@Article{Lach_etal2015, author="Lach, P. and Cathelineau, M. and Brouand, M. and Fiet, N.", title="In-situ Isotopic and Chemical Study of Pyrite from Chu-Sarysu (Kazakhstan) Roll-front Uranium Deposit", journal="Procedia Earth and Planetary Science", year="2015", volume="13", pages="207--210", optkeywords="LA-ICP-MS", optkeywords="pyrite", optkeywords="roll-front", optkeywords="SIMS", optkeywords="sulfur isotopy", optkeywords="traces elements", optkeywords="uranium", abstract="Pyrite is common in roll-front type uranium deposit in Chu-sarysu basin, Kazakhstan. Combined in-situ microstructural, isotopic and chemical analysis of pyrite indicates variation in precipitation conditions and in fluid composition. Broad-scale $\delta$34S heterogeneity indicates a complex multi-facet evolution. First generation authigenic frambo{\"i}dal aggregates are biogenic as demonstrated by the lowest $\delta$34S values of -48{\texttenthousand} to -28{\texttenthousand}. The latest generation pyrites are probably hydrothermal with greater $\delta$34S variation (-30{\texttenthousand} to +12{\texttenthousand}). This hydrothermal pyrite commonly displays variable enrichment of several trace elements especially As, Co and Ni. Strong variation in $\delta$34S values and variable trace element enrichment is interpreted in terms of continuous variations in fluid composition.", optnote="exported from refbase (http://www.uhydro.de/base/show.php?record=182), last updated on Fri, 26 Jan 2024 13:19:04 +0100", issn="1878-5220", opturl="https://www.sciencedirect.com/science/article/pii/S1878522015001927" }