Abstract: Elevated groundwater nitrate levels are common in drylands, often in excess of WHO guidelines, with concern for human and animal health. In light of recent attempts to identify nitrate sources in the Kalahari this paper presents the first unsaturated zone (USZ) nitrate profiles and recharge rate estimates for the important transboundary Stampriet Basin, alongside the first rainfall chemistry records. Elevated subsurface nitrate reaches 100–250 and 250–525 mg/L NO3–N, with NO3–N/Cl of 4–12, indicating input above evapotranspiration. Chloride mass balance recharge rates range from 4 to 27 mm/y, indicating a vertical movement of these nitrate pulses toward the water table over multi-decadal timescales. These profiles are sampled from dune crests, away from high concentrations of animals and without termite mounds. Given low-density animal grazing is unlikely to contribute consistent spot-scale nitrate over decades, these profiles give an initial estimate of naturally-produced concentrations. This insight is important for the management of the Stampriet Basin and wider Kalahari groundwater. This study expands our knowledge about elevated nitrate in dryland USZs, demonstrating that it can occur as pulses, probably in response to transient vegetation cover and that it is not limited to long-residence time USZs with very limited downward moisture flux (recharge).

Abstract: Study region Transboundary aquifers (TBAs) of Africa. Study focus Review of work on TBAs in Africa, including an overview of assessments and management efforts that have taken place over the last half century. New hydrological insights Seventy-two TBAs have been mapped in Africa. They underlie 40% of the continent, where 33% of the population lives, often in arid or semi-arid regions. TBA inventories have progressed since 2000 and remain work in progress. Despite their importance only eleven TBAs have been subjected to more detailed studies. Cooperation has been formalised for seven TBAs. Most of these TBAs are in North Africa and the Sahel. The recent global Transboundary Waters Assessment Programme compiled information at the national level to describe TBAs in terms of key indicators related to the water resource, socio-economic, and legal and institutional conditions. Availability of data at national level is low, hampering regional assessment. Comparing indicators, from questionnaire surveys, with those from a global water-use model showed variable levels of agreement, calling for further research. Reports on agreements scoping TBA management, indicate that this may be dealt with within international river/lake agreements, but reported inconsistencies between TBA sharing countries also indicate that implementation is limited. Increasing awareness and support to joint TBA management is noticeable amongst international organisations. However, such cooperation requires long-term commitment to produce impacts at the local level.