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Author Müller, M.; Alaoui, A.; Külls, C.; Leistert, H.; Meusburger, K.; Stumpp, C.; Weiler, M.; Alewell, C.
Title Tracking water pathways in steep hillslopes by δ18O depth profiles of soil water Type Journal Article
Year 2014 Publication Journal of hydrology Abbreviated Journal
Volume (down) 519 Issue Pages 340-352
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Corporate Author Thesis
Publisher Elsevier Place of Publication Editor
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Notes Approved no
Call Number THL @ christoph.kuells @ Mueller2014tracking Serial 20
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Author Tan, K.; Li, C.; Liu, J.; Qu, H.; Xia, L.; Hu, Y.; Li, Y.
Title A novel method using a complex surfactant for in-situ leaching of low permeable sandstone uranium deposits Type Journal Article
Year 2014 Publication Hydrometallurgy Abbreviated Journal
Volume (down) 150 Issue Pages 99-106
Keywords Complex surfactant, In-situ leaching of uranium mining, Leaching kinetics, Low permeable sandstone uranium deposit, Resin adsorption and elution
Abstract Applications of a complex surfactant developed in-house to in-situ leaching of low permeable sandstone uranium deposits are described based on results from agitation leaching, column leaching, resin adsorption, and elution experiments using uranium containing solution from the in-situ leaching site. The results of agitation leaching experiments show that adding surfactant with different concentrations into leaching solution improves the leaching rate of uranium. The maximum leaching rate of uranium from agitation leaching reached 92.6% at an added surfactant concentration of 10mg/l. Result of column leaching experiment shows that adding surfactant with varying concentrations into leaching solutions increased the permeability coefficient of ore-bearing layer by 42.7–86.8%. The leaching rate of uranium from column leaching increased by 58.0% and reached 85.8%. The result of kinetic analysis shows that for the extraction of uranium controlled by diffusion without surfactant the apparent rate constant 0.0023/d changed to 0.0077/d for the extraction with surfactant controlled by both diffusion and surface chemical reactions. Results from resin adsorption and elution experiments show that there was no influence on resin adsorption and elution of uranium with an addition of 50mg/l surfactant to production solution from in-situ leaching. The adsorption curve, sorption capacity of resin, recycling of resin remained the same as without adding any surfactant. Introducing complex surfactant to leaching solution increased the peak concentration of uranium in eluents, reduced the residual uranium content in resin, and promoted the elution efficiency. The method of using a complex surfactant for in-situ leaching is useful for low permeable sandstone uranium deposits.
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ISSN 0304-386x ISBN Medium
Area Expedition Conference
Notes Approved no
Call Number THL @ christoph.kuells @ tan_novel_2014 Serial 201
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Author Alvarado, J.A.C.; Balsiger, B.; Röllin, S.; Jakob, A.; Burger, M.
Title Radioactive and chemical contamination of the water resources in the former uranium mining and milling sites of Mailuu Suu (Kyrgyzstan) Type Journal Article
Year 2014 Publication Journal of Environmental Radioactivity Abbreviated Journal
Volume (down) 138 Issue Pages 1-10
Keywords Former uranium mines, Kyrgyzstan, Mailuu Suu, Uranium contamination, Water resources
Abstract An assessment of the radioactive and chemical contamination of the water resources at the former uranium mines and processing sites of Mailuu-Suu, in Kyrgyzstan, was carried out. A large number of water samples were collected from the drinking water distribution system (DWDS), rivers, shallow aquifers and drainage water from the mine tailings. Radionuclides and trace metal contents in water from the DWDS were low in general, but were extremely high for Fe, Al and Mn. These elements were associated with the particle fractions in the water and strongly correlated with high turbidity levels. Overall, these results suggest that water from the DWDS does not represent a serious radiological hazard to the Mailuu Suu population. However, due to the high turbidities and contents of some elements, this water is not good quality drinking water. Water from artesian and dug wells were characterized by elevated levels of U (up to 10 μg/L) and some trace elements (e.g. As, Se, Cr, V and F) and anions (e.g. Cl−, NO3−, SO42−). In two artesian wells, the WHO guideline value of 10 μg/L for As in water was exceeded. As the artesian wells are used as a source of drinking water by a large number of households, special care should be taken in order to stay within the WHO recommended guidelines. Drainage water from the mine tailings was as expected highly contaminated with many chemicals (e.g. As) and radioactive contaminants (e.g. U). The concentrations of U were more than 200 times the WHO guideline value of 30 μg/L for U in drinking water. A large variation in 234U/238U isotopic ratios in water was observed, with values near equilibrium at the mine tailings and far from equilibrium outside this area (reaching ratios of 2.3 in the artesian well). This result highlights the potential use of this ratio as an indicator of the origin of U contamination in Mailuu Suu.
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ISSN 0265-931x ISBN Medium
Area Expedition Conference
Notes Approved no
Call Number THL @ christoph.kuells @ alvarado_radioactive_2014 Serial 123
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Author Ingham, E.S.; Cook, N.J.; Cliff, J.; Ciobanu, C.L.; Huddleston, A.
Title A combined chemical, isotopic and microstructural study of pyrite from roll-front uranium deposits, Lake Eyre Basin, South Australia Type Journal Article
Year 2014 Publication Geochimica et Cosmochimica Acta Abbreviated Journal
Volume (down) 125 Issue Pages 440-465
Keywords
Abstract The common sulfide mineral pyrite is abundant throughout sedimentary uranium systems at Pepegoona, Pepegoona West and Pannikan, Lake Eyre Basin, South Australia. Combined chemical, isotopic and microstructural analysis of pyrite indicates variation in fluid composition, sulfur source and precipitation conditions during a protracted mineralization event. The results show the significant role played by pyrite as a metal scavenger and monitor of fluid changes in low-temperature hydrothermal systems. In-situ micrometer-scale sulfur isotope analyses of pyrite demonstrated broad-scale isotopic heterogeneity (δ34S=−43.9 to +32.4‰VCDT), indicative of complex, multi-faceted pyrite evolution, and sulfur derived from more than a single source. Preserved textures support this assertion and indicate a genetic model involving more than one phase of pyrite formation. Authigenic pyrite underwent prolonged evolution and recrystallization, evidenced by a genetic relationship between archetypal framboidal aggregates and pyrite euhedra. Secondary hydrothermal pyrite commonly displays hyper-enrichment of several trace elements (Mn, Co, Ni, As, Se, Mo, Sb, W and Tl) in ore-bearing horizons. Hydrothermal fluids of magmatic and meteoric origins supplied metals to the system but the geochemical signature of pyrite suggests a dominantly granitic source and also the influence of mafic rock types. Irregular variation in δ34S, coupled with oscillatory trace element zonation in secondary pyrite, is interpreted in terms of continuous variations in fluid composition and cycles of diagenetic recrystallization. A late-stage oxidizing fluid may have mobilized selenium from pre-existing pyrite. Subsequent restoration of reduced conditions within the aquifer caused ongoing pyrite re-crystallization and precipitation of selenium as native selenium. These results provide the first qualitative constraints on the formation mechanisms of the uranium deposits at Beverley North. Insights into depositional conditions and sources of both sulfide and uranium mineralization and an improved understanding of pyrite geochemistry can also underpin an effective vector for uranium exploration at Beverley North and other sedimentary systems of the Lake Eyre Basin, as well as in comparable geological environments elsewhere.
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ISSN 0016-7037 ISBN Medium
Area Expedition Conference
Notes Approved no
Call Number THL @ christoph.kuells @ ingham_combined_2014 Serial 188
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Author Shams, A.
Title A rediscovered-new ‘Qanat’ system in the High Mountains of Sinai Peninsula, with Levantine reflections Type Journal Article
Year 2014 Publication Journal of Arid Environments Abbreviated Journal
Volume (down) 110 Issue Pages 69-74
Keywords Foggara, Irrigation, Levant, Qanat, Sinai Peninsula
Abstract Since the Achaemenid Empire in 532–332 BCE, the ‘Qanat’ became the central irrigation system in the arid and semi-arid lands. Several terms are used for ‘Qanat’ in different regions, including the Karez, Qanat, Falaj type Daudi, Qanat Romani, Fuqara (Foggara), or Khettara as known in Central Asia, Persia, Southeast Arabia, Levant, North Africa, or Morocco respectively. Typically, the ground, spring or surface water (i.e. seasonal floods or river-fed) sources feed similar irrigation system. Based on thirteen years of extensive survey and analysis work (i.e. Sinai Peninsula Research 2000–2013 CE), this paper presents a rediscovered-new Qanat system in the High Mountains of Sinai Peninsula (i.e. UNESCO World Heritage Site ‘WHS’ no. 954) under chronological open question with Levantine reflections. In 1970s CE, the present Sinaitic site of Farsh Abu A’lwan or the anciently known Farsh Shamma’a was archaeologically surveyed without a direct reference to the Qanat system in-situ. Scientifically, it is an argumentative and unique Qanat system in terms of chronology, location (region), site (local-setting), water source, size and household utility. It is the only discovered ‘Qanat’ across the Sinai, connecting the Near East and North Africa.
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Series Editor Series Title Abbreviated Series Title
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ISSN 0140-1963 ISBN Medium
Area Expedition Conference
Notes Approved no
Call Number THL @ christoph.kuells @ Shams201469 Serial 248
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