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Author |
Liesch, T.; Hinrichsen, S.; Goldscheider, N. |
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Title |
Uranium in groundwater — Fertilizers versus geogenic sources |
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Journal Article |
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Year |
2015 |
Publication |
Science of The Total Environment |
Abbreviated Journal |
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Volume |
536 |
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981-995 |
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Drinking water, Fertilizer, Geogenic background, Groundwater, Uranium |
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Abstract |
Due to its radiological and toxicological properties even at low concentration levels, uranium is increasingly recognized as relevant contaminant in drinking water from aquifers. Uranium originates from different sources, including natural or geogenic, mining and industrial activities, and fertilizers in agriculture. The goal of this study was to obtain insights into the origin of uranium in groundwater while differentiating between geogenic sources and fertilizers. A literature review concerning the sources and geochemical processes affecting the occurrence and distribution of uranium in the lithosphere, pedosphere and hydrosphere provided the background for the evaluation of data on uranium in groundwater at regional scale. The state of Baden-Württemberg, Germany, was selected for this study, because of its hydrogeological and land-use diversity, and for reasons of data availability. Uranium and other parameters from N=1935 groundwater monitoring sites were analyzed statistically and geospatially. Results show that (i) 1.6% of all water samples exceed the German legal limit for drinking water (10μg/L); (ii) The range and spatial distribution of uranium and occasional peak values seem to be related to geogenic sources; (iii) There is a clear relation between agricultural land-use and low-level uranium concentrations, indicating that fertilizers generate a measurable but low background of uranium in groundwater. |
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0048-9697 |
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THL @ christoph.kuells @ liesch_uranium_2015 |
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145 |
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Author |
Yabusaki, S.B.; Fang, Y.; Long, P.E.; Resch, C.T.; Peacock, A.D.; Komlos, J.; Jaffe, P.R.; Morrison, S.J.; Dayvault, R.D.; White, D.C.; Anderson, R.T. |
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Title |
Uranium removal from groundwater via in situ biostimulation: Field-scale modeling of transport and biological processes |
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Journal Article |
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Year |
2007 |
Publication |
Journal of Contaminant Hydrology |
Abbreviated Journal |
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93 |
Issue |
1 |
Pages |
216-235 |
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Keywords |
Bioremediation, Biostimulation, Field experiment, Iron, Reactive transport, Sulfate, Uranium |
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Abstract |
During 2002 and 2003, bioremediation experiments in the unconfined aquifer of the Old Rifle UMTRA field site in western Colorado provided evidence for the immobilization of hexavalent uranium in groundwater by iron-reducing Geobacter sp. stimulated by acetate amendment. As the bioavailable Fe(III) terminal electron acceptor was depleted in the zone just downgradient of the acetate injection gallery, sulfate-reducing organisms came to dominate the microbial community. In the present study, we use multicomponent reactive transport modeling to analyze data from the 2002 field experiment to identify the dominant transport and biological processes controlling uranium mobility during biostimulation, and determine field-scale parameters for these modeled processes. The coupled process simulation approach was able to establish a quantitative characterization of the principal flow, transport, and reaction processes based on the 2002 field experiment, that could be applied without modification to describe the 2003 field experiment. Insights gained from this analysis include field-scale estimates of the bioavailable Fe(III) mineral threshold for the onset of sulfate reduction, and rates for the Fe(III), U(VI), and sulfate terminal electron accepting processes. |
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0169-7722 |
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THL @ christoph.kuells @ yabusaki_uranium_2007 |
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156 |
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Pree, T.A.D. |
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Title |
The politics of baselining in the Grants uranium mining district of northwestern New Mexico |
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Journal Article |
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Year |
2020 |
Publication |
Journal of Environmental Management |
Abbreviated Journal |
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Volume |
268 |
Issue |
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Pages |
110601 |
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Keywords |
Critical stakeholder analysis, Environmental cleanup, Environmental monitoring, Mining reclamation/remediation/restoration, Politics of baselining |
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Abstract |
During the second half of the twentieth century, northwestern New Mexico served as the primary production site for one of the world’s largest nuclear arsenals. From 1948 to 1970 the “Grants uranium district” provided almost half of the total uranium ore accumulated by the United States federal government for the production of nuclear weapons, in addition to becoming a national source for commercial nuclear energy from the late 1960s to the early 1990s. By the twenty-first century, after a prolonged period of economic decline that began in the late 1970s, all uranium mining and milling in New Mexico had ceased, leaving a legacy of environmental health impacts. What was once referred to as “The Uranium Capital of the World” now encompasses over a thousand abandoned uranium mines and seven massive uranium mill tailings piles, which are associated with airborne and soil contamination as well as groundwater plumes of uranium and other contaminants of concern, in a landscape that has been fractured by underground mine workings and punctured by thousands of exploratory boreholes. This article presents an ethnographic study of the diverse forms of expertise involved in monitoring and managing the mine waste and mill tailings. Drawing from over two years of ethnographic research, I describe the relationship between different stakeholders from local communities, government agencies, and transnational mining corporations as they deliberate about the possibility of cleaning up the former mining district. My thesis is that the possibility of cleaning up the Grants district hinges on the “politics of baselining”—a term I introduce to describe the relationship between stakeholders and their competing environmental models and hydrogeological theories; each accounts for a different geological past prior to mining that can be deemed “natural,” as the background against which to measure the anthropogenic impacts from mining. |
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0301-4797 |
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THL @ christoph.kuells @ pree_politics_2020 |
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151 |
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Author |
Stone, A.E.C.; Edmunds, W.M. |
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Title |
Naturally-high nitrate in unsaturated zone sand dunes above the Stampriet Basin, Namibia |
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Journal Article |
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Year |
2014 |
Publication |
Journal of Arid Environments |
Abbreviated Journal |
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Volume |
105 |
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41-51 |
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Keywords |
Kalahari, Namibia, Nitrate in the unsaturated zone, Stampriet Basin, Transboundary basin, Unsaturated zone recharge |
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Elevated groundwater nitrate levels are common in drylands, often in excess of WHO guidelines, with concern for human and animal health. In light of recent attempts to identify nitrate sources in the Kalahari this paper presents the first unsaturated zone (USZ) nitrate profiles and recharge rate estimates for the important transboundary Stampriet Basin, alongside the first rainfall chemistry records. Elevated subsurface nitrate reaches 100–250 and 250–525 mg/L NO3–N, with NO3–N/Cl of 4–12, indicating input above evapotranspiration. Chloride mass balance recharge rates range from 4 to 27 mm/y, indicating a vertical movement of these nitrate pulses toward the water table over multi-decadal timescales. These profiles are sampled from dune crests, away from high concentrations of animals and without termite mounds. Given low-density animal grazing is unlikely to contribute consistent spot-scale nitrate over decades, these profiles give an initial estimate of naturally-produced concentrations. This insight is important for the management of the Stampriet Basin and wider Kalahari groundwater. This study expands our knowledge about elevated nitrate in dryland USZs, demonstrating that it can occur as pulses, probably in response to transient vegetation cover and that it is not limited to long-residence time USZs with very limited downward moisture flux (recharge). |
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0140-1963 |
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THL @ christoph.kuells @ stone_naturally-high_2014 |
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91 |
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Author |
Stone, A.E.C.; Edmunds, W.M. |
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Title |
Naturally-high nitrate in unsaturated zone sand dunes above the Stampriet Basin, Namibia |
Type |
Journal Article |
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Year |
2014 |
Publication |
Journal of Arid Environments |
Abbreviated Journal |
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105 |
Issue |
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41-51 |
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Keywords |
Kalahari, Namibia, Nitrate in the unsaturated zone, Stampriet Basin, Transboundary basin, Unsaturated zone recharge |
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Abstract |
Elevated groundwater nitrate levels are common in drylands, often in excess of WHO guidelines, with concern for human and animal health. In light of recent attempts to identify nitrate sources in the Kalahari this paper presents the first unsaturated zone (USZ) nitrate profiles and recharge rate estimates for the important transboundary Stampriet Basin, alongside the first rainfall chemistry records. Elevated subsurface nitrate reaches 100–250 and 250–525 mg/L NO3–N, with NO3–N/Cl of 4–12, indicating input above evapotranspiration. Chloride mass balance recharge rates range from 4 to 27 mm/y, indicating a vertical movement of these nitrate pulses toward the water table over multi-decadal timescales. These profiles are sampled from dune crests, away from high concentrations of animals and without termite mounds. Given low-density animal grazing is unlikely to contribute consistent spot-scale nitrate over decades, these profiles give an initial estimate of naturally-produced concentrations. This insight is important for the management of the Stampriet Basin and wider Kalahari groundwater. This study expands our knowledge about elevated nitrate in dryland USZs, demonstrating that it can occur as pulses, probably in response to transient vegetation cover and that it is not limited to long-residence time USZs with very limited downward moisture flux (recharge). |
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0140-1963 |
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THL @ christoph.kuells @ Stone201441 |
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218 |
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Permanent link to this record |
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Author |
Stone, A.E.C.; Edmunds, W.M. |
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Title |
Naturally-high nitrate in unsaturated zone sand dunes above the Stampriet Basin, Namibia |
Type |
Journal Article |
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Year |
2014 |
Publication |
Journal of Arid Environments |
Abbreviated Journal |
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Volume |
105 |
Issue |
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Pages |
41-51 |
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Keywords |
Kalahari, Namibia, Nitrate in the unsaturated zone, Stampriet Basin, Transboundary basin, Unsaturated zone recharge |
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Abstract |
Elevated groundwater nitrate levels are common in drylands, often in excess of WHO guidelines, with concern for human and animal health. In light of recent attempts to identify nitrate sources in the Kalahari this paper presents the first unsaturated zone (USZ) nitrate profiles and recharge rate estimates for the important transboundary Stampriet Basin, alongside the first rainfall chemistry records. Elevated subsurface nitrate reaches 100–250 and 250–525 mg/L NO3–N, with NO3–N/Cl of 4–12, indicating input above evapotranspiration. Chloride mass balance recharge rates range from 4 to 27 mm/y, indicating a vertical movement of these nitrate pulses toward the water table over multi-decadal timescales. These profiles are sampled from dune crests, away from high concentrations of animals and without termite mounds. Given low-density animal grazing is unlikely to contribute consistent spot-scale nitrate over decades, these profiles give an initial estimate of naturally-produced concentrations. This insight is important for the management of the Stampriet Basin and wider Kalahari groundwater. This study expands our knowledge about elevated nitrate in dryland USZs, demonstrating that it can occur as pulses, probably in response to transient vegetation cover and that it is not limited to long-residence time USZs with very limited downward moisture flux (recharge). |
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0140-1963 |
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THL @ christoph.kuells @ Stone201441 |
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279 |
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Author |
Heaton, T.H.E. |
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Title |
Sources of the nitrate in phreatic groundwater in the western Kalahari |
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Journal Article |
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1984 |
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Journal of Hydrology |
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67 |
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1 |
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249-259 |
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Elevated levels of nitrate occur in phreatic groundwater in the western Kalahari, Namibia. Nitrate in water containing 0.4–3.1 meq NO−3l−1, of widespread occurrence, has δ15N values in the range +4.9 to +8.0‰, suggesting natural derivation from the soil. The sporadic occurrence of very high levels of nitrate (> 4 meq NO−3l−1), which has δ15N between +9.3 to +18.7‰, reflects pollution derived from animal waste. The importance of considering the possible isotopic effects of denitrification, and the significance of leaching in the nitrogen budget of the Kalahari soil, are also discussed. |
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0022-1694 |
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THL @ christoph.kuells @ Heaton1984249 |
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278 |
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Author |
Martínez-Santos, P.; Martínez-Alfaro, P.E. |
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Title |
A priori mapping of historical water-supply galleries based on archive records and sparse material remains. An application to the Amaniel qanat (Madrid, Spain) |
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Journal Article |
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2014 |
Publication |
Journal of Cultural Heritage |
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15 |
Issue |
6 |
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656-664 |
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Hydraulic heritage, Qanat, Groundwater, Foggara, Water-supply, Amaniel, Madrid |
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Engineering heritage refers to a broad variety of items of social, economic, aesthetic or historic relevance, including roads, dams, buildings and supply networks. Due to their utilitarian nature, their heritage value is often overlooked. This occurs even with those infrastructures that have played an essential role in underpinning the daily existence of entire civilizations. Underground water-supply networks provide an excellent example. Although there are exceptions, water networks tend to be functional in design, rather than monumental. Moreover, they present intricate linear layouts that often span several kilometres. This means they are costly to maintain once their operational life is over, and that they are prone to abandonment and destruction. Devising a priori protection strategies is important to preserve these valuable cultural assets. The following pages present a method to map linear structures based on archive records and sparse material remains. The method is illustrated through its application to the Amaniel qanat, a water-supply gallery built in Madrid, Spain, in the early 17th Century. An appraisal of the known remains was carried out first, leading to an inventory of galleries, shafts, shaft caps and deposits. This was followed by a thorough survey of over one thousand handwritten manuscripts, including physical descriptions of the aqueduct, budget accounts or water metering campaigns, among other documents. Known remains and written evidence were matched against original and auxiliary maps to reconstruct the itinerary of the aqueduct. This led to the identification of sectors where it is still possible to find remains in good condition. Thus, a priori mapping is advocated a valuable technique to locate and preserve these remains, as well as to devise non-invasive surveys and establish heritage protection zones. |
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1296-2074 |
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THL @ christoph.kuells @ Martinezsantos2014656 |
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270 |
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Author |
Mühr-Ebert, E.L.; Wagner, F.; Walther, C. |
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Title |
Speciation of uranium: Compilation of a thermodynamic database and its experimental evaluation using different analytical techniques |
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Journal Article |
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2019 |
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Applied Geochemistry |
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100 |
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213-222 |
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Environmental hazards are caused by uranium mining legacies and enhanced radioactivity in utilized groundwater and surface water resources. Knowledge of uranium speciation in these waters is essential for predicting radionuclide migration and for installing effective water purification technology. The validity of the thermodynamic data for the environmental media affected by uranium mining legacies is of utmost importance. Therefore, a comprehensive and consistent database was established according to current knowledge. The uranium data included in the database is based on the NEA TDB (Guillaumont et al., 2003) and is modified or supplemented as necessary e.g. for calcium and magnesium uranyl carbonates. The specific ion interaction theory (Brönsted, 1922) is used to estimate activity constants, which is sufficient for the considered low ionic strengths. The success of this approach was evaluated by comparative experimental investigations and model calculations (PHREEQC (Parkhurst and Appelo, 1999)) for several model systems. The waters differ in pH (2.7–9.8), uranium concentration (10−9-10−4 mol/L) and ionic strength (0.002–0.2 mol/L). We used chemical extraction experiments, ESI-Orbitrap-MS and time-resolved laser-induced fluorescence spectroscopy (TRLFS) to measure the uranium speciation. The latter method is nonintrusive and therefore does not change the chemical composition of the investigated waters. This is very important, because any change of the system under study may also change the speciation. |
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0883-2927 |
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THL @ christoph.kuells @ muhr-ebert_speciation_2019 |
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142 |
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Tariq, A.; Beni, L.H.; Ali, S.; Adnan, S.; Hatamleh, W.A. |
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An effective geospatial-based flash flood susceptibility assessment with hydrogeomorphic responses on groundwater recharge |
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Journal Article |
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2023 |
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Groundwater for Sustainable Development |
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23 |
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100998 |
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Flood hydrology, AHP, Flood susceptibility, FR, Unit stream power, GIS |
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Floods are one of the most common natural disasters, resulting in the extensive destruction of infrastructure, property, and human life. The destructive potential of a flood depends on numerous factors, including the size of the flood, the rate of flooding, the time it takes for the water to move through a given area, the river’s planform and cross-section geometry, and other similar factors. The present study is a unique analysis of flood mapping that was accomplished with the help of the Analytical Hierarchy Process (AHP), Frequency Ratio (FR), and hydrogeomorphic response to floods by integrating geospatial analysis and unit stream power modeling. The Indus catchment region of Pakistan is where the subject topic is put into practice. According to the hydrologic analysis of the yearly peak discharge, the hydro-station in Gilgit-Baltistan can move boulders measuring up to 0.5 m in height during significant flooding. On the other hand, there will be no change to the geometry of the cross-section throughout 1980–2020 in Gilgit-Baltistan. The flood susceptibility map is constructed using data from twelve influencing parameters, including elevation, proximity to the drainage network, slope, drainage density, geomorphology, rainfall, the curvature of the topography, flow accumulation, geology, land use, Topographic Wetness Index (TWI), and Stream Power Index (SPI). The area under the curve (AUC) approach, which demonstrates a substantial degree of accuracy (85% and 83%), is utilized to evaluate the effectiveness of the AHP and FR. The current study fills the gaps between the geospatial approach and the hydrogeomorphic assessment of flood to determine flood susceptibility. |
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2352-801x |
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THL @ christoph.kuells @ Tariq2023100998 |
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234 |
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