| |
Records |
Links |
|
Author |
Tujchneider, O.; Christelis, G.; Gun, J.V. der |
|
| |
Title |
Towards scientific and methodological innovation in transboundary aquifer resource management |
Type |
Journal Article |
| |
Year |
2013 |
Publication |
Environmental Development |
Abbreviated Journal |
|
|
| |
Volume |
7 |
Issue |
|
Pages |
6-16 |
|
| |
Keywords |
Communication, Cooperation, Holistic methodological approach, Science, Transboundary aquifer management |
|
| |
Abstract |
Groundwater is both an invaluable and a vulnerable resource. Aquifer resources management, aiming at the responsible exploitation and adequate protection of the groundwater resources, is therefore of key importance and has to be based on sound hydrological, environmental, economic and social principles. Aquifer-wide groundwater projects are carried out to collect the required area-specific information, to understand ongoing processes, to identify the management issues to be addressed and to develop an adequate management strategy and action plan. The quality of the project results depends to a large extent on the science and methodologies adopted in the design and used during the implementation of the projects. In this context, a project was carried out recently to analyse the scientific aspects of—among others—the transboundary aquifer projects within the IW: Portfolio of the Global Environmental Facility (GEF) and to make recommendations for scientific strengthening and innovation. This paper presents the main outcomes of this analysis. In order to accomplish groundwater resources management goals in the case of transboundary aquifers, a balanced joint strategy is needed. Analysis of documentation on completed and on-going transboundary aquifer projects has shown a wide range of scientific activities that contribute positively to the development of such strategies. This analysis has also identified options for increasing the positive impacts of science on strategy development; some of these options have been pioneered already and deserve wider application other ones are relatively new. Important options are: integrating transboundary aquifer resource management in a wider environmental–socio-economical context (holistic approach); exploring causal chains to better understand the processes of change of groundwater resources; using this improved understanding for optimising groundwater assessment and monitoring programmes; and adaptive management. In addition, to obtain maximum benefit of the scientific results there is a general need to promote effective communication at all levels, between the scientific community and policy-/decision makers, as well as with the local community who have a major role to play in the use and conservation of the resources. All of this should be accompanied by the harmonisation of the legal instruments and co-operation agreements between countries and the communities involved. Two case studies, one in South America and one in Southern Africa, are added as examples of the setting and approach of the analysed transboundary aquifer projects. |
|
| |
Address |
|
|
| |
Corporate Author |
|
Thesis |
|
|
| |
Publisher |
|
Place of Publication |
|
Editor |
|
|
| |
Language |
|
Summary Language |
|
Original Title |
|
|
| |
Series Editor |
|
Series Title |
|
Abbreviated Series Title |
|
|
| |
Series Volume |
|
Series Issue |
|
Edition |
|
|
| |
ISSN |
2211-4645 |
ISBN |
|
Medium  |
|
|
| |
Area |
|
Expedition |
|
Conference |
|
|
| |
Notes |
|
Approved |
no |
|
| |
Call Number |
THL @ christoph.kuells @ tujchneider_towards_2013 |
Serial |
105 |
|
| Permanent link to this record |
| |
|
| |
|
Author |
Puri, S. |
|
| |
Title |
Chapter 9 – Transboundary aquifers: a shared subsurface asset, in urgent need of sound governance |
Type |
Book Chapter |
| |
Year |
2021 |
Publication |
Global Groundwater |
Abbreviated Journal |
|
|
| |
Volume |
|
Issue |
|
Pages |
113-128 |
|
| |
Keywords |
ILC Draft Articles, impact on GDP, sound governance, Transboundary aquifers |
|
| |
Abstract |
Apart from some notable exceptions, the sound governance of transboundary aquifers (coupled or uncoupled to rivers) is seriously lacking in most regions of the world, despite a highly successful 20-year ISARM initiative. The distinction between regions of water abundance (as in the Haute Savoie–Geneva aquifers) and those of water scarcity (\textless1000 m3/an/capita), as in the Rum-Saq aquifer, ought to be a driver for the urgency in adopting sound governance. In the latter regions, however, such an urgent response faces too many hurdles (institutional, financial, and weak capacity). Climate change, one of the global megatrends (among demography, economic shift, resources stress, urbanization, and novel viruses such as COVID-19), will exacerbate the problem in the coming decade and beyond. This chapter provides an critical perspective on the status of this subsurface asset in 570 or so, domestic and transboundary aquifers of the world (self-identified by country experts), while taking full account of their interconnections, or not, with surface waters. This critical perspective will be grounded in two important factors, first the hiatus in adoption by countries of the evolving international water law and guidance on transboundary aquifers (the Draft Articles, which provide legal pathways for collaboration or eventually dispute resolution), and second the framework of the sustainable development goals (SDG) 6 (clean water and sanitation), which countries have committed themselves to with reference to transboundary waters. The critical perspective finds that despite the lack of momentum in adopting formal global norms, sporadic cooperation and collaboration is continuing and is well received, when delivered methodically through the support of international agencies. The findings of the critical perspective are that even if water-related SDGs will have been achieved across the world, it would contribute precious little to meaningful enhancement of governance of transboundary aquifers, unless they have been explicitly addressed in terms that are tangible to decision makers, such as the impact of disregarding them on the current or future national GDP. The onset of a “new socioeconomic normal” in the aftermath of COVID-19 could further defer meaningful progress, taking the example of Latin America, where a 5% decline has been forecast for 2020. With such declines in the finances of governments, attention to shared aquifer resources may well decline even further. Urgent wise reaction to this possibility must be a priority for the professional science-policy community. |
|
| |
Address |
|
|
| |
Corporate Author |
|
Thesis |
|
|
| |
Publisher |
Elsevier |
Place of Publication |
|
Editor |
Mukherjee, A.; Scanlon, B.R.; Aureli, A.; Langan, S.; Guo, H.; McKenzie, A.A. |
|
| |
Language |
|
Summary Language |
|
Original Title |
|
|
| |
Series Editor |
|
Series Title |
|
Abbreviated Series Title |
|
|
| |
Series Volume |
|
Series Issue |
|
Edition |
|
|
| |
ISSN |
|
ISBN |
978-0-12-818172-0 |
Medium |
|
|
| |
Area |
|
Expedition |
|
Conference |
|
|
| |
Notes |
|
Approved |
no |
|
| |
Call Number |
THL @ christoph.kuells @ mukherjee_chapter_2021 |
Serial |
106 |
|
| Permanent link to this record |
| |
|
| |
|
Author |
Lim, S.; Chase, B.M.; Chevalier, M.; Reimer, P.J. |
|
| |
Title |
50,000years of vegetation and climate change in the southern Namib Desert, Pella, South Africa |
Type |
Journal Article |
| |
Year |
2016 |
Publication |
Palaeogeography, Palaeoclimatology, Palaeoecology |
Abbreviated Journal |
|
|
| |
Volume |
451 |
Issue |
|
Pages |
197-209 |
|
| |
Keywords |
Climate reconstruction, Late Quaternary, Namib Desert, Pollen, Rock hyrax middens, South Africa |
|
| |
Abstract |
This paper presents the first continuous pollen record from the southern Namib Desert spanning the last 50,000years. Obtained from rock hyrax middens found near the town of Pella, South Africa, these data are used to reconstruct vegetation change and quantitative estimates of temperature and aridity. Results indicate that the last glacial period was characterised by increased water availability at the site relative to the Holocene. Changes in temperature and potential evapotranspiration appear to have played a significant role in determining the hydrologic balance. The record can be considered in two sections: 1) the last glacial period, when low temperatures favoured the development of more mesic Nama-Karoo vegetation at the site, with periods of increased humidity concurrent with increased coastal upwelling, both responding to lower global/regional temperatures; and 2) the Holocene, during which time high temperatures and potential evapotranspiration resulted in increased aridity and an expansion of the Desert Biome. During this latter period, increases in upwelling intensity created drier conditions at the site. Considered in the context of discussions of forcing mechanisms of regional climate change and environmental dynamics, the results from Pella stand in clear contrast with many inferences of terrestrial environmental change derived from regional marine records. Observations of a strong precessional signal and interpretations of increased humidity during phases of high local summer insolation in the marine records are not consistent with the data from Pella. Similarly, while high percentages of Restionaceae pollen has been observed in marine sediments during the last glacial period, they do not exceed 1% of the assemblage from Pella, indicating that no significant expansion of the Fynbos Biome has occurred during the last 50,000years. These findings pose interesting questions regarding the nature of environmental change in southwestern Africa, and the significance of the diverse records that have been obtained from the region. |
|
| |
Address |
|
|
| |
Corporate Author |
|
Thesis |
|
|
| |
Publisher |
|
Place of Publication |
|
Editor |
|
|
| |
Language |
|
Summary Language |
|
Original Title |
|
|
| |
Series Editor |
|
Series Title |
|
Abbreviated Series Title |
|
|
| |
Series Volume |
|
Series Issue |
|
Edition |
|
|
| |
ISSN |
0031-0182 |
ISBN |
|
Medium |
|
|
| |
Area |
|
Expedition |
|
Conference |
|
|
| |
Notes |
|
Approved |
no |
|
| |
Call Number |
THL @ christoph.kuells @ lim_50000years_2016 |
Serial |
107 |
|
| Permanent link to this record |
| |
|
| |
|
Author |
Stone, A. |
|
| |
Title |
Recharge investigations above the Stampriet Aquifer in semi-arid Namibia using geochemical methods and environmental tracers; sand, salt and water |
Type |
Journal Article |
| |
Year |
2012 |
Publication |
Quaternary International |
Abbreviated Journal |
|
|
| |
Volume |
279-280 |
Issue |
|
Pages |
470-471 |
|
| |
Keywords |
|
|
| |
Abstract |
|
|
| |
Address |
|
|
| |
Corporate Author |
|
Thesis |
|
|
| |
Publisher |
|
Place of Publication |
|
Editor |
|
|
| |
Language |
|
Summary Language |
|
Original Title |
|
|
| |
Series Editor |
|
Series Title |
|
Abbreviated Series Title |
|
|
| |
Series Volume |
|
Series Issue |
|
Edition |
|
|
| |
ISSN |
1040-6182 |
ISBN |
|
Medium |
|
|
| |
Area |
|
Expedition |
|
Conference |
|
|
| |
Notes |
|
Approved |
no |
|
| |
Call Number |
THL @ christoph.kuells @ stone_recharge_2012 |
Serial |
108 |
|
| Permanent link to this record |
| |
|
| |
|
Author |
Castro, M.C.; Stute, M.; Schlosser, P. |
|
| |
Title |
Comparison of 4He ages and 14C ages in simple aquifer systems: implications for groundwater flow and chronologies |
Type |
Journal Article |
| |
Year |
2000 |
Publication |
Applied Geochemistry |
Abbreviated Journal |
|
|
| |
Volume |
15 |
Issue |
8 |
Pages |
1137-1167 |
|
| |
Keywords |
|
|
| |
Abstract |
4He concentrations in excess of the solubility equilibrium with the atmosphere by up to two to three orders of magnitude are observed in the Carrizo Aquifer in Texas, the Ojo Alamo and Nacimiento aquifers in the San Juan Basin, New Mexico, and the Auob Sandstone Aquifer in Namibia. A simple 4He accumulation model is applied to explain these excess 4He concentrations in terms of both in situ production and a crustal flux across the bottom layer of the aquifer. Results from the model simulations suggest variability in the 4He fluxes, ranging from 6×10−6 cm3 STP cm−2 yr−1 for the Auob Sandstone Aquifer to 3.6×10−7 cm3 STP cm−2 yr−1 for the Carrizo aquifer. For the Ojo Alamo and Nacimiento aquifers an intermediate value of 3×10−6 cm3 STP cm−2 yr−1 was estimated. The contribution of in-situ produced 4He to the measured concentrations was also estimated. This contribution is negligible for the Auob Sandstone Aquifer as compared with both the concentrations measured at the top and bottom of the aquifer for most of the pathway. In the Carrizo aquifer, in-situ produced 4He contributes 27.5% and 15.4%, to the total 4He observed at the top and bottom of the aquifer, respectively. For both aquifers of the San Juan Basin in-situ production almost entirely dominates the 4He concentrations at the top of the aquifer for most of the pathway. In contrast, the internal production is negligible as compared with the measured concentrations at the bottom of these aquifers, reaching, at most, 1.1%. The model simulations require an exponential decrease in the horizontal velocity of the water with increasing recharge distance to reproduce the distribution of 4He in these aquifers. For the Auob Sandstone Aquifer the highest range in the velocity values is obtained (25 to 0.4 m yr−1). The simulations for the Carrizo aquifer and both aquifers located in the San Juan Basin require velocities varying from 4 to 0.1 m yr−1, and from 2 to 0.3 m yr−1, respectively. For each aquifer, average permeability values were also estimated. They are generally in agreement with results obtained from pumping tests, hydrodynamic modeling and previous 14C measurements. On the basis of the results obtained by calibrating the model with the measured 4He concentrations, the mean water residence times were estimated. They agree reasonably well with 14C ages. When applied as chronologies for noble gas temperatures in the same aquifers, the calculated 4He ages allow the identification of three different climate periods similar to those previously identified using 14C ages: (1) the Holocene period (0–10 Ka BP), (2) the Last Glacial Maximum (≈18 Ka BP), and (3) the preceeding period (30–150 Ka BP). |
|
| |
Address |
|
|
| |
Corporate Author |
|
Thesis |
|
|
| |
Publisher |
|
Place of Publication |
|
Editor |
|
|
| |
Language |
|
Summary Language |
|
Original Title |
|
|
| |
Series Editor |
|
Series Title |
|
Abbreviated Series Title |
|
|
| |
Series Volume |
|
Series Issue |
|
Edition |
|
|
| |
ISSN |
0883-2927 |
ISBN |
|
Medium |
|
|
| |
Area |
|
Expedition |
|
Conference |
|
|
| |
Notes |
|
Approved |
no |
|
| |
Call Number |
THL @ christoph.kuells @ castro_comparison_2000 |
Serial |
109 |
|
| Permanent link to this record |
| |
|
| |
|
Author |
Brook, G.A.; Railsback, L.B.; Marais, E. |
|
| |
Title |
Reassessment of carbonate ages by dating both carbonate and organic material from an Etosha Pan (Namibia) stromatolite: Evidence of humid phases during the last 20ka |
Type |
Journal Article |
| |
Year |
2011 |
Publication |
Quaternary International |
Abbreviated Journal |
|
|
| |
Volume |
229 |
Issue |
1 |
Pages |
24-37 |
|
| |
Keywords |
|
|
| |
Abstract |
Previous research on lacustrine stromatolites from Etosha Pan in Namibia obtained ages on carbonate close to or beyond the limits of radiocarbon dating. These ages suggested that the basin was likely not subject to extensive flooding during the last ca. 40ka. This study shows that AMS radiocarbon ages for the carbonate of a stromatolite from Poacher’s Point are 15–21ka older than ages for organic material in the stromatolite structure. Calibrated ages range from 30 to 40ka for carbonate and 3–19ka for the organic residue. The new ages, together with petrographic and isotopic data for the stromatolite, have provided important new information on past flooding of Etosha Pan including evidence of prolonged lacustrine conditions during the Holocene Climatic Optimum. |
|
| |
Address |
|
|
| |
Corporate Author |
|
Thesis |
|
|
| |
Publisher |
|
Place of Publication |
|
Editor |
|
|
| |
Language |
|
Summary Language |
|
Original Title |
|
|
| |
Series Editor |
|
Series Title |
|
Abbreviated Series Title |
|
|
| |
Series Volume |
|
Series Issue |
|
Edition |
|
|
| |
ISSN |
1040-6182 |
ISBN |
|
Medium |
|
|
| |
Area |
|
Expedition |
|
Conference |
|
|
| |
Notes |
|
Approved |
no |
|
| |
Call Number |
THL @ christoph.kuells @ brook_reassessment_2011 |
Serial |
110 |
|
| Permanent link to this record |
| |
|
| |
|
Author |
Hall, S.M.; Gosen, B.S.V.; Zielinski, R.A. |
|
| |
Title |
Sandstone-hosted uranium deposits of the Colorado Plateau, USA |
Type |
Journal Article |
| |
Year |
2023 |
Publication |
Ore Geology Reviews |
Abbreviated Journal |
|
|
| |
Volume |
155 |
Issue |
|
Pages |
105353 |
|
| |
Keywords |
Colorado, Plateau, Uranium, Vanadium |
|
| |
Abstract |
More than 4,000 sandstone-hosted uranium occurrences host over 1.2 billion pounds of mined and in situ U3O8 throughout the Colorado Plateau. Most of the resources are in two distinct mineral systems with deposits hosted in the Triassic Chinle and Jurassic Morrison Formations. In the Chinle mineral system, base metal sulfides typically accompany mineralization. The Morrison mineral system is characterized by V/U ratios up to 20. The uranium source was likely volcanic ash preserved as bentonitic mudstones in the Brushy Basin Member of the Morrison Formation, and lithic volcanic clasts, ash shards, and bentonitic clay in the lower part of the Chinle Formation. Vanadium originated from two possible sources: iron–titanium oxides that are extensively altered in bleached rock near deposits or from similar minerals in variably bleached red beds interbedded with and beneath the Morrison. In Chinle-hosted deposits, in addition to volcanic ash, a contributing source of both vanadium and uranium is proposed here for the first time to be underlying red beds in the Moenkopi and Cutler Formations that have undergone a cycle of reddening-bleaching-reoxidation. Transport in both systems was likely in groundwater through the more permeable sandstones and conglomerate units. The association of uranium minerals with carbonate and more rarely apatite, suggests that transport of uranium was as a carbonate or phosphate complex. The first comprehensive examination of paleoclimate, paleotopography, and subsurface structure of aquifers coupled with analysis of the geochronology of deposits suggests that that there were distinct pulses of uranium mineralization/redistribution during the period from about 259 Ma to 12 Ma when oxidized mineralizing fluids were intermittently rejuvenated in the Plateau in response to changes in tectonic regime and climate. Multiple lines of evidence indicate that deposits formed at ambient temperatures of about 25 °C to no greater than about 140 °C. In both systems, deposits formed where groundwater flow slowed and was subject to evaporative concentration. Stagnant conditions allowed for prolonged interaction of U- and V-enriched groundwater with ferrous iron-bearing reductants, such as illite and iron–titanium oxides, and more rarely organic material such as plant debris. Paragenetically late in the sequence, reducing fluids introduced additional organic matter to some deposits. Reducing fluids and introduced organic matter (now amorphous and altered by radiolysis) may originate from regional petroleum systems where peak oil and gas generation was from ∼ 82 to ∼ 5 Ma. Our novel analysis indicates that these reducing fluids bleached rock and protected affected deposits from remobilization during exposure and weathering that followed uplift of the Plateau (∼80 to 40 Ma). |
|
| |
Address |
|
|
| |
Corporate Author |
|
Thesis |
|
|
| |
Publisher |
|
Place of Publication |
|
Editor |
|
|
| |
Language |
|
Summary Language |
|
Original Title |
|
|
| |
Series Editor |
|
Series Title |
|
Abbreviated Series Title |
|
|
| |
Series Volume |
|
Series Issue |
|
Edition |
|
|
| |
ISSN |
0169-1368 |
ISBN |
|
Medium |
|
|
| |
Area |
|
Expedition |
|
Conference |
|
|
| |
Notes |
|
Approved |
no |
|
| |
Call Number |
THL @ christoph.kuells @ hall_sandstone-hosted_2023 |
Serial |
111 |
|
| Permanent link to this record |
| |
|
| |
|
Author |
Milena-Pérez, A.; Piñero-García, F.; Benavente, J.; Expósito-Suárez, V.M.; Vacas-Arquero, P.; Ferro-García, M.A. |
|
| |
Title |
Uranium content and uranium isotopic disequilibria as a tool to identify hydrogeochemical processes |
Type |
Journal Article |
| |
Year |
2021 |
Publication |
Journal of Environmental Radioactivity |
Abbreviated Journal |
|
|
| |
Volume |
227 |
Issue |
|
Pages |
106503 |
|
| |
Keywords |
234U/238U, Betic cordillera, Groundwater, Hydrogeochemistry, Uranium natural isotopes |
|
| |
Abstract |
This paper studies the uranium content and uranium isotopic disequilibria as a tool to identify hydrogeochemical processes from 52 groundwater samples in the province of Granada (Betic Cordillera, southeastern Spain). According to the geological complexity of the zone, three groups of samples have been considered. In Group 1 (thermal waters; longest residence time), the average uranium content was 2.63 ± 0.16 μg/L, and 234U/238U activity ratios (AR) were the highest of all samples, averaging 1.92 ± 0.30. In Group 2 (mainly springs from carbonate aquifers; intermediate residence time), dissolved uranium presented an average value of 1.34 ± 0.13 μg/L, while AR average value was 1.38 ± 0.25. Group 3 comes from pumping wells in a highly anthropized alluvial aquifer. In this group, where the residence time of the groundwater is the shortest of the three, average uranium content was 5.28 ± 0.26 μg/L, and average AR is the lowest (1.17 ± 0.12). In addition, the high dissolved uranium value and the low AR brought to light the contribution of fertilizers (Group 3). In the three groups, 235U/238U activity ratios were similar to the natural value of 0.046. Therefore, 235U detected in the samples comes from natural sources. This study is completed with the determination of major ions and physicochemical parameters in the groundwater samples and the statistical analysis of the data by using the Principal Component Analysis. This calculation indicates the correlation between uranium isotopes and bicarbonate and nitrate anions. |
|
| |
Address |
|
|
| |
Corporate Author |
|
Thesis |
|
|
| |
Publisher |
|
Place of Publication |
|
Editor |
|
|
| |
Language |
|
Summary Language |
|
Original Title |
|
|
| |
Series Editor |
|
Series Title |
|
Abbreviated Series Title |
|
|
| |
Series Volume |
|
Series Issue |
|
Edition |
|
|
| |
ISSN |
0265-931x |
ISBN |
|
Medium |
|
|
| |
Area |
|
Expedition |
|
Conference |
|
|
| |
Notes |
|
Approved |
no |
|
| |
Call Number |
THL @ christoph.kuells @ milena-perez_uranium_2021 |
Serial |
112 |
|
| Permanent link to this record |
| |
|
| |
|
Author |
Merembayev, T.; Yunussov, R.; Yedilkhan, A. |
|
| |
Title |
Machine Learning Algorithms for Stratigraphy Classification on Uranium Deposits |
Type |
Journal Article |
| |
Year |
2019 |
Publication |
Procedia Computer Science |
Abbreviated Journal |
|
|
| |
Volume |
150 |
Issue |
|
Pages |
46-52 |
|
| |
Keywords |
classification, geophysics logging data, machine learning, stratigraphy, uranium deposit |
|
| |
Abstract |
Machine learning today becomes more and more effective instrument to solve many particular problems, where there are difficulties to apply well known and described math model. In other words – it is a great tool to describe non-linear phenomena. We tried to use this technique to improve existing process of stratigraphy, and reduce costs on site by applying computer leaded predictions on the basis of existing on-field collected data. Article describes usage of machine learning algorithms for stratigraphy boundaries classification based on geophysics logging data for uranium deposit in Kazakhstan. Correct marking of stratigraphy from geophysics logging data is complex non-linear task. To solve this task we applied several algorithms of machine learning: random forest, logistic regression, gradient boosting, k nearest neighbour and XGBoost. |
|
| |
Address |
|
|
| |
Corporate Author |
|
Thesis |
|
|
| |
Publisher |
|
Place of Publication |
|
Editor |
|
|
| |
Language |
|
Summary Language |
|
Original Title |
|
|
| |
Series Editor |
|
Series Title |
|
Abbreviated Series Title |
|
|
| |
Series Volume |
|
Series Issue |
|
Edition |
|
|
| |
ISSN |
1877-0509 |
ISBN |
|
Medium |
|
|
| |
Area |
|
Expedition |
|
Conference |
|
|
| |
Notes |
|
Approved |
no |
|
| |
Call Number |
THL @ christoph.kuells @ merembayev_machine_2019 |
Serial |
113 |
|
| Permanent link to this record |
| |
|
| |
|
Author |
Dutova, E.M.; Nikitenkov, A.N.; Pokrovskiy, V.D.; Banks, D.; Frengstad, B.S.; Parnachev, V.P. |
|
| |
Title |
Modelling of the dissolution and reprecipitation of uranium under oxidising conditions in the zone of shallow groundwater circulation |
Type |
Journal Article |
| |
Year |
2017 |
Publication |
Journal of Environmental Radioactivity |
Abbreviated Journal |
|
|
| |
Volume |
178-179 |
Issue |
|
Pages |
63-76 |
|
| |
Keywords |
Groundwater, Hydrochemical modelling, Mineralisation, Natural uranium, Ore, Solubility |
|
| |
Abstract |
Generic hydrochemical modelling of a grantoid-groundwater system, using the Russian software “HydroGeo”, has been carried out with an emphasis on simulating the accumulation of uranium in the aqueous phase. The baseline model run simulates shallow granitoid aquifers (U content 5 ppm) under conditions broadly representative of southern Norway and southwestern Siberia: i.e. temperature 10 °C, equilibrated with a soil gas partial CO2 pressure (PCO2, open system) of 10−2.5 atm. and a mildly oxidising redox environment (Eh = +50 mV). Modelling indicates that aqueous uranium accumulates in parallel with total dissolved solids (or groundwater mineralisation M – regarded as an indicator of degree of hydrochemical evolution), accumulating most rapidly when M = 550–1000 mg L−1. Accumulation slows at the onset of saturation and precipitation of secondary uranium minerals at M = c. 1000 mg L−1 (which, under baseline modelling conditions, also corresponds approximately to calcite saturation and transition to Na-HCO3 hydrofacies). The secondary minerals are typically “black” uranium oxides of mixed oxidation state (e.g. U3O7 and U4O9). For rock U content of 5–50 ppm, it is possible to generate a wide variety of aqueous uranium concentrations, up to a maximum of just over 1 mg L−1, but with typical concentrations of up to 10 μg L−1 for modest degrees of hydrochemical maturity (as indicated by M). These observations correspond extremely well with real groundwater analyses from the Altai-Sayan region of Russia and Norwegian crystalline bedrock aquifers. The timing (with respect to M) and degree of aqueous uranium accumulation are also sensitive to Eh (greater mobilisation at higher Eh), uranium content of rocks (aqueous concentration increases as rock content increases) and PCO2 (low PCO2 favours higher pH, rapid accumulation of aqueous U and earlier saturation with respect to uranium minerals). |
|
| |
Address |
|
|
| |
Corporate Author |
|
Thesis |
|
|
| |
Publisher |
|
Place of Publication |
|
Editor |
|
|
| |
Language |
|
Summary Language |
|
Original Title |
|
|
| |
Series Editor |
|
Series Title |
|
Abbreviated Series Title |
|
|
| |
Series Volume |
|
Series Issue |
|
Edition |
|
|
| |
ISSN |
0265-931x |
ISBN |
|
Medium |
|
|
| |
Area |
|
Expedition |
|
Conference |
|
|
| |
Notes |
|
Approved |
no |
|
| |
Call Number |
THL @ christoph.kuells @ dutova_modelling_2017 |
Serial |
114 |
|
| Permanent link to this record |
