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Zhou, Y., Li, G., Xu, L., Liu, J., Sun, Z., & Shi, W. (2020). Uranium recovery from sandstone-type uranium deposit by acid in-situ leaching – an example from the Kujieertai. Hydrometallurgy, 191, 105209.
Abstract: The factors influencing uranium recovery in water-rock systems during acid in-situ leaching (ISL) were studied at the Kujieertai uranium deposit in Xinjiang. Using an ISL unit, a field leach trial (FLT) had been carried out to test the sequential effects of a leaching solution without oxidant (H2SO4 solution 4–8 g/L) and a leaching solution with oxidant (H2SO4 3–7 g/L, and Fe (III) 2–6 g/L). The observation of the leaching process revealed clearly defined stages of uranium release from the solid mineral to solution. Uranium mobilization from solid mineral into solution can be described in four stages. At the beginning of the acid ISL process, there was no oxidant to be added to the leaching solution and the desorption of hexavalent uranyl ions in the open pores, as well as dissolution of hexavalent uranium minerals, led to a short-term peak in the pregnant solution, which happened while pH decreased from about 5.3 to 2.62. Following the depletion of the adsorbed hexavalent uranium and a decline in uranium dissolution intensity, the addition of Fe(III) facilitated the oxidation of tetravalent uranium, which enabled intensive uranium mobilization again. During this process, the dissolution of uranium had a strong positive correlation with the reduction of Fe(III) and Eh in the leach solution. Beside hydrochemical factors, the deportment of uranium was also an important factor affecting uranium recovery. Uranium located in the open pores can be completely exposed to the solution and the mobilization intensity was significantly affected by hydrogeochemical conditions; but the uranium present in microfissures and in the ore matrix could not be fully exposed to the solution, so, their dissolution intensity was primarily controlled by corrosion and permeability of the ore. In general, the hydrogeochemical conditions and the deportment of uranium were the external and internal factors that significantly affected the dissolution and recovery of uranium in the early and middle stages of the FLT. However, in the latest stages, due to uranium depletion, enhancing the chemical potential of the leaching solution, specifically acidity and/or the amount of oxidant, had little improvement on uranium recovery.
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Uugulu, S., & Wanke, H. (2020). Estimation of groundwater recharge in savannah aquifers along a precipitation gradient using chloride mass balance method and environmental isotopes, Namibia. Physics and Chemistry of the Earth, Parts A/B/C, 116, 102844.
Abstract: The quantification of groundwater resources is essential especially in water scarce countries like Namibia. The chloride mass balance (CMB) method and isotopic composition were used in determining groundwater recharge along a precipitation gradient at three sites, namely: Tsumeb (600 mm/a precipitation); Waterberg (450 mm/a precipitation) and Kuzikus/Ebenhaezer (240 mm/a precipitation). Groundwater and rainwater were collected from year 2016–2017. Rainwater was collected monthly while groundwater was collected before, during and after rainy seasons. Rainwater isotopic values for δ18O and δ2H range from −10.70 to 6.10‰ and from −72.7 to 42.1‰ respectively. Groundwater isotopic values for δ18O range from −9.84 to −5.35‰ for Tsumeb; from −10.85 to −8.60‰ for Waterberg and from −8.24 to −1.56‰ for Kuzikus/Ebenhaezer, while that for δ2H range from −65.6 to −46.7‰ for Tsumeb; −69.4 to −61.2‰ for Waterberg and −54.2 to −22.7‰ for Kuzikus/Ebenhaezer. Rainwater scatters along the GMWL. Rainwater collected in January, February and March are more depleted in heavy isotopes than those in November, December, April and May. Waterberg groundwater plots on the GMWL which indicates absence of evaporation. Tsumeb groundwater plots on/close to the GMWL with an exception of groundwater from the karst Lake Otjikoto which is showing evaporation. Groundwater from Kuzikus/Ebenhaezer shows an evaporation effect, probably evaporation occurs during infiltration since it is observed in all sampling seasons. All groundwater from three sites plot in the same area with rainwater depleted in stable isotopic values, which could indicates that recharge only take place during January, February and March. CMB method revealed that Waterberg has the highest recharge rate ranging between 39.1 mm/a and 51.1 mm/a (8.7% – 11.4% of annual precipitation), Tsumeb with rates ranging from 21.1 mm/a to 48.5 mm/a (3.5% – 8.1% of annual precipitation), and lastly Kuzikus/Ebenhaezer from 3.2 mm/a to 17.5 mm/a (1.4% – 7.3% of annual precipitation). High recharge rates in Waterberg could be related to fast infiltration and absence of evaporation as indicated by the isotopic ratios. Differences in recharge rates cannot only be attributed to the precipitation gradient but also to the evaporation rates and the presence of preferential flow paths. Recharge rates estimated for these three sites can be used in managing the savannah aquifers especially at Kuzikus/Ebenhaezer where evaporation effect is observed that one can consider rain harvesting.
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Tziritis, E., Aschonitis, V., Balacco, G., Daras, P., Doulgeris, C., Fidelibus, M. D., et al. (2020). MEDSAL Project-Salinization of critical groundwater reserves in coastal Mediterranean areas: Identification, risk assessment and sustainable management with the use of integrated modelling and smart ICT tools. In EGU General Assembly Conference Abstracts (2326).
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Tamagnone, P., Comino, E., & Rosso, M. (2020). Rainwater harvesting techniques as an adaptation strategy for flood mitigation. Journal of Hydrology, 586, 124880.
Abstract: The development of adaptation and mitigation strategies to tackle anthropic and climate changes impacts is becoming a priority in drought-prone areas. This study examines the capabilities of indigenous rainwater harvesting techniques (RWHT) to be used as a viable solution for flood mitigation. The study analyses the hydraulic performance of the most used micro-catchment RWHT in sub-Saharan regions, in terms of flow peak reduction (FPR) and volume reduction (VR) at the field and basin scale. Parametrized hyetographs were built to replicate the extreme precipitations that strike Sahelian countries during rainy seasons. 2D hydrodynamic simulations showed that half-moons placed with a staggered configuration (S-HM) have the best performances in reducing runoff. At the field scale, S-HM showed a remarkable FPR of 77% and a VR of 70% in case of extreme rainfall. Instead at the basin scale, in which only 5% of the surface was treated, 13% and 8% respectively for FPR and VR were obtained. In addition, the reduction of the runoff coefficient (Rc) between the different configuration was analyzed. The study critically evaluates hydraulic performances of the different techniques and shows how pitting practices cannot guarantee high performance in case of extreme precipitations. These results will enrich the knowledge of the hydraulic behavior of RWHT; aspect marginally investigated in the scientific literature. Moreover, this study presents the first scientific application of HEC-RAS as a rainfall-runoff model. Despite some limitations, this model has the effective feature of using very high-resolution topography as input for hydraulic simulations. The results presented in this study should encourage stakeholders to upscale the use of RWHT in order to lessen the flood hazard and land degradation that oppresses arid and semi-arid areas.
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Su, X., Liu, Z., Yao, Y., & Du, Z. (2020). Petrology, mineralogy, and ore leaching of sandstone-hosted uranium deposits in the Ordos Basin, North China. Ore Geology Reviews, 127, 103768.
Abstract: The Nalinggou–Daying uranium metallogenic belt is situated at the northern Ordos Basin, China. Petrographical, mineralogical and geochemical techniques were used to study the ore-bearing sandstones and host rocks in the Nalinggou–Daying uranium metallogenic belt. The present study shows that uranium minerals, i.e., coffinite, pitchblende, and brannerite, are mostly disseminated around pyrite and detrital particles. The ore-bearing sandstones are enriched in organic matter, with which this reductive environment influenced uranium leaching. The carbonate concentration of the uranium ores is markedly higher than that of the host rocks, and intense carbonatization occurs in the ore-bearing sandstones. In this case, the usage of the classical in-situ leach uranium mining technique by injecting H2SO4 + H2O2 solution produces calcium sulfate precipitate, which can lead to blocking of the ore-bearing strata. For this reason, laboratory and field uranium mining tests were conducted using CO2 + O2 in-situ leaching technology and were demonstrated to be successful, illustrating that this approach is technically feasible. Inhibiting ore bed blockage and increasing the amount of injected O2 are important for uranium leaching in this setting.
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