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Lawrinenko, M.; Kurwadkar, S.; Wilkin, R.T. |
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Title |
Long-term performance evaluation of zero-valent iron amended permeable reactive barriers for groundwater remediation – A mechanistic approach |
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Journal Article |
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Year |
2023 |
Publication |
Geoscience Frontiers |
Abbreviated Journal |
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14 |
Issue |
2 |
Pages |
101494 |
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Keywords |
Geochemistry, Iron, Permeable reactive barrier, Plating reactions, Reduction potential, Surface passivation |
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Abstract |
Permeable reactive barriers (PRBs) are used for groundwater remediation at contaminated sites worldwide. This technology has been efficient at appropriate sites for treating organic and inorganic contaminants using zero-valent iron (ZVI) as a reductant and as a reactive material. Continued development of the technology over the years suggests that a robust understanding of PRB performance and the mechanisms involved is still lacking. Conflicting information in the scientific literature downplays the critical role of ZVI corrosion in the remediation of various organic and inorganic pollutants. Additionally, there is a lack of information on how different mechanisms act in tandem to affect ZVI-groundwater systems through time. In this review paper, we describe the underlying mechanisms of PRB performance and remove isolated misconceptions. We discuss the primary mechanisms of ZVI transformation and aging in PRBs and the role of iron corrosion products. We review numerous sites to reinforce our understanding of the interactions between groundwater contaminants and ZVI and the authigenic minerals that form within PRBs. Our findings show that ZVI corrosion products and mineral precipitates play critical roles in the long-term performance of PRBs by influencing the reactivity of ZVI. Pore occlusion by mineral precipitates occurs at the influent side of PRBs and is enhanced by dissolved oxygen and groundwater rich in dissolved solids and high alkalinity, which negatively impacts hydraulic conductivity, allowing contaminants to potentially bypass the treatment zone. Further development of site characterization tools and models is needed to support effective PRB designs for groundwater remediation. |
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1674-9871 |
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THL @ christoph.kuells @ lawrinenko_long-term_2023 |
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143 |
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Zhao, Y.; Li, X.; Lei, L.; Chen, L.; Luo, Z. |
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Title |
Permeability evolution mechanism and the optimum permeability determination of uranium leaching from low-permeability sandstone treated with low-frequency vibration |
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Journal Article |
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Year |
2023 |
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Journal of Rock Mechanics and Geotechnical Engineering |
Abbreviated Journal |
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15 |
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10 |
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2597-2610 |
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Chemical reactive rate, Low-frequency vibration, Low-permeability sandstone, Optimum permeability, Permeability evolution mechanism, Uranium migration |
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Abstract |
Low-frequency vibrations can effectively improve natural sandstone permeability, and higher vibration frequency is associated with larger permeability. However, the optimum permeability and permeability evolution mechanism for uranium leaching and the relationship between permeability and the change of chemical reactive rate affecting uranium leaching have not been determined. To solve the above problems, in this study, identical homogeneous sandstone samples were selected to simulate low-permeability sandstone; a permeability evolution model considering the combined action of vibration stress, pore water pressure, water flow impact force, and chemical erosion was established; and vibration leaching experiments were performed to test the model accuracy. Both the permeability and chemical reactions were found to simultaneously restrict U6+ leaching, and the vibration treatment increased the permeability, causing the U6+ leaching reaction to no longer be diffusion-constrained but to be primarily controlled by the reaction rate. Changes of the model calculation parameters were further analyzed to determine the permeability evolution mechanism under the influence of vibration and chemical erosion, to prove the correctness of the mechanism according to the experimental results, and to develop a new method for determining the optimum permeability in uranium leaching. The uranium leaching was found to primarily follow a process consisting of (1) a permeability control stage, (2) achieving the optimum permeability, (3) a chemical reactive rate control stage, and (4) a channel flow stage. The resolution of these problems is of great significance for facilitating the application and promotion of low-frequency vibration in the CO2 + O2 leaching process. |
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1674-7755 |
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THL @ christoph.kuells @ zhao_permeability_2023 |
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198 |
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Hdeib, R.; Aouad, M. |
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Title |
Rainwater harvesting systems: An urban flood risk mitigation measure in arid areas |
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Journal Article |
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2023 |
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Water Science and Engineering |
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16 |
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3 |
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219-225 |
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Rainwater harvesting, Urban floods, Flood map, Hydrodynamic model, Built environment, Arid areas |
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Rainwater harvesting (RWH) systems have been developed to compensate for shortage in the water supply worldwide. Such systems are not very common in arid areas, particularly in the Gulf Region, due to the scarcity of rainfall and their reduced efficiency in covering water demand and reducing water consumption rates. In spite of this, RWH systems have the potential to reduce urban flood risks, particularly in densely populated areas. This study aimed to assess the potential use of RWH systems as urban flood mitigation measures in arid areas. Their utility in the retention of stormwater runoff and the reduction of water depth and extent were evaluated. The study was conducted in a residential area in Bahrain that experienced waterlogging after heavy rainfall events. The water demand patterns of housing units were analyzed, and the daily water balance for RWH tanks was evaluated. The effect of the implementation of RWH systems on the flood volume was evaluated with a two-dimensional hydrodynamic model. Flood simulations were conducted in several rainfall scenarios with different probabilities of occurrence. The results showed significant reductions in the flood depth and flood extent, but these effects were highly dependent on the rainfall intensity of the event. RWH systems are effective flood mitigation measures, particularly in urban arid regions short of proper stormwater control infrastructure, and they enhance the resilience of the built environment to urban floods. |
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1674-2370 |
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THL @ christoph.kuells @ Hdeib2023219 |
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242 |
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Akter, A.; Tanim, A.H.; Islam, M.K. |
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Title |
Possibilities of urban flood reduction through distributed-scale rainwater harvesting |
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2020 |
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Water Science and Engineering |
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13 |
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2 |
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95-105 |
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Low-impact development (LID), SWMM, HEC-RAS, Remote sensing, Urban flooding, Inundation depth |
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Urban flooding in Chittagong City usually occurs during the monsoon season and a rainwater harvesting (RWH) system can be used as a remedial measure. This study examines the feasibility of rain barrel RWH system at a distributed scale within an urbanized area located in the northwestern part of Chittagong City that experiences flash flooding on a regular basis. For flood modeling, the storm water management model (SWMM) was employed with rain barrel low-impact development (LID) as a flood reduction measure. The Hydrologic Engineering Center’s River Analysis System (HEC-RAS) inundation model was coupled with SWMM to observe the detailed and spatial extent of flood reduction. Compared to SWMM simulated floods, the simulated inundation depth using remote sensing data and the HEC-RAS showed a reasonable match, i.e., the correlation coefficients were found to be 0.70 and 0.98, respectively. Finally, using LID, i.e., RWH, a reduction of 28.66% could be achieved for reducing flood extent. Moreover, the study showed that 10%–60% imperviousness of the subcatchment area can yield a monthly RWH potential of 0.04–0.45 m3 from a square meter of rooftop area. The model can be used for necessary decision making for flood reduction and to establish a distributed RWH system in the study area. |
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1674-2370 |
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THL @ christoph.kuells @ Akter202095 |
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247 |
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Rajfur, M.; Kłos, A.; Wacławek, M. |
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Sorption properties of algae Spirogyra sp. and their use for determination of heavy metal ions concentrations in surface water |
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Journal Article |
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2010 |
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Bioelectrochemistry |
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80 |
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1 |
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81-86 |
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Biomonitoring, Heavy metal ions, Algae sp., Sorption kinetics, Langmuir isotherm |
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Kinetics of heavy-metal ions sorption by alga Spirogyra sp. was evaluated experimentally in the laboratory, using both the static and the dynamic approach. The metal ions – Mn2+, Cu2+, Zn2+ and Cd2+ – were sorbed from aqueous solutions of their salts. The static experiments showed that the sorption equilibria were attained in 30min, with 90-95% of metal ions sorbed in first 10min of each process. The sorption equilibria were approximated with the Langmuir isotherm model. The algae sorbed each heavy metal ions proportionally to the amount of this metal ions in solution. The experiments confirmed that after 30min of exposition to contaminated water, the concentration of heavy metal ions in the algae, which initially contained small amounts of these metal ions, increased proportionally to the concentration of metal ions in solution. The presented results can be used for elaboration of a method for classification of surface waters that complies with the legal regulations. |
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1567-5394 |
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A Selection of Papers presented at the 4th International Workshop on Surface Modification for Chemical and Biochemical Sensing (SMCBS 2009) |
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THL @ christoph.kuells @ Rajfur201081 |
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283 |
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