Abstract: Since the coming into force of the European Council Directive 51/2013 EURATOM and its transposition into the Spanish legislation, the presence of radioactive substances in drinking waters must be kept under surveillance to ensure that the health protection requirements are met. Driven by this regulatory framework, in an attempt to know the starting point from which to design surveillance plans, the groundwaters intended for human consumption of Castilla y León (Spain) have been radiologically characterised by using both low-level γ-ray and α-particle spectrometry to determine the activity concentration of the natural radionuclides needed to account for the indicative dose estimation. This extensive research has comprised the radiological characterisation of more than 400 drinking water samples from one of the European Union’s largest regions. Furthermore, the gross α and gross β activities have been analysed. Results showed a high geographical variability that can be related to the hydrogeological formations where the groundwaters come from. The uranium isotopes, 234U and 238U, are the main radionuclides present in the analysed drinking waters reaching values up to 2000 mBq/L, in the southwestern and western of Castilla y León, where U-rich minerals are part of the host rock. High 210Pb and 226,228Ra occurrences are found in the low permeability igneous and metasedimentary hydrogeological formations of Salamanca province. From a public health protection point of view, 4.4% of the total drinking water samples from intakes exceeded the Indicative Dose parametric value of 0.1 mSv, which is a not negligible number of samples, being very likely related to granitic and metamorphosed host rock under specific local conditions. This fact highlights the need for research and consideration of special surveillance of the groundwaters from these areas.

Abstract: Rainwater harvesting (RWH) systems have been developed to compensate for shortage in the water supply worldwide. Such systems are not very common in arid areas, particularly in the Gulf Region, due to the scarcity of rainfall and their reduced efficiency in covering water demand and reducing water consumption rates. In spite of this, RWH systems have the potential to reduce urban flood risks, particularly in densely populated areas. This study aimed to assess the potential use of RWH systems as urban flood mitigation measures in arid areas. Their utility in the retention of stormwater runoff and the reduction of water depth and extent were evaluated. The study was conducted in a residential area in Bahrain that experienced waterlogging after heavy rainfall events. The water demand patterns of housing units were analyzed, and the daily water balance for RWH tanks was evaluated. The effect of the implementation of RWH systems on the flood volume was evaluated with a two-dimensional hydrodynamic model. Flood simulations were conducted in several rainfall scenarios with different probabilities of occurrence. The results showed significant reductions in the flood depth and flood extent, but these effects were highly dependent on the rainfall intensity of the event. RWH systems are effective flood mitigation measures, particularly in urban arid regions short of proper stormwater control infrastructure, and they enhance the resilience of the built environment to urban floods.

Abstract: Permeable reactive barriers (PRBs) are used for groundwater remediation at contaminated sites worldwide. This technology has been efficient at appropriate sites for treating organic and inorganic contaminants using zero-valent iron (ZVI) as a reductant and as a reactive material. Continued development of the technology over the years suggests that a robust understanding of PRB performance and the mechanisms involved is still lacking. Conflicting information in the scientific literature downplays the critical role of ZVI corrosion in the remediation of various organic and inorganic pollutants. Additionally, there is a lack of information on how different mechanisms act in tandem to affect ZVI-groundwater systems through time. In this review paper, we describe the underlying mechanisms of PRB performance and remove isolated misconceptions. We discuss the primary mechanisms of ZVI transformation and aging in PRBs and the role of iron corrosion products. We review numerous sites to reinforce our understanding of the interactions between groundwater contaminants and ZVI and the authigenic minerals that form within PRBs. Our findings show that ZVI corrosion products and mineral precipitates play critical roles in the long-term performance of PRBs by influencing the reactivity of ZVI. Pore occlusion by mineral precipitates occurs at the influent side of PRBs and is enhanced by dissolved oxygen and groundwater rich in dissolved solids and high alkalinity, which negatively impacts hydraulic conductivity, allowing contaminants to potentially bypass the treatment zone. Further development of site characterization tools and models is needed to support effective PRB designs for groundwater remediation.

Abstract: More than 4,000 sandstone-hosted uranium occurrences host over 1.2 billion pounds of mined and in situ U3O8 throughout the Colorado Plateau. Most of the resources are in two distinct mineral systems with deposits hosted in the Triassic Chinle and Jurassic Morrison Formations. In the Chinle mineral system, base metal sulfides typically accompany mineralization. The Morrison mineral system is characterized by V/U ratios up to 20. The uranium source was likely volcanic ash preserved as bentonitic mudstones in the Brushy Basin Member of the Morrison Formation, and lithic volcanic clasts, ash shards, and bentonitic clay in the lower part of the Chinle Formation. Vanadium originated from two possible sources: iron–titanium oxides that are extensively altered in bleached rock near deposits or from similar minerals in variably bleached red beds interbedded with and beneath the Morrison. In Chinle-hosted deposits, in addition to volcanic ash, a contributing source of both vanadium and uranium is proposed here for the first time to be underlying red beds in the Moenkopi and Cutler Formations that have undergone a cycle of reddening-bleaching-reoxidation. Transport in both systems was likely in groundwater through the more permeable sandstones and conglomerate units. The association of uranium minerals with carbonate and more rarely apatite, suggests that transport of uranium was as a carbonate or phosphate complex. The first comprehensive examination of paleoclimate, paleotopography, and subsurface structure of aquifers coupled with analysis of the geochronology of deposits suggests that that there were distinct pulses of uranium mineralization/redistribution during the period from about 259 Ma to 12 Ma when oxidized mineralizing fluids were intermittently rejuvenated in the Plateau in response to changes in tectonic regime and climate. Multiple lines of evidence indicate that deposits formed at ambient temperatures of about 25 °C to no greater than about 140 °C. In both systems, deposits formed where groundwater flow slowed and was subject to evaporative concentration. Stagnant conditions allowed for prolonged interaction of U- and V-enriched groundwater with ferrous iron-bearing reductants, such as illite and iron–titanium oxides, and more rarely organic material such as plant debris. Paragenetically late in the sequence, reducing fluids introduced additional organic matter to some deposits. Reducing fluids and introduced organic matter (now amorphous and altered by radiolysis) may originate from regional petroleum systems where peak oil and gas generation was from ∼ 82 to ∼ 5 Ma. Our novel analysis indicates that these reducing fluids bleached rock and protected affected deposits from remobilization during exposure and weathering that followed uplift of the Plateau (∼80 to 40 Ma).

Abstract: Many studies highlight the decrease in precipitation due to climate change in the Mediterranean region, making it a prominent hotspot. This study examines the combined impacts of climate change and three groundwater demand scenarios on the water resources of the Western Mountain Aquifer (WMA) in Israel and the West Bank. While commonly used methods for quantifying groundwater recharge and water resources rely on regression models, it is important to acknowledge their limitations when assessing climate change impacts. Regression models and other data-driven approaches are effective within observed variability but may lack predictive power when extrapolated to conditions beyond historical fluctuations. A comprehensive assessment requires distributed process-based numerical models incorporating a broader range of relevant physical flow processes and, ideally, ensemble model projections. In this study, we simulate the dynamics of dual-domain infiltration and precipitation partitioning using a HydroGeoSphere (HGS) model for variably saturated water flow coupled to a soil-epikarst water balance model in the WMA. The model input includes downscaled high-resolution climate projections until 2070 based on the IPCC RCP4.5 scenario. The results reveal a 5% to 10% decrease in long-term average groundwater recharge compared to a 30% reduction in average precipitation. The heterogeneity of karstic flow and increased intensity of individual rainfall events contribute to this mitigated impact on groundwater recharge, underscoring the importance of spatiotemporally resolved climate models with daily precipitation data. However, despite the moderate decrease in recharge, the study highlights the increasing length and severity of consecutive drought years with low recharge values. It emphasizes the need to adjust current management practices to climate change, as freshwater demand is expected to rise during these periods. Additionally, the study examines the emergence of hydrogeological droughts and their propagation from the surface to the groundwater. The results suggest that the 48-month standardized precipitation index (SPI-48) is a suitable indicator for hydrogeological drought emergence due to reduced groundwater recharge.