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Hofmann, H., Pearce, J. K., Hayes, P., Golding, S. D., Hall, N., Baublys, K. A., et al. (2023). Multi-tracer approach to constrain groundwater flow and geochemical baseline assessments for CO2 sequestration in deep sedimentary basins. International Journal of Coal Geology, , 104438.
Abstract: Geological storage of gases will be necessary in the push to net zero and the energy transition to reduce carbon emissions to atmosphere. These include CO2 geological storage in suitable sandstone reservoirs. Understanding groundwater flow, connectivity and hydrogeochemical processes in aquifer and storage systems is vital to prevent risk and protect important water resources, such as the Great Artesian Basin. Here, we provide a ‘tool-box’ of geochemical assessment methods to provide information on flow patterns through the basin’s aquifers (changes in chemistry along flow path), stagnant versus flowing conditions (cosmogenic isotopes and noble gases), inter-aquifer connectivity and seal properties (major ions, Sr and stable isotopes), water quality (major ions and metals) and general assessments on residence times of groundwater (cosmogenic isotopes and noble gases). This information can be used with reservoir and groundwater models to inform on possible changes in the above-mentioned processes and serve as input parameters for CO2 injection impact modelling. We demonstrate the use and interpretation on an example of a potential CO2 storage geological sequestration site in the Surat Basin, part of the Great Artesian Basin, and the aquifers that overly the reservoir. The stable water isotopes are depleted compared to average rainfall and most likely indicate greater contributions from monsoonal rain events from the northern monsoonal troughs, where amount and rainout effects lead to the depletion rather than colder recharge climates. This is supported by the modern recharge temperatures from noble gases. Inter-aquifer mixing between the Precipice Sandstone reservoir and the Hutton Sandstone aquifer seems unlikely as the Sr isotope ratios are distinctly different suggesting that the Evergreen Formation is a seal in the locations sampled. Mixing, however, occurs on the edges of the basin, especially in the south-east and east where the Surat Basin transitions into the Clarence-Moreton Basin. Groundwater flow appears to be to the south in the Precipice Sandstone, with a component of flow east to the Clarence-Morton Basin. The cosmogenic isotopes and noble gases strongly indicate very long residence times of groundwater in the central south Precipice Sandstone around a proposed storage site. 14C values below analytical uncertainty, R36Cl ratios at secular equilibrium as well as high He concentrations and high 40Ar/36Ar ratios support the argument that groundwater flow in this area is extremely slow or groundwater is stagnant. The results of this study reflect the geological and hydrogeological complexities of sedimentary basins and that baseline studies, such as this one, are paramount for management strategies.
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Holmes, M., Campbell, E. E., Wit, M. de, & Taylor, J. C. (2023). Can diatoms be used as a biomonitoring tool for surface and groundwater?: Towards a baseline for Karoo water. South African Journal of Botany, 161, 211–221.
Abstract: The environmental risks from shale gas extraction through the unconventional method of ‘fracking’ are considerable and impact on water supplies below and above ground. Since 2010 the recovery of natural shale gas through fracking has been proposed in parts of the fragile semi-arid ecosystems that make up the Karoo biome in South Africa. These unique ecosystems are heavily reliant on underground water, intermittent and ephemeral springs, which are at great risk of contamination by fracking processes. Diatoms are present in all water bodies and reflect aspects of the environment in which they are located. As the possibility of fracking has not been removed, the aim of the project was to determine if diatoms could be used for rapid biomonitoring of underground and surface waters in the Karoo. Over a period of 24 months, water samples and diatom species were collected simultaneously from 65 sites. A total of 388 diatom taxa were identified from 290 samples with seasonal and substrate variation affecting species composition but not the environmental information. Species diversity information, on the other hand, often varied significantly between substrates within a single sample. Analysis using CCA established that the diatom composition was affected by lithium, oxidized nitrogen, electrical conductivity, and sulphate levels in the sampled water. We conclude that changes in diatom community composition in the Karoo do reflect the water chemistry and could be useful as bioindicators.
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Hu, K., Wang, Q., Tao, G., Wang, A., & Ding, D. (2011). Experimental Study on Restoration of Polluted Groundwater from in Situ Leaching Uranium Mining with Sulfate Reducing Bacteria and ZVI-SRB. Procedia Earth and Planetary Science, 2, 150–155.
Abstract: In the case of in situ leaching of uranium, the primitive geochemical environment for groundwater is changed since leachant is injected into the water beaving uranium deposit. This increases the concentration of uranium and results in the groundwater contamination.Microbial reduction technology by Sulfate reducing bacteria and Zero Valent Iron were employed to treat uranium wastewater. The experiments were conducted to evaluate the influence of anion (sulfate and nitrate) on dealing with uranium wastewater. Experimental results show that the utilization of both SRB system and ZVI – SRB system to process uranium wastewater is affected by sulfate ion and nitrate ion. As the concentration of sulfate radical is lower than 4000mg/L, sulfate-reducing bacteria has no influence on precipitated uranium. However, as the concentration of sulfate is more than 6,000mg/L, uranium removal rate decreases significantly, from 80% to 14.1%. When adding sulfate radical on ZVI – SRB system to process uranium wastewater, its uranium removal rate is higher than SRB system. Low concentration of nitrate contributes to reduction metabolism of SRB. High concentration of nitrate inhibits the growth and metabolism of SRB and affects the treatment efficiency of uranium wastewater. When the concentration of nitrate reaches 1500mg/L, uranium removal rate is less than 0.1%. Nevertheless, as the concentration of nitrate is lower than 1000mg/L, uranium removal rate could reach more than 75%. As existence of nitrate radical, uranium removal rate of SRB by adding ZVI is higher than that without adding.
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Hubbard, B. E., Gallegos, T. J., Stengel, V., Hoefen, T. M., Kokaly, R. F., & Elliott, B. (2024). Hyperspectral (VNIR-SWIR) analysis of roll front uranium host rocks and industrial minerals from Karnes and Live Oak Counties, Texas Coastal Plain. Journal of Geochemical Exploration, 257, 107370.
Abstract: VNIR-SWIR (400–2500 nm) reflectance measurements were made on the surfaces of various cores, cuttings and sample splits of sedimentary rocks from the Tertiary Jackson Group, and Catahoula, Oakville and Goliad Formations. These rocks vary in composition and texture from mudstone and claystone to sandstone and are known host rocks for roll front uranium occurrences in Karnes and Live Oak Counties, Texas. Spectral reflectance profiles, 569 in total, were reduced to 125 representative spectral signatures, which were analyzed using the U.S. Geological Survey’s (USGS) Material Identification and Characterization Algorithm (MICA). MICA uses an automated continuum-removal procedure together with a least-squares linear regression to determine the fit of observed sample spectral absorption features to those of reference mineral standards in a spectral library. The reference minerals include various clay, mica, carbonate, ferric and ferrous iron minerals and their mixtures. In addition, absorption feature band-depth analysis was done to identify rock surfaces exhibiting absorption features related to uranium and zeolite minerals, which were not included in the command files used to execute MICA. Rocks from each of the four geologic units produced broadly similar spectral signatures as a result of comparable mineral compositions, but there were some notable differences. For example, Ca- and Na-montmorillonite was matched most frequently to the spectral absorption features in 2-μm (∼2000–2500 nm) wavelengths, while goethite occurred often at 1-μm (∼400–1000 nm) wavelengths. The latter is related to limonitic iron-staining in and around oxidized zones of the uranium roll front as described in previous papers. Rocks of the Jackson Group differed from those of the Catahoula, Oakville and Goliad units in that the former exhibited spectral features we interpret as being due to the presence of lignite-bearing mudstone layers. Goliad rocks exhibit spectral features related to dolomite, gypsum, anhydrite, and an unidentified green clay mineral that is possibly glauconite. Jackson Group rocks also exhibit weak but well-resolved absorption features at 964 and 1157 nm related to either or both zeolite minerals clinoptilolite and heulandite. These zeolite minerals and a few spectra exhibiting hydrous silica absorption features are indicative of alteration of volcanic glass in tuffaceous mudstone and claystone layers. A few sample spectra exhibited strong absorption features at around 1135 nm related to the uranium mineral coffinite. Both the 1135 nm coffinite and 1157 nm zeolite absorption features overlap somewhat, potentially making them difficult to distinguish without additional hyperspectral field, laboratory or remote sensing data. The results of this study were compared to mixtures of minerals described for ore, gangue and alteration minerals in deposit models for sandstone-hosted uranium, sedimentary bentonite and sedimentary zeolite. Use of these spectra can help facilitate mapping of both waste materials from the legacy mining of the above commodities, as well as future exploration and resource assessment activities.
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Ibrahim, A. S., Zayed, I. S. A., Abdelhaleem, F. S., Afify, M. M., Ahmed, A., & Abd-Elaty, I. (2023). Identifying cost-effective locations of storage dams for rainfall harvesting and flash flood mitigation in arid and semi-arid regions. Journal of Hydrology: Regional Studies, 50, 101526.
Abstract: Study region Wadi Tayyibah is located in south Sinai, Egypt, in a region called Abou Zenima, and it is used to develop this study. Study focus Flash floods tremendously impact many facets of human life due to their destructive consequences and the costs associated with mitigating efforts. This study aims to evaluate the harvesting of Runoff by delineating the watersheds using the Hydrologic Engineering Center-1 (HEC-1) model and ArcGIS software in trying to benefit from it in different ways. All morphometric parameters of the basin were considered, and the risk degree of the different sub-basins was determined. The suitable locations of dams were identified using a Geographical Information System (GIS) using the basin’s morphometric characteristics. New hydrological insights for the region The study proposed a total number of eight dams, including five dams that were recommended for sub-basin (1) and three dams in sub-basin (4), while sub-basins (2) and (3) are not suitable locations to build dams according to the contour map of Wadi Tayyibah. Results indicate that, based on the constructed flash flood hazard maps and the basin’s detailed morphometric characteristics, the best locations of dams are Dam (3) in sub-basin (1) and Dam (7) in sub-basin (4), where the runoff volume reached 3.13 million cubic meters (Mm3) and 5.56 Mm3 for return period 100, respectively. This study is useful for decision-makers and designers for using morphometric parameters and flash flood hazard degree maps to select dam locations. Also, the cost-benefit analysis for using the morphometric parameters is required to be investigated.
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