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Author (down) Li, J.; Pang, Z.; Liu, Y.; Hu, S.; Jiang, W.; Tian, L.; Yang, G.; Jiang, Y.; Jiao, X.; Tian, J.
Title Changes in groundwater dynamics and geochemical evolution induced by drainage reorganization: Evidence from 81Kr and 36Cl dating of geothermal water in the Weihe Basin of China Type Journal Article
Year 2023 Publication Earth and Planetary Science Letters Abbreviated Journal
Volume 623 Issue Pages 118425
Keywords Kr dating, Cl dating, Geothermal water, Groundwater dynamics, Weihe basin
Abstract 81Kr and 36Cl can both be used to date groundwater beyond the dating range of 14C. 81Kr usually provides reliable groundwater ages because it has uniform initial distribution and negligible subsurface generation, while 36Cl is commonly influenced by subsurface sources or “dead” chloride dissolution. Therefore, the combined use of 81Kr and 36Cl could provide clues on the evolution history of groundwater. In the present study, we performed 36Cl and 81Kr dating of geothermal water in Weihe Basin of China and interpreted the possible cause of disagreement. Two distinct water masses were identified with distinctive isotopic signals: groundwater with significant δ18O shifts (up to −2.0‰), dissolved dead Cl and ages < 1.0 Ma (Cluster A), and older water with little δ18O shifts, negligible dissolved Cl and ages >1.0 Ma (Cluster B). The results confirm the eastward flow path of Cluster B to the Ancient Sanmen Lake with an increasing trend of Cl concentration and age. Modern recharge from the mountains flows to the basin center with intense interaction between water and carbonate under respective reservoir temperatures (100 ∼ 130 °C). These waters flow through the saline stratum emerging from the spillover of the Ancient Sanmen Lake, resulting in higher dead Cl dissolution. A significant linear relationship is observed with the older end-member of ∼1.3Ma under the topographically-driven faster circulation effect. 81Kr ages seem to support the hypothesis that the birth of the modern Yellow River was at about 1.0–1.3 Ma. We inferred the drainage reorganization from the Ancient Sanmen Lake to the modern Yellow River since the Mid-Pleistocene Transition induced the change in groundwater dynamics as well as its chemical evolution. The excavation of the Ancient Sanmen Lake and the accentuated incision of the Weihe River induced groundwater gradient, and therefore the recharge from precipitation from both slopes of the Qinling Mountains in the south and the Beishan Mountains in the north. Our results highlight the effects of dead Cl on 36Cl dating and demonstrate the significant impact of catchment reorganization on groundwater dynamics and its chemistry.
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Language Summary Language Original Title
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0012-821x ISBN Medium
Area Expedition Conference
Notes Approved no
Call Number THL @ christoph.kuells @ Li2023118425 Serial 212
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Author (down) Lawrinenko, M.; Kurwadkar, S.; Wilkin, R.T.
Title Long-term performance evaluation of zero-valent iron amended permeable reactive barriers for groundwater remediation – A mechanistic approach Type Journal Article
Year 2023 Publication Geoscience Frontiers Abbreviated Journal
Volume 14 Issue 2 Pages 101494
Keywords Geochemistry, Iron, Permeable reactive barrier, Plating reactions, Reduction potential, Surface passivation
Abstract Permeable reactive barriers (PRBs) are used for groundwater remediation at contaminated sites worldwide. This technology has been efficient at appropriate sites for treating organic and inorganic contaminants using zero-valent iron (ZVI) as a reductant and as a reactive material. Continued development of the technology over the years suggests that a robust understanding of PRB performance and the mechanisms involved is still lacking. Conflicting information in the scientific literature downplays the critical role of ZVI corrosion in the remediation of various organic and inorganic pollutants. Additionally, there is a lack of information on how different mechanisms act in tandem to affect ZVI-groundwater systems through time. In this review paper, we describe the underlying mechanisms of PRB performance and remove isolated misconceptions. We discuss the primary mechanisms of ZVI transformation and aging in PRBs and the role of iron corrosion products. We review numerous sites to reinforce our understanding of the interactions between groundwater contaminants and ZVI and the authigenic minerals that form within PRBs. Our findings show that ZVI corrosion products and mineral precipitates play critical roles in the long-term performance of PRBs by influencing the reactivity of ZVI. Pore occlusion by mineral precipitates occurs at the influent side of PRBs and is enhanced by dissolved oxygen and groundwater rich in dissolved solids and high alkalinity, which negatively impacts hydraulic conductivity, allowing contaminants to potentially bypass the treatment zone. Further development of site characterization tools and models is needed to support effective PRB designs for groundwater remediation.
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Language Summary Language Original Title
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 1674-9871 ISBN Medium
Area Expedition Conference
Notes Approved no
Call Number THL @ christoph.kuells @ lawrinenko_long-term_2023 Serial 143
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Author (down) Kurmanseiit, M.B.; Tungatarova, M.S.; Royer, J.-J.; Aizhulov, D.Y.; Shayakhmetov, N.M.; Kaltayev, A.
Title Streamline-based reactive transport modeling of uranium mining during in-situ leaching: Advantages and drawbacks Type Journal Article
Year 2023 Publication Hydrometallurgy Abbreviated Journal
Volume 220 Issue Pages 106107
Keywords 3D modeling, In-situ leaching, Reactive transport model, Streamlines, Uranium recovery
Abstract Reactive transport modeling is known to be computationally intensive when applied to 3D problems. Transforming sequential computing on the computer processor units (CPU) into parallelized computation on the high-performance parallel graphic processor units (GPU) is a classical approach to increasing computational performance. Another complementary approach is to decompose a complex 3D modeling problem into a set of simpler 1D problems using streamline approaches which can be easily parallelized, therefore reducing computation time. This paper investigates solutions to the equations governing dissolution and transport using streamlines coupled with a parallelization approach. In addition, an analytical solution to the dissolution and transfer equations of uranium describing the In-Situ Leaching (ISL) mining recovery is found using an approximation series to the 2nd order. The analytical solution is compared to the 1D numerical resolution along the streamlines and to the 3D simulation results superimposed on the streamline. Both approaches give similar results with a relative error of \textless2 % (2%). The proposed methodology is then applied to a case study in which the classical 3D resolution is compared to the newly suggested streamline solution, demonstrating that the streamline approach increases computational performances by a factor ranging from hundred to thousand depending on the complexity of the grid-block model.
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Language Summary Language Original Title
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0304-386x ISBN Medium
Area Expedition Conference
Notes Approved no
Call Number THL @ christoph.kuells @ kurmanseiit_streamline-based_2023 Serial 190
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Author (down) Kamruzzaman, M.; Chowdhury, A.
Title Flash flooding considerations aside: Knowledge brokering by the extension and advisory services to adapt a farming system to flash flooding Type Journal Article
Year 2023 Publication Heliyon Abbreviated Journal
Volume 9 Issue 9 Pages 19662
Keywords Flash flooding, Knowledge brokering, Extension and advisory services, Farming system, Climate change
Abstract The development of agriculture sector and livelihood in Bangladesh are threatened by various climatic stressors, including flash flooding. Therefore, Extension and advisory services (EAS) need to navigate the knowledge landscape effectively to connect various farm actors and help secure the optimum benefits of knowledge and information for making rational decisions. However, little is known how EAS can perform this task to combat various effects of climate change. This study investigates the means of brokering knowledge by the EAS to help the farming sector adapt to flash flooding. The research was conducted in the north-eastern part of Bangladesh with 73 staff of the Department of Agricultural Extension (DAE), the largest public EAS in Bangladesh. The results showed that DAE primarily dealt with crop production-related information. However, EAS did not navigate knowledge and information about flash flooding, such as weather forecasting and crop-saving-embankments updates, among the farming actors. Moreover, they missed the broad utilization of internet-based-communication channels to rapidly navigate information and knowledge about possible flash flooding and its adaptation strategies. This article provides some policy implications to effectively support the adaptation of farming system to flash flooding through EAS.
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Publisher Place of Publication Editor
Language Summary Language Original Title
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 2405-8440 ISBN Medium
Area Expedition Conference
Notes Approved no
Call Number THL @ christoph.kuells @ KAMRUZZAMAN2023e19662 Serial 235
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Author (down) Jroundi, F.; Povedano-Priego, C.; Pinel-Cabello, M.; Descostes, M.; Grizard, P.; Purevsan, B.; Merroun, M.L.
Title Evidence of microbial activity in a uranium roll-front deposit: Unlocking their potential role as bioenhancers of the ore genesis Type Journal Article
Year 2023 Publication Science of The Total Environment Abbreviated Journal
Volume 861 Issue Pages 160636
Keywords ISR, Metatranscriptomes, Microbial metabolisms, Ore genesis, Roll-front deposit, Uranium
Abstract Uranium (U) roll-front deposits constitute a valuable source for an economical extraction by in situ recovery (ISR) mining. Such technology may induce changes in the subsurface microbiota, raising questions about the way their activities could build a functional ecosystem in such extreme environments (i.e.: oligotrophy and high SO4 concentration and salinity). Additionally, more information is needed to dissipate the doubts about the microbial role in the genesis of such U orebodies. A U roll-front deposit hosted in an aquifer driven system (in Zoovch Ovoo, Mongolia), intended for mining by acid ISR, was previously explored and showed to be governed by a complex bacterial diversity, linked to the redox zonation and the geochemical conditions. Here for the first time, transcriptional activities of microorganisms living in such U ore deposits are determined and their metabolic capabilities allocated in the three redox-inherited compartments, naturally defined by the roll-front system. Several genes encoding for crucial metabolic pathways demonstrated a strong biological role controlling the subsurface cycling of many elements including nitrate, sulfate, metals and radionuclides (e.g.: uranium), through oxidation-reduction reactions. Interestingly, the discovered transcriptional behaviour gives important insights into the good microbial adaptation to the geochemical conditions and their active contribution to the stabilization of the U ore deposits. Overall, evidences on the importance of these microbial metabolic activities in the aquifer system are discussed that may clarify the doubts on the microbial role in the genesis of low-temperature U roll-front deposits, along the Zoovch Ovoo mine.
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Language Summary Language Original Title
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0048-9697 ISBN Medium
Area Expedition Conference
Notes Approved no
Call Number THL @ christoph.kuells @ jroundi_evidence_2023 Serial 138
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Author (down) Johnson, R.S.H.; Alila, Y.
Title Nonstationary stochastic paired watershed approach: Investigating forest harvesting effects on floods in two large, nested, and snow-dominated watersheds in British Columbia, Canada Type Journal Article
Year 2023 Publication Journal of Hydrology Abbreviated Journal
Volume 625 Issue Pages 129970
Keywords Probabilistic physics, Forest hydrology, Attribution science, Flood Frequency Analysis, Stochastic hydrology, Nonstationarity
Abstract Drawing on advances in nonstationary frequency analysis and the science of causation and attribution, this study employs a newly developed nonstationary stochastic paired watershed approach to determine the effect of forest harvesting on snowmelt-generated floods. Moreover, this study furthers the application of stochastic physics to evaluate the environmental controls and drivers of flood response. Physically-based climate and time-varying harvesting data are used as covariates to drive the nonstationary flood frequency distribution parameters to detect, attribute, and quantify the effect of harvesting on floods in the snow-dominated Deadman River (878 km2) and nested Joe Ross Creek (99 km2) watersheds. Harvesting only 21% of the watershed caused a 38% and 84% increase in the mean but no increase in variability around the mean of the frequency distribution in the Deadman River and Joe Ross Creek, respectively. Consequently, the 7-year, 20-year, 50-year, and 100-year flood events became approximately two, four, six, and ten times more frequent in both watersheds. An increase in the mean is posited to occur from an increase in moisture availability following harvest from suppressed snow interception and increased net radiation reaching the snowpack. Variability was not increased because snowmelt synchronization was inhibited by the buffering capacity of abundant lakes, evenly distributed aspects, and widespread spatial distribution of cutblocks in the watersheds, preventing any potential for harvesting to increase the efficiency of runoff delivery to the outlet. Consistent with similar recent studies, the effect of logging on floods is controlled not only by the harvest rate but most importantly the physiographic characteristics of the watershed and the spatial distribution of the cutblocks. Imposed by the probabilistic framework to understanding and predicting the relation between extremes and their environmental controls, commonly used in the general sciences but not forest hydrology, it is the inherent nature of snowmelt-driven flood regimes which cause even modest increases in magnitude, especially in the upper tail of the distribution, to translate into surprisingly large changes in frequency. Contrary to conventional wisdom, harvesting influenced small, medium, and very large flood events, and the sensitivity to harvest increased with increasing flood event size and watershed area.
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Publisher Place of Publication Editor
Language Summary Language Original Title
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0022-1694 ISBN Medium
Area Expedition Conference
Notes Approved no
Call Number THL @ christoph.kuells @ Johnson2023129970 Serial 245
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Author (down) Ibrahim, A.S.; Zayed, I.S.A.; Abdelhaleem, F.S.; Afify, M.M.; Ahmed, A.; Abd-Elaty, I.
Title Identifying cost-effective locations of storage dams for rainfall harvesting and flash flood mitigation in arid and semi-arid regions Type Journal Article
Year 2023 Publication Journal of Hydrology: Regional Studies Abbreviated Journal
Volume 50 Issue Pages 101526
Keywords Flash flood, Morphometric parameters, GIS, Cost-effective, Wadi Tayyibah, Dams
Abstract Study region Wadi Tayyibah is located in south Sinai, Egypt, in a region called Abou Zenima, and it is used to develop this study. Study focus Flash floods tremendously impact many facets of human life due to their destructive consequences and the costs associated with mitigating efforts. This study aims to evaluate the harvesting of Runoff by delineating the watersheds using the Hydrologic Engineering Center-1 (HEC-1) model and ArcGIS software in trying to benefit from it in different ways. All morphometric parameters of the basin were considered, and the risk degree of the different sub-basins was determined. The suitable locations of dams were identified using a Geographical Information System (GIS) using the basin’s morphometric characteristics. New hydrological insights for the region The study proposed a total number of eight dams, including five dams that were recommended for sub-basin (1) and three dams in sub-basin (4), while sub-basins (2) and (3) are not suitable locations to build dams according to the contour map of Wadi Tayyibah. Results indicate that, based on the constructed flash flood hazard maps and the basin’s detailed morphometric characteristics, the best locations of dams are Dam (3) in sub-basin (1) and Dam (7) in sub-basin (4), where the runoff volume reached 3.13 million cubic meters (Mm3) and 5.56 Mm3 for return period 100, respectively. This study is useful for decision-makers and designers for using morphometric parameters and flash flood hazard degree maps to select dam locations. Also, the cost-benefit analysis for using the morphometric parameters is required to be investigated.
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Language Summary Language Original Title
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 2214-5818 ISBN Medium
Area Expedition Conference
Notes Approved no
Call Number THL @ christoph.kuells @ Ibrahim2023101526 Serial 238
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Author (down) Holmes, M.; Campbell, E.E.; Wit, M. de; Taylor, J.C.
Title Can diatoms be used as a biomonitoring tool for surface and groundwater?: Towards a baseline for Karoo water Type Journal Article
Year 2023 Publication South African Journal of Botany Abbreviated Journal
Volume 161 Issue Pages 211-221
Keywords Bioindicator, Diatom, Hydraulic fracturing, Karoo, Water quality
Abstract The environmental risks from shale gas extraction through the unconventional method of ‘fracking’ are considerable and impact on water supplies below and above ground. Since 2010 the recovery of natural shale gas through fracking has been proposed in parts of the fragile semi-arid ecosystems that make up the Karoo biome in South Africa. These unique ecosystems are heavily reliant on underground water, intermittent and ephemeral springs, which are at great risk of contamination by fracking processes. Diatoms are present in all water bodies and reflect aspects of the environment in which they are located. As the possibility of fracking has not been removed, the aim of the project was to determine if diatoms could be used for rapid biomonitoring of underground and surface waters in the Karoo. Over a period of 24 months, water samples and diatom species were collected simultaneously from 65 sites. A total of 388 diatom taxa were identified from 290 samples with seasonal and substrate variation affecting species composition but not the environmental information. Species diversity information, on the other hand, often varied significantly between substrates within a single sample. Analysis using CCA established that the diatom composition was affected by lithium, oxidized nitrogen, electrical conductivity, and sulphate levels in the sampled water. We conclude that changes in diatom community composition in the Karoo do reflect the water chemistry and could be useful as bioindicators.
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Publisher Place of Publication Editor
Language Summary Language Original Title
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0254-6299 ISBN Medium
Area Expedition Conference
Notes Approved no
Call Number THL @ christoph.kuells @ holmes_can_2023 Serial 163
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Author (down) Hofmann, H.; Pearce, J.K.; Hayes, P.; Golding, S.D.; Hall, N.; Baublys, K.A.; Raiber, M.; Suckow, A.
Title Multi-tracer approach to constrain groundwater flow and geochemical baseline assessments for CO2 sequestration in deep sedimentary basins Type Journal Article
Year 2023 Publication International Journal of Coal Geology Abbreviated Journal
Volume Issue Pages 104438
Keywords CO geological storage, Great Artesian Basin, Groundwater chemistry, Isotopic tracer, Surat Basin
Abstract Geological storage of gases will be necessary in the push to net zero and the energy transition to reduce carbon emissions to atmosphere. These include CO2 geological storage in suitable sandstone reservoirs. Understanding groundwater flow, connectivity and hydrogeochemical processes in aquifer and storage systems is vital to prevent risk and protect important water resources, such as the Great Artesian Basin. Here, we provide a ‘tool-box’ of geochemical assessment methods to provide information on flow patterns through the basin’s aquifers (changes in chemistry along flow path), stagnant versus flowing conditions (cosmogenic isotopes and noble gases), inter-aquifer connectivity and seal properties (major ions, Sr and stable isotopes), water quality (major ions and metals) and general assessments on residence times of groundwater (cosmogenic isotopes and noble gases). This information can be used with reservoir and groundwater models to inform on possible changes in the above-mentioned processes and serve as input parameters for CO2 injection impact modelling. We demonstrate the use and interpretation on an example of a potential CO2 storage geological sequestration site in the Surat Basin, part of the Great Artesian Basin, and the aquifers that overly the reservoir. The stable water isotopes are depleted compared to average rainfall and most likely indicate greater contributions from monsoonal rain events from the northern monsoonal troughs, where amount and rainout effects lead to the depletion rather than colder recharge climates. This is supported by the modern recharge temperatures from noble gases. Inter-aquifer mixing between the Precipice Sandstone reservoir and the Hutton Sandstone aquifer seems unlikely as the Sr isotope ratios are distinctly different suggesting that the Evergreen Formation is a seal in the locations sampled. Mixing, however, occurs on the edges of the basin, especially in the south-east and east where the Surat Basin transitions into the Clarence-Moreton Basin. Groundwater flow appears to be to the south in the Precipice Sandstone, with a component of flow east to the Clarence-Morton Basin. The cosmogenic isotopes and noble gases strongly indicate very long residence times of groundwater in the central south Precipice Sandstone around a proposed storage site. 14C values below analytical uncertainty, R36Cl ratios at secular equilibrium as well as high He concentrations and high 40Ar/36Ar ratios support the argument that groundwater flow in this area is extremely slow or groundwater is stagnant. The results of this study reflect the geological and hydrogeological complexities of sedimentary basins and that baseline studies, such as this one, are paramount for management strategies.
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Language Summary Language Original Title
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0166-5162 ISBN Medium
Area Expedition Conference
Notes Approved no
Call Number THL @ christoph.kuells @ hofmann_multi-tracer_2023 Serial 165
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Author (down) Heidari, B.; Prideaux, V.; Jack, K.; Jaber, F.H.
Title A planning framework to mitigate localized urban stormwater inlet flooding using distributed Green Stormwater Infrastructure at an urban scale: Case study of Dallas, Texas Type Journal Article
Year 2023 Publication Journal of Hydrology Abbreviated Journal
Volume 621 Issue Pages 129538
Keywords Green stormwater infrastructure, Localized inlet pluvial flooding, Opportunity subwatersheds, Stormwater investment prioritization, Resilient urban watershed planning
Abstract Mitigation of localized pluvial flooding is one of the major resiliency goals in urban environments, and Green Stormwater Infrastructure (GSI) has the potential to deliver such an outcome. However, there is a lack of systematic approaches to prioritize investment in different candidate areas. This study provides a framework to identify vulnerable stormwater drainage inlets and their contributing areas, prioritize them, identify dominant factors in their selection, assess the potential of GSI in mitigating their overflows, and compare the impact and its cost to gray infrastructure upgrade alternatives. Using SWMM 5.1.013, decision trees, and a volumetric-based assessment of GSI overflow capture, we applied the framework to the City of Dallas, Texas, for three design storms with three GSI practices— bioretention cells, raingardens, and rainwater harvesting tanks. Results showed that there was a significant increase in the number of overflowing stormwater drainage inlets, referred to as hotspots, and their contributing subwatersheds, referred to as opportunity areas, with more intense storms especially in problematic watersheds. Also, prioritization results provided a series of maps to rank the opportunity areas based on overflow severity, recurrence of the overflows, and GSI availability. Moreover, classification results showed that inlet features, especially the inlet depth, were the dominant factors in the identification of the non-problematic inlets. Finally, the GSI impact assessment showed substantial overflow mitigation even at the “very high” severity levels when GSI is comprehensively deployed across opportunity areas. Despite gray infrastructure upgrades yielding higher reduction levels, their cost per cubic meter was higher than GSI. Therefore, a combination of GSI and gray results in maximum overflow reduction at a lower cost compared to common practices.
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Publisher Place of Publication Editor
Language Summary Language Original Title
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0022-1694 ISBN Medium
Area Expedition Conference
Notes Approved no
Call Number THL @ christoph.kuells @ Heidari2023129538 Serial 226
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