Abstract: During 2002 and 2003, bioremediation experiments in the unconfined aquifer of the Old Rifle UMTRA field site in western Colorado provided evidence for the immobilization of hexavalent uranium in groundwater by iron-reducing Geobacter sp. stimulated by acetate amendment. As the bioavailable Fe(III) terminal electron acceptor was depleted in the zone just downgradient of the acetate injection gallery, sulfate-reducing organisms came to dominate the microbial community. In the present study, we use multicomponent reactive transport modeling to analyze data from the 2002 field experiment to identify the dominant transport and biological processes controlling uranium mobility during biostimulation, and determine field-scale parameters for these modeled processes. The coupled process simulation approach was able to establish a quantitative characterization of the principal flow, transport, and reaction processes based on the 2002 field experiment, that could be applied without modification to describe the 2003 field experiment. Insights gained from this analysis include field-scale estimates of the bioavailable Fe(III) mineral threshold for the onset of sulfate reduction, and rates for the Fe(III), U(VI), and sulfate terminal electron accepting processes.

Abstract: Study region Zohreh River Basin, Southwest Iran Study focus The salinity of Zohreh River sharply increases in three salinity zones (SZs) along the river named SZ1, SZ2 (the focus of this study), and SZ3. Determining the salinity sources and salinization mechanism using an integrated approach including geological, hydrochemical, isotopic, geophysical, river sinuosity and hydrocarbon analysis are the main objectives of this study. The study focuses on the combination of evidence of regional-scale (i.e., river sinuosity and seismic data) and small-scale (i.e., drilling core analysis). New hydrologic insights for the region Among several known sources of river salinity, it was found that the water quality of the Zohreh River is mainly threatened by the salt-bearing Gachsaran Formation and oil-field brine. It is concluded that halite brine and oil-field brine simultaneously cause the salinization in SZ2, and their contributions were delineated to be 95% and 5%, respectively. The lack of reliable geological evidence to support halite dissolution in surficial layers by circulating waters suggests the possibility of a deep source of halite brine in SZ2. The results revealed that deep halite brine of the salt layers of Gachsaran Formation is mainly responsible for the salinization of SZ2. The mechanism of deep brine penetration to the river through the hidden fault failures detected by the combination of river sinuosity analysis and geophysical data for the first time.