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Author Ren, Y.; Yang, X.; Hu, X.; Wei, J.; Tang, C. url  openurl
  Title Mineralogical and geochemical evidence for biogenic uranium mineralization in northern Songliao Basin, NE China Type Journal Article
  Year 2022 Publication (up) Ore Geology Reviews Abbreviated Journal  
  Volume 141 Issue Pages 104556  
  Keywords Bacterial sulfate reduction, In-situ S isotope of pyrite, Northern Songliao basin, Sandstone-type uranium deposit, Sifangtai Formation  
  Abstract The sandstone-hosted uranium mineralization areas in the Sanzhao Sag of the northern Songliao Basin have been newly identified. The target stratum is the Upper Cretaceous Sifangtai Formation and the uranium mineralization mainly occurs in the bottom of Sifangtai Formation, corresponding to channel sand bodies in meandering river system, characterized by medium to fine-grained sandstone. This study proposes the uranium metallogenic model through petrographic observation, whole rock geochemistry, mineralogical study of uranium occurrence form (SEM), organic matter rock–eval pyrolysis analysis (REP) and in-situ sulfur isotope determination of different generations of pyrite by LA-MC-ICP-MS. Compared with the sandstones collected in barren reduction and oxidization zones, the mineralized sandstones show obvious increase in the contents of TOC, total sulfur, Y and U. Petrographic observations indicate that organic matters are mainly inherited from land plants. REP data display that the organic matter (OM) disseminated in the sandstone has very low hydrogen index (HI) from around 0 to 21 mg HC/g TOC and varied oxygen index (OI) from 44 to 115 mg CO2/g TOC, corresponding to Type Ⅳ kerogen (degraded kerogen). There are two types of coffinite with different grain size, micro-particles (μm-sized) and large aggregates (generally up to 100 μm) respectively. The coffinite micro spherules exhibit short rod-like or worm-like morphology occurring in clay matrix and cell cavities in degradofusinite or around subidiomorphic-idiomorphic pyrite. The coarse-grained coffinite contains other mineral facies (e.g. pyrite, quartz) and some of large coffinite aggregates display thrombolite-type microbial structures. The irregular pyrite relict particles in coarse-grained colloidal coffinite have light sulfur isotope compositions characterized by δ34S values from –39.96‰ to –49.89‰. The δ34S values of colloidal pyrite in replacement of OM or of the sub-idiomorphic FeS2 cement filling in the cavities of OM range from –52.77‰ to –13.88‰. Some of sub-idiomorphic pyrite cement and idiomorphic crystal have the heavier signature from – 27.06‰ to + 14.23‰. The light sulfur isotope signature suggests that the sulfur originates from bacterial sulfate reduction (BSR). The OM replacement by pyrite and the highest OI values recorded by REP in uranium mineralized samples are lines of evidence of biodegradation. Bacteria use the organic matter as food source and produce isotopically light reduced sulfur species. Oxygenated uranium-bearing waters infiltrated through the denudated windows at Daqing placanticline into the porous reduced sandstones deposited in the Sanzhao Sag. Uranium was indirectly reduced by BSR-derived iron disulfides or directly reduced by sulfate-reducing bacteria.  
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  ISSN 0169-1368 ISBN Medium  
  Area Expedition Conference  
  Notes Approved no  
  Call Number THL @ christoph.kuells @ ren_mineralogical_2022 Serial 144  
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Author Min, M.; Chen, J.; Wang, J.; Wei, G.; Fayek, M. url  openurl
  Title Mineral paragenesis and textures associated with sandstone-hosted roll-front uranium deposits, NW China Type Journal Article
  Year 2005 Publication (up) Ore Geology Reviews Abbreviated Journal  
  Volume 26 Issue 1 Pages 51-69  
  Keywords China, Mineralogy, Paragenesis, Sandstone-hosted roll-type uranium deposit  
  Abstract We present a first paragenetic study of the Wuyier, Wuyisan, Wuyiyi and Shihongtan sandstone-hosted roll-front uranium deposits, northwest China. The mineralization is hosted by Lower–Middle Jurassic coarse- to medium-grained sandstones, which are dark-gray to black due to a mixture of ore minerals and carbonaceous debris. The sandstone is alluvial fan-braided river facies. Minerals associated with these deposits can be broadly categorized as detrital, authigenic, and ore-stage mineralization. Ore minerals consist of uraninite and coffinite. This is the first noted occurrence of coffinite in this type of deposit in China. Sulfide minerals associated with the uranium minerals are pyrite, marcasite, and less commonly, sphalerite and galena. The sulfide minerals are largely in textural equilibrium with the uranium minerals. However, these sulfide minerals occasionally appear to predate, as well as postdate, the uranium minerals. This implies that there are multiple generations of sulfides associated with these deposits. The ore minerals occur interstitially between fossilized wood cells in the sandstones as well as replace fossilized wood and biotite. The deposits are generally low-grade. Primary uranium minerals associated with the low-grade deposits are generally too small, ranging from 0.2 to 0.3 μm in diameter, to be observed by optical microscopy and are only observed by electron microscopy. Mineral paragenesis and textures indicate that these deposits formed under low temperature (30–50 °C) conditions.  
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  ISSN 0169-1368 ISBN Medium  
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  Notes Approved no  
  Call Number THL @ christoph.kuells @ min_mineral_2005 Serial 175  
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Author Rallakis, D.; Michels, R.; Cathelineau, M.; Parize, O.; Brouand, M. url  openurl
  Title Conditions for uranium biomineralization during the formation of the Zoovch Ovoo roll-front-type uranium deposit in East Gobi Basin, Mongolia Type Journal Article
  Year 2021 Publication (up) Ore Geology Reviews Abbreviated Journal  
  Volume 138 Issue Pages 104351  
  Keywords Bioreduction, East Gobi Basin, Mongolia, Organic matter, Roll-front, Sulfur isotopes, Uranium  
  Abstract The Zoovch Ovoo uranium roll-front-type deposit is hosted in the Sainshand Formation, a Late Cretaceous siliciclastic reservoir, which constitutes the upper part of the post-rift infilling of the Mesozoic East Gobi Basin in SE Mongolia. The Sainshand Formation consists of unconsolidated medium-grained sand, silt and clay intervals deposited in fluvial-lacustrine settings. The uranium deposit is confined within a 60–80 m thick siliciclastic sequence inside aquifer-driven systems. The overall system experienced shallow burial and was never subjected to temperatures higher than 40 °C. This study proposes a comprehensive metallogenic model for this uranium deposit. Sedimentological and mineralogical observations from drill core samples to the microscopic scale (optical and Scanning Electron Microscopy) together with in situ geochemistry of late-formed phases (Laser Ablation–Inductively Coupled Plasma Mass Spectrometry, Electron Probe Microanalysis, Fourier Transform–Infrared Spectroscopy) were considered for the reconstruction of the main stages of U trapping. In the mineralized zone, the uranium ore is expressed as Ca–enriched uraninite (UO2) and less commonly as Ca–enriched phospho-coffinite (U, P)SiO4. Trapping mechanisms include i) complexation (i.e. uranyl-carboxyl complexes), ii) adsorption on organic or clay particles) and iii) reduction by pyrite and by bacterial activity to amorphous uraninite. In all cases, the organic matter plays either the role of trap for uranium or nutrient for bacteria that can trap uranium through their metabolism. The shallow burial diagenesis conditions do not allow direct reduction of U(VI) by organic carbon. The δ34S values of the iron disulfide are very diverse, fluctuating in extreme cases between −50 to + 50‰, with an average δ34S value for framboidal pyrite at 2‰, and −20‰ for euhedral pyrite. The positive and negative values reflect close versus open fractionation systems, while bacterial sulphate reduction (BSR) is active during the whole diagenetic history of the deposit as an essential source of reduced sulfur. Therefore, using detrital organic matter as a carbon source, microorganisms play a significant role in uranium trapping, either as a direct reducing agent for uranium or pyrite formation, which will trap uranium through redox driven epigenetic processes.  
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  Notes Approved no  
  Call Number THL @ christoph.kuells @ rallakis_conditions_2021 Serial 176  
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Author Min, M.; Xu, H.; Chen, J.; Fayek, M. url  openurl
  Title Evidence of uranium biomineralization in sandstone-hosted roll-front uranium deposits, northwestern China Type Journal Article
  Year 2005 Publication (up) Ore Geology Reviews Abbreviated Journal  
  Volume 26 Issue 3 Pages 198-206  
  Keywords Biomineralization, China, Roll-front uranium deposit, Sandstone  
  Abstract We show evidence that the primary uranium minerals, uraninite and coffinite, from high-grade ore samples (U3O8\textgreater0.3%) in the Wuyiyi, Wuyier, and Wuyisan sandstone-hosted roll-front uranium deposits, Xinjiang, northwestern China were biogenically precipitated and psuedomorphically replace fungi and bacteria. Uranium (VI), which was the sole electron acceptor, was likely to have been enzymically reduced. Post-mortem accumulation of uranium may have also occurred through physio-chemical interaction between uranium and negatively-charged cellular sites, and inorganic adsorption or precipitation reactions. These results suggest that microorganisms may have played a key role in formation of the sandstone- or roll-type uranium deposits, which are among the most economically significant uranium deposits in the world.  
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  ISSN 0169-1368 ISBN Medium  
  Area Expedition Conference  
  Notes Approved no  
  Call Number THL @ christoph.kuells @ min_evidence_2005 Serial 186  
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Author Belz, L.; Schüller, I.; Wehrmann, A.; Köster, J.; Wilkes, H. url  openurl
  Title The leaf wax biomarker record of a Namibian salt pan reveals enhanced summer rainfall during the Last Glacial-Interglacial Transition Type Journal Article
  Year 2020 Publication (up) Palaeogeography, Palaeoclimatology, Palaeoecology Abbreviated Journal  
  Volume 543 Issue Pages 109561  
  Keywords -Alkanes, -Alkanols, Late Quaternary, Organic geochemistry, Palaeohydrology, Southern Africa  
  Abstract Conventional continental geoarchives are rarely available in arid southern Africa. Therefore, palaeoclimate data in this area are still patchy and late Quaternary climate development is only poorly understood. In the western Kalahari, salt pans (playas, ephemeral lakes) are common and can feature quasi-continuous sedimentation. This study presents the first climate-related biomarker record using sediments from the Omongwa Pan, a Kalahari salt pan located in eastern Namibia. Our approach to reconstruct vegetation and hydrology focuses on biogeochemical bulk parameters and plant wax-derived lipid biomarkers (n-alkanes, n-alkanols, and fatty acids) and their compound-specific carbon and hydrogen isotopic compositions. The presented record reaches back to 27 ka. During the glacial, rather low δ2H values of n-alkanes and low sediment input exclude a strong influence of winter rainfall. n-Alkane and n-alkanol distributions and δ13C values of n-hentriacontane (n-C31) indicate a shift to a vegetation with a higher proportion of C4 plants at the end of the Last Glacial Maximum until the end of Heinrich Stadial I (ca. 18–14.8 ka), which we interpret to indicate an abrupt excursion to a short wetter period likely to be caused by a temporary southward shift of the Intertropical Convergence Zone. Shifts in δ2H values of n-C31 and plant wax parameters give evidence for changes to drier conditions during early Holocene. Comparison of this dataset with representative continental records from the region points to a major influence of summer rainfall at Omongwa Pan during the regarded time span and demonstrates the potential of southern African salt pans as archives for biomarker-based climate proxies.  
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  ISSN 0031-0182 ISBN Medium  
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  Notes Approved no  
  Call Number THL @ christoph.kuells @ belz_leaf_2020 Serial 104  
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Author Lim, S.; Chase, B.M.; Chevalier, M.; Reimer, P.J. url  openurl
  Title 50,000years of vegetation and climate change in the southern Namib Desert, Pella, South Africa Type Journal Article
  Year 2016 Publication (up) Palaeogeography, Palaeoclimatology, Palaeoecology Abbreviated Journal  
  Volume 451 Issue Pages 197-209  
  Keywords Climate reconstruction, Late Quaternary, Namib Desert, Pollen, Rock hyrax middens, South Africa  
  Abstract This paper presents the first continuous pollen record from the southern Namib Desert spanning the last 50,000years. Obtained from rock hyrax middens found near the town of Pella, South Africa, these data are used to reconstruct vegetation change and quantitative estimates of temperature and aridity. Results indicate that the last glacial period was characterised by increased water availability at the site relative to the Holocene. Changes in temperature and potential evapotranspiration appear to have played a significant role in determining the hydrologic balance. The record can be considered in two sections: 1) the last glacial period, when low temperatures favoured the development of more mesic Nama-Karoo vegetation at the site, with periods of increased humidity concurrent with increased coastal upwelling, both responding to lower global/regional temperatures; and 2) the Holocene, during which time high temperatures and potential evapotranspiration resulted in increased aridity and an expansion of the Desert Biome. During this latter period, increases in upwelling intensity created drier conditions at the site. Considered in the context of discussions of forcing mechanisms of regional climate change and environmental dynamics, the results from Pella stand in clear contrast with many inferences of terrestrial environmental change derived from regional marine records. Observations of a strong precessional signal and interpretations of increased humidity during phases of high local summer insolation in the marine records are not consistent with the data from Pella. Similarly, while high percentages of Restionaceae pollen has been observed in marine sediments during the last glacial period, they do not exceed 1% of the assemblage from Pella, indicating that no significant expansion of the Fynbos Biome has occurred during the last 50,000years. These findings pose interesting questions regarding the nature of environmental change in southwestern Africa, and the significance of the diverse records that have been obtained from the region.  
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  ISSN 0031-0182 ISBN Medium  
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  Notes Approved no  
  Call Number THL @ christoph.kuells @ lim_50000years_2016 Serial 107  
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Author Hamutoko, J.; Mapani, B.; Ellmies, R.; Bittner, A.; Külls, C. url  openurl
  Title A fingerprinting method for the identification of uranium sources in alluvial aquifers: An example from the Khan and Swakop Rivers, Namibia Type Journal Article
  Year 2014 Publication (up) Physics and Chemistry of the Earth, Parts A/B/C Abbreviated Journal  
  Volume 72 Issue Pages 34-42  
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  Address  
  Corporate Author Thesis  
  Publisher Pergamon Place of Publication Editor  
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  Notes Approved no  
  Call Number THL @ christoph.kuells @ Hamutoko2014fingerprinting Serial 19  
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Author Uugulu, S.; Wanke, H. url  openurl
  Title Estimation of groundwater recharge in savannah aquifers along a precipitation gradient using chloride mass balance method and environmental isotopes, Namibia Type Journal Article
  Year 2020 Publication (up) Physics and Chemistry of the Earth, Parts A/B/C Abbreviated Journal  
  Volume 116 Issue Pages 102844  
  Keywords Chloride mass balance, Groundwater recharge, Isotopic values, Precipitation gradient  
  Abstract The quantification of groundwater resources is essential especially in water scarce countries like Namibia. The chloride mass balance (CMB) method and isotopic composition were used in determining groundwater recharge along a precipitation gradient at three sites, namely: Tsumeb (600 mm/a precipitation); Waterberg (450 mm/a precipitation) and Kuzikus/Ebenhaezer (240 mm/a precipitation). Groundwater and rainwater were collected from year 2016–2017. Rainwater was collected monthly while groundwater was collected before, during and after rainy seasons. Rainwater isotopic values for δ18O and δ2H range from −10.70 to 6.10‰ and from −72.7 to 42.1‰ respectively. Groundwater isotopic values for δ18O range from −9.84 to −5.35‰ for Tsumeb; from −10.85 to −8.60‰ for Waterberg and from −8.24 to −1.56‰ for Kuzikus/Ebenhaezer, while that for δ2H range from −65.6 to −46.7‰ for Tsumeb; −69.4 to −61.2‰ for Waterberg and −54.2 to −22.7‰ for Kuzikus/Ebenhaezer. Rainwater scatters along the GMWL. Rainwater collected in January, February and March are more depleted in heavy isotopes than those in November, December, April and May. Waterberg groundwater plots on the GMWL which indicates absence of evaporation. Tsumeb groundwater plots on/close to the GMWL with an exception of groundwater from the karst Lake Otjikoto which is showing evaporation. Groundwater from Kuzikus/Ebenhaezer shows an evaporation effect, probably evaporation occurs during infiltration since it is observed in all sampling seasons. All groundwater from three sites plot in the same area with rainwater depleted in stable isotopic values, which could indicates that recharge only take place during January, February and March. CMB method revealed that Waterberg has the highest recharge rate ranging between 39.1 mm/a and 51.1 mm/a (8.7% – 11.4% of annual precipitation), Tsumeb with rates ranging from 21.1 mm/a to 48.5 mm/a (3.5% – 8.1% of annual precipitation), and lastly Kuzikus/Ebenhaezer from 3.2 mm/a to 17.5 mm/a (1.4% – 7.3% of annual precipitation). High recharge rates in Waterberg could be related to fast infiltration and absence of evaporation as indicated by the isotopic ratios. Differences in recharge rates cannot only be attributed to the precipitation gradient but also to the evaporation rates and the presence of preferential flow paths. Recharge rates estimated for these three sites can be used in managing the savannah aquifers especially at Kuzikus/Ebenhaezer where evaporation effect is observed that one can consider rain harvesting.  
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  ISSN 1474-7065 ISBN Medium  
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  Notes Approved no  
  Call Number THL @ christoph.kuells @ uugulu_estimation_2020 Serial 99  
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Author Alexander, A.C.; Ndambuki, J.M. url  openurl
  Title Impact of mine closure on groundwater resource: Experience from Westrand Basin-South Africa Type Journal Article
  Year 2023 Publication (up) Physics and Chemistry of the Earth, Parts A/B/C Abbreviated Journal  
  Volume 131 Issue Pages 103432  
  Keywords Acid mine drainage, Groundwater quality, Mine closure, Spatio-temporal variation, Westrand Basin  
  Abstract The mining sector is at the edge of expanding to cater for natural resources that are much needed for technological development and manufacturing. Mushrooming of mines will consequently increase the number of mines closure. Moreover, mines closure have adverse impact on the environment at large and specifically on water resources. This study analyses historical groundwater quality parameters in mine intensive basin of Westrand Basin (WRB) to understand the status of groundwater quality in relation to mining activities and mine closure. Geographic information system (GIS) was used to map the spatio-temporal variation of groundwater quality in the basin and groundwater quality index (GQI) to evaluate its status. The coefficient of variation (CV) was applied to understand the stability of groundwater quality after the mine closure. Results indicated unstable and altered trend with increasing levels of acidity and salts concentration around the mines vicinity following the mine closure. The resultant maps indicated a significant deterioration of groundwater quality around the WRB with concentrations decreasing downstream. Obtained average GQI for the study period of 1996–2015 suggested a moderate groundwater quality at a range of GQI = 64–73. The CV indicated varying water quality at CV \textgreater 30% suggesting presence of source of contamination. Observed groundwater quality trends in Westrand basin suggested that mines closure present potential threat on groundwater quality and thus, a need for a robust mine closure plan and implementation.  
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  ISSN 1474-7065 ISBN Medium  
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  Notes Approved no  
  Call Number THL @ christoph.kuells @ alexander_impact_2023 Serial 134  
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Author Mathuthu, M.; Uushona, V.; Indongo, V. url  openurl
  Title Radiological safety of groundwater around a uranium mine in Namibia Type Journal Article
  Year 2021 Publication (up) Physics and Chemistry of the Earth, Parts A/B/C Abbreviated Journal  
  Volume 122 Issue Pages 102915  
  Keywords Groundwater, ICP-MS, Radiological hazard, Uranium mining  
  Abstract Uranium mining activities produce the main element used in nuclear energy production. However, it can also negatively affect the environment including groundwater by release of residues or effluent containing radioactive elements. The study investigated the concentration and radiological hazard of uranium in groundwater and seepage water from the tailings of a uranium mine in Namibia. Inductively Coupled Plasma Mass Spectrometry (ICP-MS) was used to assess the concentration of uranium in the groundwater and seepage water and the radiological hazards were determined. The radiological hazard indices Radium equivalent activity (Raeq), Absorbed dose (D), Annual Effective Dose equivalent (AEDE), External hazard index (Hex) and Internal hazard index (Hin) were determined and compared to limits recommended by United Nations Scientific Committee on the Effects of Atomic Radiation (UNSCEAR). The calculated average value of D and Hin of groundwater is 108.11nGyh−1 and 1.26, respectively and are above the UNSCEAR values (55 nGyh−1 and 1). Further, the average values of Raeq, AEDE and Hex were below the recommended values. The isotopic ratio of uranium radionuclides in groundwater indicates that the uranium in the sampled groundwater is below 1 suggesting it is not natural uranium present but a possible contamination from the mine seepage. The radiological hazard parameters of the seepage water were above the recommended values and thus pose a radiation risk to human and environment.  
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  ISSN 1474-7065 ISBN Medium  
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  Notes Approved no  
  Call Number THL @ christoph.kuells @ mathuthu_radiological_2021 Serial 160  
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