Abstract: Numerous groundwater analyses from the crystalline bedrock in the Forsmark area have been performed between 2002 and 2019, together with thorough geological, geophysical, and hydrogeological studies, within the site investigations carried out by the Swedish Nuclear Fuel and Waste Management Company. The groundwater samples have been taken from boreholes down to ≈ 1000 m and the analysis include major- and trace-elements, stable and radiogenic isotopes, gases and microbes. The chemical and isotopic composition of these groundwaters evidences the presence of non-marine brackish to saline groundwaters with very long residence times (many hundreds of thousands of years) and a series of complex mixing events resulting from the recharge of different waters over time: glacial meltwaters, probably from different glaciations of which the latest culminated some 20,000 years ago, and marine waters from the Baltic starting some 7000 years ago. Later, meteoric water and present Baltic Sea water have recharged in different parts of the upper 100 m. These mixing events have also triggered chemical and microbial reactions that have conditioned some of the important groundwater parameters and, together with the structural complexity of the area, they have promoted a heterogeneous distribution of groundwater compositions in the bedrock. Due to these evident differences in chemistry, residence time and origin of the groundwater, several groundwater types were defined in order to facilitate the visualisation and communication. The differentiation (linked to the paleohydrological history of the area) was based on Cl concentration, Cl/Mg ratio (marine component), and δ18O value (glacial component). The work presented in this paper increases the understanding of the groundwater evolution in fractured and compartmentalised aquifers where mixing processes are the most important mechanisms. The model proposed to characterise the present groundwater system of the Forsmark area will also help to predict the future hydrogeochemical behaviour of the groundwater system after the construction of the repositories for the nuclear wastes.

Abstract: Paleohydrological data from the African tropics and subtropics, including lake, groundwater and speleothem records, are reviewed to show how environments and climates from both hemispheres are inter-related. Although orbitally induced changes in the monsoon strength account for a large part of long-term climatic changes in tropical Africa, the Late Pleistocene–Holocene hydrological fluctuations rather appear to have been a series of abrupt events that reflect complex interactions between orbital forcing, atmosphere, ocean and land surface conditions. During the Last Glacial Maximum (23–18ka BP), most records indicate that generally dry conditions have prevailed in both hemispheres, associated with lower tropical land- and sea-surface temperatures. This agrees with simulations using coupled ocean–atmosphere models, which predict cooling and reduced summer precipitation in tropical Africa; the global hydrological cycle was weaker than today when the extent of large polar ice-sheets and sea-ice was a prominent forcing factor of the Earth’s climate. Glacial-interglacial climatic changes started early: a first wetting/warming phase at ca. 17–16ka BP took place during a period of rapid temperature increase in Antarctica. Next, two drastic arid-humid transitions in equatorial and northern Africa occurred around 15–14.5ka BP and 11.5–11ka BP. Both are thought to match the major Greenland warming events, in concert with the switching of the oceanic thermohaline circulation to modern mode. However, part of the climatic signal after 15 ka BP also seems related to the Antarctica climate. During the Holocene, Africa has also experienced rapid hydrological fluctuations of dramatic magnitude compared to the climatic changes at high latitudes. In particular, major dry spells occurred around 8.4–8ka and 4.2–4ka BP in the northern monsoon domain. Comparison with other parts of the world indicates that these events have a worldwide distribution but different regional expressions. In the absence of large polar ice sheets, changes in the continental hydrological cycles in the tropics may have a significant impact on the global climate system. Climate information gathered here allows to identify geographical and methodological gaps, and raise some scientific questions that remain to be solved to better understand how the tropics respond to changes in major climate-forcing factors, and how they influence climate globally.

Abstract: Carbon dioxide (CO2) enhanced oil recovery (EOR) provides a pathway for economic reuse and storage of CO2, a greenhouse gas. One challenge with this practice is ensuring CO2 injection does not result in target reservoir fluids migrating into overlying shallow (\textless1000 m) groundwater formations. Effective monitoring for leakage from storage formations could involve measuring sensitive chemical indicators in overlying groundwater units and within the producing formation itself for evidence of deviation from an initial state. In this study, produced waters and overlying groundwaters were monitored over a five-year period to evaluate which geochemical signals may be useful to ensure that oilfield produced waters did not impact overlying groundwaters. During this five-year period, a mature carbonate oil reservoir in the Permian Basin transitioned from a waterflooding operation to a water-alternating-gas injection (WAG), in which the formation was flooded with CO2 and various mixtures of produced water. Significant increases in dissolved inorganic constituents [alkalinity, TDS, Na+, Cl−, SO42−] were observed in produced waters following CO2 injection; however, carbonate reservoir dissolution-precipitation reactions appear to be minimal and injected CO2 appears to be stored via solubility trapping. Although there are statistically significant geochemical variations following CO2 injection, applying isometric log-ratios to certain parameters establishes a narrow range for post-CO2 injection produced waters. This narrow range can be considered a baseline for post-CO2 injection produced waters; this baseline can be utilized to monitor overlying local groundwaters for produced water intrusion. Additionally, certain parameters [Na+, Ca2+, K+, Cl−, alkalinity, and TDS] display large concentration disparities between produced water and overlying groundwaters; these parameters would be sensitive indicators of produced water intrusion into overlying groundwaters.