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Author (up) Eliades, M.; Bruggeman, A.; Djuma, H.; Christofi, C.; Kuells, C. url  doi
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  Title Quantifying Evapotranspiration and Drainage Losses in a Semi-Arid Nectarine (Prunus persica var. nucipersica) Field with a Dynamic Crop Coefficient (Kc) Derived from Leaf Area Index Measurements Type Journal Article
  Year 2022 Publication Water Abbreviated Journal  
  Volume 14 Issue 5 Pages  
  Keywords  
  Abstract Quantifying evapotranspiration and drainage losses is essential for improving irrigation efficiency. The FAO-56 is the most popular method for computing crop evapotranspiration. There is, however, a need for locally derived crop coefficients (Kc) with a high temporal resolution to reduce errors in the water balance. The aim of this paper is to introduce a dynamic Kc approach, based on Leaf Area Index (LAI) observations, for improving water balance computations. Soil moisture and meteorological data were collected in a terraced nectarine (Prunus persica var. nucipersica) orchard in Cyprus, from 22 March 2019 to 18 November 2021. The Kc was derived as a function of the canopy cover fraction (c), from biweekly in situ LAI measurements. The use of a dynamic Kc resulted in Kc estimates with a bias of 17 mm and a mean absolute error of 0.8 mm. Evapotranspiration (ET) ranged from 41% of the rainfall (P) and irrigation (I) in the wet year (2019) to 57% of P + I in the dry year (2021). Drainage losses from irrigation (DR_I) were 44% of the total irrigation. The irrigation efficiency in the nectarine field could be improved by reducing irrigation amounts and increasing the irrigation frequency. Future studies should focus on improving the dynamic Kc approach by linking LAI field observations with remote sensing observations and by adding ground cover observations.  
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  ISSN 2073-4441 ISBN Medium  
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  Notes Approved no  
  Call Number THL @ christoph.kuells @ w14050734 Serial 85  
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Author (up) Emparanza, A.R.; Kampmann, R.; Caso, F.D.; Morales, C.; Nanni, A. url  openurl
  Title Durability assessment of GFRP rebars in marine environments Type Journal Article
  Year 2022 Publication Construction and Building Materials Abbreviated Journal  
  Volume 329 Issue Pages 127028  
  Keywords Composite FRP rebar, Durability, Service life, Marine structures, Reinforced concrete  
  Abstract Technologies developed over the last two decades have facilitated the use of glass fiber reinforced polymer (GFRP) bars as internal reinforcement for concrete structures, specially in coastal environments, mainly due to their corrosion resistance. To-date, most durability studies have focused on a single mechanical parameter (tensile strength) and a single aging environment (exposure to high alkalinity). However, knowledge gaps exists in understanding how other mechanical parameters and relevant conditioning environments may affect the durability of GFRP bars. To this end, this study assesses the durability for different physio-mechanical properties of GFRP rebars, post exposure to accelerated conditioning in seawater. Six different GFRP rebar types were submerged in seawater tanks, at various temperatures (23°C, 40°C and 60°C) for different time periods (60, 120, 210 and 365 days). In total six different physio-mechanical properties were assessed, including: tensile strength, E-modulus, transverse and horizontal shear strength, micro-structural composition and lastly, bond strength. It was inferred that rebars with high moisture absorption resulted in poor durability, in that it affected mainly the tensile strength. Based on the Arrhenius model, at 23°C all the rebars that met the acceptance criteria by ASTM D7957 are expected to retain 85% of the tensile strength capacity.  
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  ISSN 0950-0618 ISBN Medium  
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  Notes Approved no  
  Call Number THL @ christoph.kuells @ Ruizemparanza2022127028 Serial 83  
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Author (up) French, K. url  openurl
  Title Indigenous knowledge, water management, and learning from our collective past Type Journal Article
  Year 2022 Publication Journal of Anthropological Archaeology Abbreviated Journal  
  Volume 68 Issue Pages 101466  
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  ISSN 0278-4165 ISBN Medium  
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  Notes Approved no  
  Call Number THL @ christoph.kuells @ French2022101466 Serial 253  
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Author (up) Grozeva, N.G.; Radwan, J.; Beaucaire, C.; Descostes, M. url  openurl
  Title Reactive transport modeling of U and Ra mobility in roll-front uranium deposits: Parameters influencing 226Ra/238U disequilibria Type Journal Article
  Year 2022 Publication Journal of Geochemical Exploration Abbreviated Journal  
  Volume 236 Issue Pages 106961  
  Keywords Ra/U, Radioactive disequilibria, Radium, Reactive transport modeling, Roll-front uranium deposit  
  Abstract Uranium reserve estimates in ore deposits can be significantly impacted by 226Ra/238U disequilibria arising from the differential mobility of uranium and radium during groundwater transport. 1D reactive transport models were developed to investigate the long-term effects of retention processes (UO2(am) precipitation, U(VI) and Ra sorption on smectite, Ra co-precipitation with barite) on the repartitioning of 238U and 226Ra during formation of roll-front type deposits. Analytical solutions to radioactive decay chains were used in complement to examine the influence of geochemical parameters, including fluid 234U/238U activity ratios and α-recoil loss, on 226Ra/238U disequilibria in uranium ores. Model results demonstrate that smectite and barite can produce 226Ra/238U ratios \textgreater1 at low uranium contents and may explain 226Ra/238U disequilibria occurring in altered rock up- and downstream of roll-front deposits. The capacity of these phases to take up Ra and generate 226Ra/238U disequilibria depends on both mineral contents and groundwater compositions, and is thus expected to be site-specific. Simulations of ore deposits that advance downstream with time demonstrate the formation of stronger 226Ra/238U disequilibria, as expected, in the downgradient side or nose of the ore, reflecting both younger mineralization ages and the presence of active uranium precipitation. Whether disequilibria are positive or negative with respect to secular equilibrium, however, depends on the 234U/238U activity ratio in the fluid from which uranium minerals precipitate. Smaller hydraulic conductivities are shown to generate a narrower range in 226Ra/238U activity ratios with distance, and may explain the occurrence of disequilibria in the limb ore that are less pronounced than those in the nose. Furthermore, the ability of α-recoil loss to decrease 226Ra/238U activity ratios at secular equilibrium may account for negative disequilibria in high grade ores. The South Tortkuduk uranium deposits (Kazakhstan) are subsequently used as a case study to identify the processes and parameters that may contribute to 226Ra/238U disequilibria at this site. Variations in multiple parameters, including clay contents, barite contents, and mineralization ages, are found to reproduce measured 226Ra/238U activity ratios in the roll-front ore. Prioritization of these parameters will necessitate field measurements targeting both groundwater fluids and the host rock. Results from this study will ultimately aid geologists in building appropriate hydrogeochemical data sets to more efficiently locate and exploit uranium ore deposits.  
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  ISSN 0375-6742 ISBN Medium  
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  Notes Approved no  
  Call Number THL @ christoph.kuells @ grozeva_reactive_2022 Serial 180  
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Author (up) Jana, A.; Unni, A.; Ravuru, S.S.; Das, A.; Das, D.; Biswas, S.; Sheshadri, H.; De, S. url  openurl
  Title In-situ polymerization into the basal spacing of LDH for selective and enhanced uranium adsorption: A case study with real life uranium alkaline leach liquor Type Journal Article
  Year 2022 Publication Chemical Engineering Journal Abbreviated Journal  
  Volume 428 Issue Pages 131180  
  Keywords In-situ polymerization, Layered double hydroxide, Leach liquor, Uranium adsorption, Uranium recovery  
  Abstract Uranium is used as a fuel for nuclear power plant and can be extracted from different ores, mainly acidic (silicious ore) and alkaline (carbonate ore). Recovery of uranium through acid leaching from silicious ore is well established, whereas, alkaline leaching from carbonate ore is challenging due to the excessive salinity of leach liquor and high concentration of carbonate, bicarbonate and sulphate. Herein, two monomers, acrylic acid (AA) and N, N-methylene bisacrylamide (BAM), selective towards uranyl were intercalated in-situ into the interlayer, followed by their polymerization and cross-linking to form novel polymer intercalated hybrid layered double hydroxide (LDH). The LDH acts as a backbone to overcome coiling and swelling of polymer and anchors them as free-standing. Various parameters, like, the type of metal ions, monomer ratio (AA: BAM) and metal ion ratio (M2+:M3+), were studied to determine the optimum conditions for effective intercalation and polymerization of monomers. Magnesium aluminum (MgAl) LDH with a cross-linked polymer having a monomer ratio of 3:2 (AA: BAM) as intercalating species showed maximum efficiency of uranyl adsorption (1456 mg/g at 30 °C) with highest capacity so far. The distribution coefficient (Kd, l/mg) in the order of 105 suggested that the adsorbent was highly selective for uranyl in the presence of different cations, anions and humic acid. The adsorbent extracts uranium effectively and selectively from a real-life alkaline leach liquor with an efficiency of 96% at 5 g/l dose. Uranium can be recovered from the adsorbent in the form of sodium di-uranate using 2(M) NaOH and was reused for eight cycles.  
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  ISSN 1385-8947 ISBN Medium  
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  Notes Approved no  
  Call Number THL @ christoph.kuells @ jana_-situ_2022 Serial 209  
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