Publication Hydrometallurgy Abbreviated Journal  
  Volume 220 Issue (up) Pages 106107  
  Keywords 3D modeling, In-situ leaching, Reactive transport model, Streamlines, Uranium recovery  
  Abstract Reactive transport modeling is known to be computationally intensive when applied to 3D problems. Transforming sequential computing on the computer processor units (CPU) into parallelized computation on the high-performance parallel graphic processor units (GPU) is a classical approach to increasing computational performance. Another complementary approach is to decompose a complex 3D modeling problem into a set of simpler 1D problems using streamline approaches which can be easily parallelized, therefore reducing computation time. This paper investigates solutions to the equations governing dissolution and transport using streamlines coupled with a parallelization approach. In addition, an analytical solution to the dissolution and transfer equations of uranium describing the In-Situ Leaching (ISL) mining recovery is found using an approximation series to the 2nd order. The analytical solution is compared to the 1D numerical resolution along the streamlines and to the 3D simulation results superimposed on the streamline. Both approaches give similar results with a relative error of \textless2 % (2%). The proposed methodology is then applied to a case study in which the classical 3D resolution is compared to the newly suggested streamline solution, demonstrating that the streamline approach increases computational performances by a factor ranging from hundred to thousand depending on the complexity of the grid-block model.  
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  Series Volume Series Issue Edition  
  ISSN 0304-386x ISBN Medium  
  Area Expedition Conference  
  Notes Approved no  
  Call Number THL @ christoph.kuells @ kurmanseiit_streamline-based_2023 Serial 190  
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Author Zhang, H.; Gao, J.; Xu, L.; Zhang, X. url  openurl
  Title Case studies of radioactivity of drilling mud for in situ leaching uranium mining in China Type Journal Article
  Year 2022 Publication Journal of Environmental Radioactivity Abbreviated Journal  
  Volume 251-252 Issue (up) Pages 106982  
  Keywords Drilling mud, Exemption management, In situ leaching, Radioactivity  
  Abstract The drilling mud from in situ leaching uranium mining is a type of low-radioactivity waste that contains natural nuclides and other harmful substances. In order to determine whether the drilling mud can meet the requirements of radioactive exemption management standards, field investigations and data simulations were conducted in this study. Two typical uranium mines were selected for onsite investigations. Drilling mud from different layers (i.e., the upper covering layer and ore-bearing layer) and from different stages (e.g., logging stage mud, drilling expansion stage mud, and mixed mud) was sampled. For each sample, the 238U and 226Ra concentrations of the solid components and the U and 226Ra concentrations of the supernatant were analyzed. The results revealed that the highest 238U and 226Ra concentrations of the solid components were 4122 Bq/kg and 4077 Bq/kg, while the 238U and 226Ra concentrations of the mixed drilling mud were all less than 300 Bq/kg. A radioactivity estimation model was established for scenario analysis. Exemption management screening lines of waste drilling mud, which can be used to classify and treat the drilling project according to the deposit’s grade and conditions, were proposed for in situ leaching drilling projects.  
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  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0265-931x ISBN Medium  
  Area Expedition Conference  
  Notes Approved no  
  Call Number THL @ christoph.kuells @ zhang_case_2022 Serial 191  
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