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Wilson, G. B., & McNeill, G. W. (1997). Noble gas recharge temperatures and the excess air component. Applied Geochemistry, 12(6), 747–762.
Abstract: The calculation of a groundwater recharge temperature based on the dissolved concentrations of Ne, Ar, Kr and Xe requires a correction for noble gas supersaturation due to excess air entrainment. This entrainment is commonly attributed to the recharge process or to air contamination at the wellhead during sample collection. With the exception of some local studies, most work has concentrated on interpretation of the recharge temperature or quantification of the radiogenic content for palaeoclimatic and dating purposes. The magnitude and source of the excess air is not directly relevant to these studies and so is often ignored. In this work, excess air Ne and other data have been calculated from new and published noble gas data sets for several groundwater systems. For younger groundwaters which have been recharged under one broad climatic regime, the amount of air entrainment increases according to lithology in the order granites, sandstones and limestones respectively. A negative correlation between precipitation and excess air entrainment is identified in at least one aquifer, and some of the mechanisms which may influence the entrainment process are discussed.
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Heaton, T. H. E., Talma, A. S., & Vogel, J. C. (1983). Origin and history of nitrate in confined groundwater in the western Kalahari. Journal of Hydrology, 62(1), 243–262.
Abstract: Data are presented for nitrate, dinitrogen and argon concentrations and 15N14N ratios in groundwater, with radiocarbon ages up to 40,000 yr. for three confined sandstone aquifers in the western Kalahari of South West Africa/Namibia. The nitrate is probably generated within the soil of the recharge areas, and its production rate during the period 3000-40,000 B.P. has remained between 0.5 and 1.6 meq NO−3l−1 of recharge water, with ° 15N between + 4 and + 8‰. Variations in the amount of nitrate and of “excess air” in groundwater recharge are found, and can only reflect changes in the environmental conditions during recharge. They must therefore be caused by the climatic changes that have taken place during the past 25,000 yr.
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Doulgeris, C., Tziritis, E., Pisinaras, V., Panagopoulos, A., & Külls, C. (2020). Prediction of seawater intrusion to coastal aquifers based on non-dimensional diagrams. In EGU Geophysical Abstracts (4073).
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Leibundgut, C., Maloszewski, P., & Külls, C. (2009). Tracers in Hydrology. John Wiley & Sons, Ltd.
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Külls, C. (2001). Groundwater of the North-Western Kalahari, Namibia: estimation of recharge and quantification of the flow system. Doctoral thesis, Hydrogeologie und Umwelt, .
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