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Jin, Z.; Külls, C. |
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FDM based OA-ICOS for high accuracy 13C quantification in gaseous CO2 |
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2020 |
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Earth and Environmental Science |
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EES |
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446 |
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3 |
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032061 |
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THL @ christoph.kuells @ Jin2020fdm |
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16 |
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Jana, A.; Unni, A.; Ravuru, S.S.; Das, A.; Das, D.; Biswas, S.; Sheshadri, H.; De, S. |
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In-situ polymerization into the basal spacing of LDH for selective and enhanced uranium adsorption: A case study with real life uranium alkaline leach liquor |
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Journal Article |
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Year |
2022 |
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Chemical Engineering Journal |
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428 |
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131180 |
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In-situ polymerization, Layered double hydroxide, Leach liquor, Uranium adsorption, Uranium recovery |
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Uranium is used as a fuel for nuclear power plant and can be extracted from different ores, mainly acidic (silicious ore) and alkaline (carbonate ore). Recovery of uranium through acid leaching from silicious ore is well established, whereas, alkaline leaching from carbonate ore is challenging due to the excessive salinity of leach liquor and high concentration of carbonate, bicarbonate and sulphate. Herein, two monomers, acrylic acid (AA) and N, N-methylene bisacrylamide (BAM), selective towards uranyl were intercalated in-situ into the interlayer, followed by their polymerization and cross-linking to form novel polymer intercalated hybrid layered double hydroxide (LDH). The LDH acts as a backbone to overcome coiling and swelling of polymer and anchors them as free-standing. Various parameters, like, the type of metal ions, monomer ratio (AA: BAM) and metal ion ratio (M2+:M3+), were studied to determine the optimum conditions for effective intercalation and polymerization of monomers. Magnesium aluminum (MgAl) LDH with a cross-linked polymer having a monomer ratio of 3:2 (AA: BAM) as intercalating species showed maximum efficiency of uranyl adsorption (1456 mg/g at 30 °C) with highest capacity so far. The distribution coefficient (Kd, l/mg) in the order of 105 suggested that the adsorbent was highly selective for uranyl in the presence of different cations, anions and humic acid. The adsorbent extracts uranium effectively and selectively from a real-life alkaline leach liquor with an efficiency of 96% at 5 g/l dose. Uranium can be recovered from the adsorbent in the form of sodium di-uranate using 2(M) NaOH and was reused for eight cycles. |
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1385-8947 |
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THL @ christoph.kuells @ jana_-situ_2022 |
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209 |
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Morin, E.; Grodek, T.; Dahan, O.; Benito, G.; Külls, C.; Jacoby, Y.; Van Langenhove, G.; Seely, M.; Enzel, Y. |
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Flood routing and alluvial aquifer recharge along the ephemeral arid Kuiseb River, Namibia |
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2009 |
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Journal of Hydrology |
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368 |
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1-4 |
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262-275 |
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THL @ christoph.kuells @ Morin2009flood |
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26 |
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Gómez, P.; Garralón, A.; Buil, B.; Turrero, M.J.; Sánchez, L.; Cruz, B. de la |
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Modeling of geochemical processes related to uranium mobilization in the groundwater of a uranium mine |
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Journal Article |
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2006 |
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Science of The Total Environment |
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366 |
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1 |
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295-309 |
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Geochemical modeling, Granite, Groundwater, Uranium mine, Uranium retention |
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This paper describes the processes leading to uranium distribution in the groundwater of five boreholes near a restored uranium mine (dug in granite), and the environmental impact of restoration work in the discharge area. The groundwater uranium content varied from \textless1 μg/L in reduced water far from the area of influence of the uranium ore-containing dyke, to 104 μg/L in a borehole hydraulically connected to the mine. These values, however, fail to reflect a chemical equilibrium between the water and the pure mineral phases. A model for the mobilization of uranium in this groundwater is therefore proposed. This involves the percolation of oxidized waters through the fractured granite, leading to the oxidation of pyrite and arsenopyrite and the precipitation of iron oxyhydroxides. This in turn leads to the dissolution of the primary pitchblende and, subsequently, the release of U(VI) species to the groundwater. These U(VI) species are retained by iron hydroxides. Secondary uranium species are eventually formed as reducing conditions are re-established due to water–rock interactions. |
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0048-9697 |
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THL @ christoph.kuells @ gomez_modeling_2006 |
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162 |
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Klaus, J.; Külls, C.; Dahan, O. |
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Evaluating the recharge mechanism of the Lower Kuiseb Dune area using mixing cell modeling and residence time data |
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2008 |
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Journal of Hydrology |
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358 |
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3-4 |
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304-316 |
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THL @ christoph.kuells @ Klaus2008evaluating |
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28 |
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Boumaiza, L.; Ammar, S.B.; Chesnaux, R.; Stotler, R.L.; Mayer, B.; Huneau, F.; Johannesson, K.H.; Levison, J.; Knöller, K.; Stumpp, C. |
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Nitrate sources and transformation processes in groundwater of a coastal area experiencing various environmental stressors |
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Journal Article |
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2023 |
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Journal of Environmental Management |
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345 |
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118803 |
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Aquifer, Denitrification, MixSIAR, Nitrate, Nitrification, Stable isotopes |
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In coastal salinized groundwater systems, contamination from various nitrate (NO3) inputs combined with complex hydrogeochemical processes make it difficult to distinguish NO3 sources and identify potential NO3 transformtation processes. Effective field-based NO3 studies in coastal areas are needed to improve the understanding of NO3 contamination dynamics in groundwater of such complex coastal systems. This study focuses on a typical Mediterranean coastal agricultural area, located in Tunisia, experiencing substantial NO3 contamination from multiple anthropogenic sources. Here, multiple isotopic tracers (δ18OH2O, δ2HH2O, δ15NNO3, δ18ONO3, and δ11B) combined with a Bayesian isotope MixSIAR model are used (i) to identify the major NO3 sources and their contributions, and (ii) to describe the potential NO3 transformation processes. The measured NO3 concentrations in groundwater are above the natural baseline threshold, suggesting anthropogenic influence. The measured isotopic composition of NO3 indicates that manure, soil organic matter, and sewage are the potential sources of NO3, while δ11B values constrain the NO3 contamination to manure; a finding that is supported by the results of MixSIAR model revealing that manure-derived NO3 dominates over other likely sources. Nitrate derived from manure in the study area is attributed to organic fertilizers used to promote crop growth, and livestock that deposit manure directly on the ground surface. Evidence for ongoing denitrification in groundwaters of the study area is supported by an enrichment in both 15N and 18O in the remaining NO3, although isotopic mass balances between the measured and the theoretical δ18ONO3 values also suggest the occurrence of nitrification. The simultaneous occurrence of these biogeochemical processes with heterogeneous distribution across the study area reflect the complexity of interactions within the investigated coastal aquifer. The multiple isotopic tracer approach used here can identify the effect of multiple NO3 anthropogenic activities in coastal environments, which is fundamental for sustainable groundwater resources management. |
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0301-4797 |
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THL @ christoph.kuells @ boumaiza_nitrate_2023 |
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170 |
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Dąbrowska, J.; Orellana, A.E.M.; Kilian, W.; Moryl, A.; Cielecka, N.; Michałowska, K.; Policht-Latawiec, A.; Michalski, A.; Bednarek, A.; Włóka, A. |
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Between flood and drought: How cities are facing water surplus and scarcity |
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Journal Article |
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2023 |
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Journal of Environmental Management |
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345 |
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118557 |
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Urban ecosystem management, Urban floods, Urban droughts, Nature-based solutions, Climate change, Urban resilience |
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Droughts and floods are weather-related hazards affecting cities in all climate zones and causing human deaths and material losses on all inhabited continents. The aim of this article is to review, analyse and discuss in detail the problems faced by urban ecosystems due to water surplus and scarcity, as well as the need of adaptation to climate change taking into account the legislation, current challenges and knowledge gaps. The literature review indicated that urban floods are much more recognised than urban droughts. Amongst floods, flash floods are currently the most challenging, which by their nature are difficult to monitor. Research and adaptation measures related to water-released hazards use cutting-edge technologies for risk assessment, decision support systems, or early warning systems, among others, but in all areas knowledge gaps for urban droughts are evident. Increasing urban retention and introducing Low Impact Development and Nature-based Solutions is a remedy for both droughts and floods in cities. There is the need to integrate flood and drought disaster risk reduction strategies and creating a holistic approach. |
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0301-4797 |
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THL @ christoph.kuells @ Dabrowska2023118557 |
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227 |
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Mabrouk, M.; Han, H.; Fan, C.; Abdrabo, K.I.; Shen, G.; Saber, M.; Kantoush, S.A.; Sumi, T. |
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Assessing the effectiveness of nature-based solutions-strengthened urban planning mechanisms in forming flood-resilient cities |
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Journal Article |
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2023 |
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Journal of Environmental Management |
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344 |
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118260 |
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Flood, Urban planning, Sustainable cities, LID, Natural-based solutions, Alexandria |
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Cities have experienced rapid urbanization-induced harsh climatic events, especially flooding, inevitably resulting in negative and irreversible consequences for urban resilience and endangering residents’ lives. Numerous studies have analyzed the effects of anthropogenic practices (land use changes and urbanization) on flood forecasting. However, non-structural mitigation’s effectiveness, like Nature-Based Solutions (NBS), has yet to receive adequate attention, particularly in the Middle East and North Africa (MENA) region, which have become increasingly significant and indispensable for operationalizing cities efficiently. Therefore, our study investigated the predictive influence of incorporating one of the most common NBS strategies called low-impact development tools (LID) (such as rain gardens, bio-retention cells, green roofs, infiltration trenches, permeable pavement, and vegetative swale) during the urban planning of Alexandria, Egypt, which experiences the harshest rainfall annually and includes various urban patterns. City characteristics-dependent 14 LID scenarios were simulated with recurrence intervals ranging from 2 to 100 years using the LID Treatment Train Tool (LID TTT), depending on calibrated data from 2015 to 2020, by the Nash-Sutcliffe efficiency index and deterministic coefficient, and root-mean-square error with values of 0.97, 0.91, and 0.31, respectively. Our findings confirmed the significant effectiveness of combined LID tools on total flood runoff volume reduction by 73.7%, revealing that different urban patterns can be used in flood-prone cities, provided LID tools are considered in city planning besides grey infrastructure to achieve optimal mitigation. These results, which combined multiple disciplines and were not explicitly mentioned in similar studies in developing countries, may assist municipalities’ policymakers in planning flood-resistant, sustainable cities. |
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0301-4797 |
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THL @ christoph.kuells @ Mabrouk2023118260 |
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232 |
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Baptista, V.S.G.; Coelho, V.H.R.; Bertrand, G.F.; Silva, G.B.L. da; Caicedo, N.O.L.; Montenegro, S.M.G.L.; Stefan, C.; Glass, J.; Heim, R.; Conrad, A.; Almeida, C. das N. |
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Rooftop water harvesting for managed aquifer recharge and flood mitigation in tropical cities: Towards a strategy of co-benefit evaluations in João Pessoa, northeast Brazil |
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Journal Article |
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2023 |
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Journal of Environmental Management |
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342 |
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118034 |
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Flood control, Groundwater, Injection well, Stormwater management, Urban drainage, Aquifer storage and recovery |
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Intense urbanisation in many coastal areas has led to intensification of groundwater consumption, while reducing permeable areas and increasing the frequency and magnitude of flooding. Among the potential strategies to compensate for these adverse effects, which are expected to become worse as a result of climate change, rooftop rainwater harvesting (RWH) in combination with managed aquifer recharge (MAR), may be indicated. This work investigated the performance of different configurations of such a system, tested as a twofold sustainable stormwater and domestic water management tool in a tropical metropole (João Pessoa, Brazil). This area located over a sedimentary aquifer system illustrates the water security challenges of densely urbanised areas in southern cities. To that end, several configurations of rooftop catchments and storage volumes were evaluated, by simulating a MAR-RWH system connected to the regional unconfined aquifer (Barreiras Formation) through a 6″ diameter injection well. Rainfall-runoff-recharge processes and water balances were simulated using monitored high-temporal resolution rainfall data. The results showed that catchments ranging from 180 to 810 m2, connected to tanks from 0.5 to 30.0 m³, are the optimal solutions in terms of efficient rainwater retention and peak flow reduction. These solutions provided mean annual estimates of aquifer recharge between 57 and 255 m³/yr from 2004 to 2019. The results of this study highlight the opportunity for MAR schemes to reconcile stormwater management and water supply goals. |
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0301-4797 |
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THL @ christoph.kuells @ Baptista2023118034 |
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237 |
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Emparanza, A.R.; Kampmann, R.; Caso, F.D.; Morales, C.; Nanni, A. |
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Durability assessment of GFRP rebars in marine environments |
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Journal Article |
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2022 |
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Construction and Building Materials |
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329 |
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127028 |
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Composite FRP rebar, Durability, Service life, Marine structures, Reinforced concrete |
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Technologies developed over the last two decades have facilitated the use of glass fiber reinforced polymer (GFRP) bars as internal reinforcement for concrete structures, specially in coastal environments, mainly due to their corrosion resistance. To-date, most durability studies have focused on a single mechanical parameter (tensile strength) and a single aging environment (exposure to high alkalinity). However, knowledge gaps exists in understanding how other mechanical parameters and relevant conditioning environments may affect the durability of GFRP bars. To this end, this study assesses the durability for different physio-mechanical properties of GFRP rebars, post exposure to accelerated conditioning in seawater. Six different GFRP rebar types were submerged in seawater tanks, at various temperatures (23°C, 40°C and 60°C) for different time periods (60, 120, 210 and 365 days). In total six different physio-mechanical properties were assessed, including: tensile strength, E-modulus, transverse and horizontal shear strength, micro-structural composition and lastly, bond strength. It was inferred that rebars with high moisture absorption resulted in poor durability, in that it affected mainly the tensile strength. Based on the Arrhenius model, at 23°C all the rebars that met the acceptance criteria by ASTM D7957 are expected to retain 85% of the tensile strength capacity. |
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0950-0618 |
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THL @ christoph.kuells @ Ruizemparanza2022127028 |
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83 |
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