| Records |
| Author |
Liu, Z.; Tan, K.; Li, C.; Li, Y.; Zhang, C.; Song, J.; Liu, L. |
| Title |
Geochemical and S isotopic studies of pollutant evolution in groundwater after acid in situ leaching in a uranium mine area in Xinjiang |
Type |
Journal Article |
| Year |
2023 |
Publication |
Nuclear Engineering and Technology |
Abbreviated Journal |
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| Volume |
55 |
Issue |
4 |
Pages |
1476-1484 |
| Keywords |
Acid in situ leaching of uranium, Pollution evolution, Sulfate elimination, Sulfur isotopes analysis |
| Abstract |
Laboratory experiments and point monitoring of reservoir sediments have proven that stable sulfate reduction (SSR) can lower the concentrations of toxic metals and sulfate in acidic groundwater for a long time. Here, we hypothesize that SSR occurred during in situ leaching after uranium mining, which can impact the fate of acid groundwater in an entire region. To test this, we applied a sulfur isotope fractionation method to analyze the mechanism for natural attenuation of contaminated groundwater produced by acid in situ leaching of uranium (Xinjiang, China). The results showed that δ34S increased over time after the cessation of uranium mining, and natural attenuation caused considerable, area-scale immobilization of sulfur corresponding to retention levels of 5.3%–48.3% while simultaneously decreasing the concentration of uranium. Isotopic evidence for SSR in the area, together with evidence for changes of pollutant concentrations, suggest that area-scale SSR is most likely also important at other acid mining sites for uranium, where retention of acid groundwater may be strengthened through natural attenuation. To recapitulate, the sulfur isotope fractionation method constitutes a relatively accurate tool for quantification of spatiotemporal trends for groundwater during migration and transformation resulting from acid in situ leaching of uranium in northern China. |
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1738-5733 |
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THL @ christoph.kuells @ liu_geochemical_2023 |
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192 |
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| Author |
Liu, Z.; Li, C.; Tan, K.; Li, Y.; Tan, W.; Li, X.; Zhang, C.; Meng, S.; Liu, L. |
| Title |
Study of natural attenuation after acid in situ leaching of uranium mines using isotope fractionation and geochemical data |
Type |
Journal Article |
| Year |
2023 |
Publication |
Science of The Total Environment |
Abbreviated Journal |
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| Volume |
865 |
Issue |
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Pages |
161033 |
| Keywords |
Acid in situ leaching, Geochemical and isotopic tracing, Groundwater contamination, Natural attenuation, Uranium post-mining |
| Abstract |
Acid in situ leaching (AISL) is a subsurface mining approach suitable for low-grade ores which does not generate tailings, and has been adopted widely in uranium mining. However, this technique causes an extremely high concentration of contaminants at post-mining sites and in the surroundings soon after the mining ceases. As a potential AISL remediation strategy, natural attenuation has not been studied in detail. To address this problem, groundwater collected from 26 wells located within, adjacent, upgradient, and downgradient of a post-mining site were chosen to analyze the fate of U(VI), SO42−, δ34S, and δ238U, to reveal the main mechanisms governing the migration and attenuation of the dominant contaminants and the spatio-temporal evolutions of contaminants in the confined aquifer of the post-mining site. The δ238U values vary from −0.07 ‰ to 0.09 ‰ in the post-mining site and from −1.43 ‰ to 0.03 ‰ around the post-mining site. The δ34S values were found to vary from 3.3 ‰ to 6.2 ‰ in the post-mining site and from 6.0 ‰ to 11.0 ‰ around the post-mining site. Detailed analysis suggests that there are large differences between the range of isotopic composition variation and the range of pollutants concentration distribution, and the estimated Rayleigh isotope fractionation factor is 0.9994–0.9997 for uranium and 1.0032–1.0061 for sulfur. The isotope ratio of uranium and sulfur can be used to deduce the migration history of the contaminants and the irreversibility of the natural attenuation process in the anoxic confined aquifer. Combining the isotopic fractionation data for U and S with the concentrations of uranium and sulfate improved the accuracy of understanding of reducing conditions along the flow path. The study also indicated that as long as the geological conditions are favorable for redox reactions, natural attenuation could be used as a cost-effective remediation scheme. |
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0048-9697 |
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THL @ christoph.kuells @ liu_study_2023 |
Serial |
155 |
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Li, X.; Shen, K.; Li, Q.; Deng, Y.; Zhu, P.; Wang, D. |
| Title |
Roll-over behavior in current-voltage curve introduced by an energy barrier at the front contact in thin film CdTe solar cell |
Type |
Journal Article |
| Year |
2018 |
Publication |
Solar Energy |
Abbreviated Journal |
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| Volume |
165 |
Issue |
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Pages |
27-34 |
| Keywords |
AlO HRT layer, Band alignment, CdTe solar cell, Roll-over behavior |
| Abstract |
Roll-over phenomenon in the current–voltage (J–V) curve is often observed in a CdTe thin film solar cell. The roll-over phenomenon, which is occurred near the open-circuit voltage in a light J–V curve, is due to Schottky energy barrier formed at the CdTe/metal interface in a CdTe solar cell back contact. In this study we report a J–V roll-over phenomenon which is induced by an energy barrier at the front contact of a CdTe solar cell. Two kinds of oxides, namely, Al2O3 and SnO2, were deposited as high-resistance transparent (HRT) layer between the window layer CdS and the fluorine doped tin oxide (FTO) front electrode in CdTe solar cells. These two oxides present much different electronic band alignment with FTO and CdS. SnO2 formed almost no energy barrier with CdS, this allowed smooth transport for photo-generated electrons from CdTe to CdS and FTO. However, Al2O3 formed a high energy barrier with CdS. The rather high energy barrier with a value of 3.43 eV at the CdS/Al2O3 interface induced a J–V roll-over phenomenon in a CdTe thin film solar cell, which dramatically led to a quick decrease for the cell device efficiency. The electron transport at the FTO/Al2O3/CdS interface is governed by tunneling effect. The results presented in this study demonstrate that the band structure at the front electrode plays an important role for the performance of a CdTe thin film solar cell. |
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0038-092x |
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no |
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THL @ christoph.kuells @ li_roll-over_2018 |
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187 |
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| Author |
Love, A.J.; Shand, P.; Karlstrom, K.; Crossey, L.; Rousseau-Gueutin, P.; Priestley, S.; Wholing, D.; Fulton, S.; Keppel, M. |
| Title |
Geochemistry and Travertine Dating Provide New Insights into the Hydrogeology of the Great Artesian Basin, South Australia |
Type |
Journal Article |
| Year |
2013 |
Publication |
Procedia Earth and Planetary Science |
Abbreviated Journal |
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| Volume |
7 |
Issue |
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Pages |
521-524 |
| Keywords |
GAB springs, Great Artesian Basin, Helium isotope data, Uranium series dating |
| Abstract |
While of great national and societal significance, and importance in its own right, the Great Artesian Basin of Australia is an iconic example of a continental scale artesian groundwater system. New geochemical, hydrological, and neo-tectonic data suggests that existing models that involve recharge in eastern Australia, relatively simple flowpaths and discharge in springs in the western margin require modification. New geochemical data indicate a small volume flux of deeply derived (endogenic) fluids mixing into the aquifer system at a continental scale. Neo- tectonic data indicates active tectonism today that provides a fluid pathway through faults for the deeply sourced endogenic fluids to discharge in GAB travertine depositing springs. |
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1878-5220 |
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no |
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THL @ christoph.kuells @ love_geochemistry_2013 |
Serial |
122 |
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Mabrouk, M.; Han, H.; Fan, C.; Abdrabo, K.I.; Shen, G.; Saber, M.; Kantoush, S.A.; Sumi, T. |
| Title |
Assessing the effectiveness of nature-based solutions-strengthened urban planning mechanisms in forming flood-resilient cities |
Type |
Journal Article |
| Year |
2023 |
Publication |
Journal of Environmental Management |
Abbreviated Journal |
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| Volume |
344 |
Issue |
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Pages |
118260 |
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Flood, Urban planning, Sustainable cities, LID, Natural-based solutions, Alexandria |
| Abstract |
Cities have experienced rapid urbanization-induced harsh climatic events, especially flooding, inevitably resulting in negative and irreversible consequences for urban resilience and endangering residents’ lives. Numerous studies have analyzed the effects of anthropogenic practices (land use changes and urbanization) on flood forecasting. However, non-structural mitigation’s effectiveness, like Nature-Based Solutions (NBS), has yet to receive adequate attention, particularly in the Middle East and North Africa (MENA) region, which have become increasingly significant and indispensable for operationalizing cities efficiently. Therefore, our study investigated the predictive influence of incorporating one of the most common NBS strategies called low-impact development tools (LID) (such as rain gardens, bio-retention cells, green roofs, infiltration trenches, permeable pavement, and vegetative swale) during the urban planning of Alexandria, Egypt, which experiences the harshest rainfall annually and includes various urban patterns. City characteristics-dependent 14 LID scenarios were simulated with recurrence intervals ranging from 2 to 100 years using the LID Treatment Train Tool (LID TTT), depending on calibrated data from 2015 to 2020, by the Nash-Sutcliffe efficiency index and deterministic coefficient, and root-mean-square error with values of 0.97, 0.91, and 0.31, respectively. Our findings confirmed the significant effectiveness of combined LID tools on total flood runoff volume reduction by 73.7%, revealing that different urban patterns can be used in flood-prone cities, provided LID tools are considered in city planning besides grey infrastructure to achieve optimal mitigation. These results, which combined multiple disciplines and were not explicitly mentioned in similar studies in developing countries, may assist municipalities’ policymakers in planning flood-resistant, sustainable cities. |
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0301-4797 |
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no |
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THL @ christoph.kuells @ Mabrouk2023118260 |
Serial |
232 |
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Tanwer, N.; Arora, V.; Kant, K.; Singh, B.; Laura, J.S.; Khosla, B. |
| Title |
Chapter 17 – Prevalence of Uranium in groundwater of rural and urban regions of India |
Type |
Book Chapter |
| Year |
2024 |
Publication |
Water Resources Management for Rural Development |
Abbreviated Journal |
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Issue |
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Pages |
213-234 |
| Keywords |
Distribution, Heath impacts, Remediation techniques, Sources, Uranium |
| Abstract |
Abnormally high uranium (U) prevalence in groundwater is a neoteric subject of concern throughout the world because of its direct impact on human health and well-being. Groundwater is used as the most preferred choice for drinking because of its good quality and ease of availability in rural and urban parts of India, and also in different parts of the world. India is an agriculture-dominant country and its 50–80% irrigational requirement is met by groundwater, besides this nearly 90% of rural and 50% of urban water needs are fulfilled by groundwater. The uranium concentration in groundwater in different parts of India namely Punjab, Haryana, Rajasthan, Madhya Pradesh, Karnataka, etc. found to be varying from 0 mg/L to 1443 mg/L, and in different parts of the world, it is found up to 1400 mg/L in the countries like United States, Canada, Finland, Mongolia, Nigeria, South Korea, Pakistan, Burundi, China, Afghanistan, etc. Various natural factors such as geology, hydro-geochemistry, and prevailing conditions as well as anthropogenic factors including mining, nuclear activities, erratic use of fertilizers, and overexploitation of groundwater resources are responsible for adding uranium in groundwater. Groundwater is considered a primary source of uranium ingestion in human beings as it contributes 85% while food contributes 15%. Uranium affects living beings as a two-way sword, being a radioactive element, causing radiotoxicity, and on the other hand as a heavy metal, it causes chemotoxicity. The main target organs affected by the consumption of uranium-contaminated water are kidneys, bones, lungs, etc. It can cause renal failure, impair cell functioning and bone growth, and mutation in DNA. Although, its toxic effects, being a heavy metal, are more severe than its radiotoxicity. Various techniques are available for the efficient removal of uranium from the groundwater such as bioremediation, nanotechnology-enhanced remediation, adsorption, filtration, etc. This chapter entails a comprehensive investigation of uranium contamination in groundwater of rural and urban parts of India their probable sources, health impacts, treatment, and mitigation techniques available to manage groundwater resources. |
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Elsevier |
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Madhav, S.; Srivastav, A.L.; Izah, S.C.; Hullebusch, E. van |
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978-0-443-18778-0 |
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THL @ christoph.kuells @ madhav_chapter_2024 |
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152 |
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Martínez-Santos, P.; Martínez-Alfaro, P.E. |
| Title |
A priori mapping of historical water-supply galleries based on archive records and sparse material remains. An application to the Amaniel qanat (Madrid, Spain) |
Type |
Journal Article |
| Year |
2014 |
Publication |
Journal of Cultural Heritage |
Abbreviated Journal |
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15 |
Issue |
6 |
Pages |
656-664 |
| Keywords |
Hydraulic heritage, Qanat, Groundwater, Foggara, Water-supply, Amaniel, Madrid |
| Abstract |
Engineering heritage refers to a broad variety of items of social, economic, aesthetic or historic relevance, including roads, dams, buildings and supply networks. Due to their utilitarian nature, their heritage value is often overlooked. This occurs even with those infrastructures that have played an essential role in underpinning the daily existence of entire civilizations. Underground water-supply networks provide an excellent example. Although there are exceptions, water networks tend to be functional in design, rather than monumental. Moreover, they present intricate linear layouts that often span several kilometres. This means they are costly to maintain once their operational life is over, and that they are prone to abandonment and destruction. Devising a priori protection strategies is important to preserve these valuable cultural assets. The following pages present a method to map linear structures based on archive records and sparse material remains. The method is illustrated through its application to the Amaniel qanat, a water-supply gallery built in Madrid, Spain, in the early 17th Century. An appraisal of the known remains was carried out first, leading to an inventory of galleries, shafts, shaft caps and deposits. This was followed by a thorough survey of over one thousand handwritten manuscripts, including physical descriptions of the aqueduct, budget accounts or water metering campaigns, among other documents. Known remains and written evidence were matched against original and auxiliary maps to reconstruct the itinerary of the aqueduct. This led to the identification of sectors where it is still possible to find remains in good condition. Thus, a priori mapping is advocated a valuable technique to locate and preserve these remains, as well as to devise non-invasive surveys and establish heritage protection zones. |
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Edition |
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1296-2074 |
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no |
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THL @ christoph.kuells @ Martinezsantos2014656 |
Serial |
270 |
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Mathuthu, M.; Uushona, V.; Indongo, V. |
| Title |
Radiological safety of groundwater around a uranium mine in Namibia |
Type |
Journal Article |
| Year |
2021 |
Publication |
Physics and Chemistry of the Earth, Parts A/B/C |
Abbreviated Journal |
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122 |
Issue |
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Pages |
102915 |
| Keywords |
Groundwater, ICP-MS, Radiological hazard, Uranium mining |
| Abstract |
Uranium mining activities produce the main element used in nuclear energy production. However, it can also negatively affect the environment including groundwater by release of residues or effluent containing radioactive elements. The study investigated the concentration and radiological hazard of uranium in groundwater and seepage water from the tailings of a uranium mine in Namibia. Inductively Coupled Plasma Mass Spectrometry (ICP-MS) was used to assess the concentration of uranium in the groundwater and seepage water and the radiological hazards were determined. The radiological hazard indices Radium equivalent activity (Raeq), Absorbed dose (D), Annual Effective Dose equivalent (AEDE), External hazard index (Hex) and Internal hazard index (Hin) were determined and compared to limits recommended by United Nations Scientific Committee on the Effects of Atomic Radiation (UNSCEAR). The calculated average value of D and Hin of groundwater is 108.11nGyh−1 and 1.26, respectively and are above the UNSCEAR values (55 nGyh−1 and 1). Further, the average values of Raeq, AEDE and Hex were below the recommended values. The isotopic ratio of uranium radionuclides in groundwater indicates that the uranium in the sampled groundwater is below 1 suggesting it is not natural uranium present but a possible contamination from the mine seepage. The radiological hazard parameters of the seepage water were above the recommended values and thus pose a radiation risk to human and environment. |
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Edition |
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1474-7065 |
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THL @ christoph.kuells @ mathuthu_radiological_2021 |
Serial |
160 |
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| Author |
Mekuria, W.; Tegegne, D. |
| Title |
Water harvesting |
Type |
Book Chapter |
| Year |
2023 |
Publication |
Encyclopedia of Soils in the Environment (Second Edition) |
Abbreviated Journal |
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Issue |
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Pages |
593-607 |
| Keywords |
Climate change, Ecosystem services, Environmental benefits, Population growth, Resilient community, Resilient environment, Socio-economic benefits, Urbanizations, Water harvesting, Water quality, Water security |
| Abstract |
Water harvesting is the intentional collection and concentration of rainwater and runoff to offset irrigation demands. Secondary benefits include decreased flood and erosion risk. Water harvesting techniques include micro- and macro-catchment systems, floodwater harvesting, and rooftop and groundwater harvesting. The techniques vary with catchment type and size, and the method of water storage. Micro-catchment water harvesting, for example, requires the development of small structures and targets increased water delivery and storage to the root zone whereas macro-catchment systems collect runoff water from large areas. The sustainability of water harvesting techniques at the local level are usually constrained by several factors such as labor, construction costs, loss of productive land, and maintenance, suggesting that multiple solutions are required to sustain the benefits of water harvesting techniques. |
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Academic Press |
Place of Publication |
Oxford |
Editor |
Goss, M.J.; Oliver, M. |
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978-0-323-95133-3 |
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no |
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THL @ christoph.kuells @ Mekuria2023593 |
Serial |
225 |
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| Author |
Mekuria, W.; Tegegne, D. |
| Title |
Water harvesting |
Type |
Book Chapter |
| Year |
2023 |
Publication |
Encyclopedia of Soils in the Environment (Second Edition) |
Abbreviated Journal |
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Issue |
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Pages |
593-607 |
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Climate change, Ecosystem services, Environmental benefits, Population growth, Resilient community, Resilient environment, Socio-economic benefits, Urbanizations, Water harvesting, Water quality, Water security |
| Abstract |
Water harvesting is the intentional collection and concentration of rainwater and runoff to offset irrigation demands. Secondary benefits include decreased flood and erosion risk. Water harvesting techniques include micro- and macro-catchment systems, floodwater harvesting, and rooftop and groundwater harvesting. The techniques vary with catchment type and size, and the method of water storage. Micro-catchment water harvesting, for example, requires the development of small structures and targets increased water delivery and storage to the root zone whereas macro-catchment systems collect runoff water from large areas. The sustainability of water harvesting techniques at the local level are usually constrained by several factors such as labor, construction costs, loss of productive land, and maintenance, suggesting that multiple solutions are required to sustain the benefits of water harvesting techniques. |
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Academic Press |
Place of Publication |
Oxford |
Editor |
Goss, M.J.; Oliver, M. |
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978-0-323-95133-3 |
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no |
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THL @ christoph.kuells @ Mekuria2023593 |
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265 |
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