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Author Aderemi, B.A.; Olwal, T.O.; Ndambuki, J.M.; Rwanga, S.S. url  openurl
  Title Groundwater levels forecasting using machine learning models: A case study of the groundwater region 10 at Karst Belt, South Africa Type Journal Article
  Year 2023 Publication Systems and Soft Computing Abbreviated Journal  
  Volume 5 Issue Pages 200049  
  Keywords Artificial intelligence, Forecasting model, Groundwater levels, Machine learning, Neural networks, Rainfall, Regression, Temperature, Time series  
  Abstract The crucial role which groundwater resource plays in our environment and the overall well-being of all living things can not be underestimated. Nonetheless, mismanagement of resources, over-exploitation, inadequate supply of surface water and pollution have led to severe drought and an overall drop in groundwater resources’ levels over the past decades. To address this, a groundwater flow model and several mathematical data-driven models have been developed for forecasting groundwater levels. However, there is a problem of unavailability and scarcity of the on-site input data needed by the data-driven models to forecast the groundwater level. Furthermore, as a result of the dynamics and stochastic characteristics of groundwater, there is a need for an appropriate, accurate and reliable forecasting model to solve these challenges. Over the years, the broad application of Machine Learning (ML) and Artificial Intelligence (AI) models are gaining attraction as an alternative solution for forecasting groundwater levels. Against this background, this article provides an overview of forecasting methods for predicting groundwater levels. Also, this article uses ML models such as Regressions Models, Deep Auto-Regressive models, and Nonlinear Autoregressive Neural Networks with External Input (NARX) to forecast groundwater levels using the groundwater region 10 at Karst belt in South Africa as a case study. This was done using Python Mx. Version 1.9.1., and MATLAB R2022a machine learning toolboxes. Moreover, the Coefficient of Determination (R2);, Root Mean Square Error (RMSE), Mutual Information gain, Mean Absolute Percentage Error (MAPE), Mean Squared Error (MSE), Mean Absolute Error (MAE), and the Mean Absolute Scaled Error (MASE)) models were the forecasting statistical performance metrics used to assess the predictive performance of these models. The results obtained showed that NARX and Support Vector Machine (SVM) have higher performance metrics and accuracy compared to other models used in this study.  
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  ISSN 2772-9419 ISBN Medium  
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  Notes Approved no  
  Call Number THL @ christoph.kuells @ Aderemi2023200049 Serial 219  
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Author Rajfur, M.; Kłos, A.; Wacławek, M. url  openurl
  Title Sorption properties of algae Spirogyra sp. and their use for determination of heavy metal ions concentrations in surface water Type Journal Article
  Year 2010 Publication Bioelectrochemistry Abbreviated Journal  
  Volume 80 Issue 1 Pages 81-86  
  Keywords Biomonitoring, Heavy metal ions, Algae sp., Sorption kinetics, Langmuir isotherm  
  Abstract Kinetics of heavy-metal ions sorption by alga Spirogyra sp. was evaluated experimentally in the laboratory, using both the static and the dynamic approach. The metal ions – Mn2+, Cu2+, Zn2+ and Cd2+ – were sorbed from aqueous solutions of their salts. The static experiments showed that the sorption equilibria were attained in 30min, with 90-95% of metal ions sorbed in first 10min of each process. The sorption equilibria were approximated with the Langmuir isotherm model. The algae sorbed each heavy metal ions proportionally to the amount of this metal ions in solution. The experiments confirmed that after 30min of exposition to contaminated water, the concentration of heavy metal ions in the algae, which initially contained small amounts of these metal ions, increased proportionally to the concentration of metal ions in solution. The presented results can be used for elaboration of a method for classification of surface waters that complies with the legal regulations.  
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  Series Volume Series Issue Edition  
  ISSN 1567-5394 ISBN Medium  
  Area Expedition Conference  
  Notes A Selection of Papers presented at the 4th International Workshop on Surface Modification for Chemical and Biochemical Sensing (SMCBS 2009) Approved no  
  Call Number THL @ christoph.kuells @ Rajfur201081 Serial 283  
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Author Konapala, G.; Mishra, A.K.; Wada, Y.; Mann, M.E. url  doi
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  Title Climate change will affect global water availability through compounding changes in seasonal precipitation and evaporation Type Journal Article
  Year 2020 Publication Nature Communications Abbreviated Journal  
  Volume 11 Issue 1 Pages 3044  
  Keywords  
  Abstract Both seasonal and annual mean precipitation and evaporation influence patterns of water availability impacting society and ecosystems. Existing global climate studies rarely consider such patterns from non-parametric statistical standpoint. Here, we employ a non-parametric analysis framework to analyze seasonal hydroclimatic regimes by classifying global land regions into nine regimes using late 20th century precipitation means and seasonality. These regimes are used to assess implications for water availability due to concomitant changes in mean and seasonal precipitation and evaporation changes using CMIP5 model future climate projections. Out of 9 regimes, 4 show increased precipitation variation, while 5 show decreased evaporation variation coupled with increasing mean precipitation and evaporation. Increases in projected seasonal precipitation variation in already highly variable precipitation regimes gives rise to a pattern of “seasonally variable regimes becoming more variable”. Regimes with low seasonality in precipitation, instead, experience increased wet season precipitation.  
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  Language English Summary Language Original Title  
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  Series Volume Series Issue Edition  
  ISSN 2041-1723 ISBN Medium  
  Area Expedition Conference  
  Notes Approved no  
  Call Number THL @ christoph.kuells @ Konapala2020 Serial 284  
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Author Wolfe, P. url  openurl
  Title The Simplex Method For Quadratic Programming Type Journal Article
  Year 1959 Publication Econometrica Abbreviated Journal  
  Volume 27 Issue Pages 170  
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  Notes Approved no  
  Call Number THL @ christoph.kuells @ Wolfe1959 Serial 285  
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Author United Nations openurl 
  Title Stampriet Transboundary Aquifer System Assessment: governance of Groundwater resources in Transboundary Aquifers (GGRETA), phase 1: technical report Type Miscellaneous
  Year 1998 Publication Abbreviated Journal  
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  Notes Incl. bibl. Approved no  
  Call Number THL @ christoph.kuells @ Serial 286  
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Author Stone, A.E.C.; Edmunds, W.M. url  openurl
  Title Naturally-high nitrate in unsaturated zone sand dunes above the Stampriet Basin, Namibia Type Journal Article
  Year 2014 Publication Journal of Arid Environments Abbreviated Journal  
  Volume 105 Issue Pages 41-51  
  Keywords Kalahari, Namibia, Nitrate in the unsaturated zone, Stampriet Basin, Transboundary basin, Unsaturated zone recharge  
  Abstract Elevated groundwater nitrate levels are common in drylands, often in excess of WHO guidelines, with concern for human and animal health. In light of recent attempts to identify nitrate sources in the Kalahari this paper presents the first unsaturated zone (USZ) nitrate profiles and recharge rate estimates for the important transboundary Stampriet Basin, alongside the first rainfall chemistry records. Elevated subsurface nitrate reaches 100–250 and 250–525 mg/L NO3–N, with NO3–N/Cl of 4–12, indicating input above evapotranspiration. Chloride mass balance recharge rates range from 4 to 27 mm/y, indicating a vertical movement of these nitrate pulses toward the water table over multi-decadal timescales. These profiles are sampled from dune crests, away from high concentrations of animals and without termite mounds. Given low-density animal grazing is unlikely to contribute consistent spot-scale nitrate over decades, these profiles give an initial estimate of naturally-produced concentrations. This insight is important for the management of the Stampriet Basin and wider Kalahari groundwater. This study expands our knowledge about elevated nitrate in dryland USZs, demonstrating that it can occur as pulses, probably in response to transient vegetation cover and that it is not limited to long-residence time USZs with very limited downward moisture flux (recharge).  
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  ISSN 0140-1963 ISBN Medium  
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  Notes Approved no  
  Call Number THL @ christoph.kuells @ stone_naturally-high_2014 Serial 91  
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Author Rossetto, R.; Filippis, G.D.; Borsi, I.; Foglia, L.; Cannata, M.; Criollo, R.; Vázquez-Suñé, E. url  openurl
  Title Integrating free and open source tools and distributed modelling codes in GIS environment for data-based groundwater management Type Journal Article
  Year 2018 Publication Environmental Modelling & Software Abbreviated Journal  
  Volume 107 Issue Pages 210-230  
  Keywords Free and Open Source Software, FREEWAT, Groundwater management, ICT, MODFLOW, QGIS  
  Abstract Integrating advanced simulation techniques and data analysis tools in a freeware Geographic Information System (GIS) provides a valuable contribution to the management of conjunctive use of groundwater (the world’s largest freshwater resource) and surface-water. To this aim, we describe here the FREEWAT (FREE and open source software tools for WATer resource management) platform. FREEWAT is a free and open source, QGIS-integrated interface for planning and management of water resources, with specific attention to groundwater. The FREEWAT platform couples the power of GIS geo-processing and post-processing tools in spatial data analysis with that of process-based simulation models. The FREEWAT environment allows storage of large spatial datasets, data management and visualization, and running of several distributed modelling codes (mainly belonging to the MODFLOW family). It simulates hydrologic and transport processes, and provides a database framework and visualization capabilities for hydrochemical analysis. Examples of real case study applications are provided.  
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  ISSN 1364-8152 ISBN Medium  
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  Notes Approved no  
  Call Number THL @ christoph.kuells @ rossetto_integrating_2018 Serial 92  
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Author Nijsten, G.-J.; Christelis, G.; Villholth, K.G.; Braune, E.; Gaye, C.B. url  openurl
  Title Transboundary aquifers of Africa: Review of the current state of knowledge and progress towards sustainable development and management Type Journal Article
  Year 2018 Publication Journal of Hydrology: Regional Studies Abbreviated Journal  
  Volume 20 Issue Pages 21-34  
  Keywords Africa, Assessment, Governance, Indicators, Transboundary aquifers  
  Abstract Study region Transboundary aquifers (TBAs) of Africa. Study focus Review of work on TBAs in Africa, including an overview of assessments and management efforts that have taken place over the last half century. New hydrological insights Seventy-two TBAs have been mapped in Africa. They underlie 40% of the continent, where 33% of the population lives, often in arid or semi-arid regions. TBA inventories have progressed since 2000 and remain work in progress. Despite their importance only eleven TBAs have been subjected to more detailed studies. Cooperation has been formalised for seven TBAs. Most of these TBAs are in North Africa and the Sahel. The recent global Transboundary Waters Assessment Programme compiled information at the national level to describe TBAs in terms of key indicators related to the water resource, socio-economic, and legal and institutional conditions. Availability of data at national level is low, hampering regional assessment. Comparing indicators, from questionnaire surveys, with those from a global water-use model showed variable levels of agreement, calling for further research. Reports on agreements scoping TBA management, indicate that this may be dealt with within international river/lake agreements, but reported inconsistencies between TBA sharing countries also indicate that implementation is limited. Increasing awareness and support to joint TBA management is noticeable amongst international organisations. However, such cooperation requires long-term commitment to produce impacts at the local level.  
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  ISSN 2214-5818 ISBN Medium  
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  Notes Approved no  
  Call Number THL @ christoph.kuells @ nijsten_transboundary_2018 Serial 93  
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Author Rooyen, J.D. van; Watson, A.W.; Miller, J.A. url  openurl
  Title Using tritium and radiocarbon activities to constrain regional modern and fossil groundwater mixing in Southern Africa Type Journal Article
  Year 2022 Publication Journal of Hydrology Abbreviated Journal  
  Volume 614 Issue Pages 128570  
  Keywords Radiocarbon, Residence time, SADC, Tritium  
  Abstract This study combines historical records of 14C and 3H in the atmosphere and soil with renewal rate and groundwater lumped parameter models to predict the abundance of 14C and 3H in groundwater over time. 624 groundwater samples from numerous studies, over four decades (1978–2019), in South Africa, Namibia, Botswana and Mozambique were collated to compare with predicted groundwater activities of 14C and 3H within the South African Development Community (SADC) region. Spatial datasets of carbonate bearing lithology, C3/C4 vegetation, summer/winter rainfall and coastal proximity were used to apply corrections to 14C and 3H data. Corrected values of 14C and 3H were compared with the theoretical abundance of these tracers, derived from the lumped parameter models, to estimate the general mean residence times and presence of groundwater mixing between modern recharge and older groundwaters. This study found that corrected values produced varying mean residence times derived from 14C ages (∼500–28500 years) and a wide range of potentially mixed waters within each aquifer system (0–100 % of tested wells) across the study area. The largest proportions of mixed groundwater, as well as the youngest mean residence times, were found in alluvial and primary fractured rock aquifers (e.g., western coast of South Africa and southern Mozambique). The smallest proportions of mixed groundwater were predicted in deep confined clay-rich aquifers as well as layered coal bearing carbonate sequences (e.g., Orapa, Malwewe and Serowe, Botswana). Insights into the proportions of mixed groundwater and mean residence times can help assess hydrological resilience on a regional scale. Such information is pertinent in promoting socio-economic development and increased water/food security in the SADC region. By understanding the resilience of groundwater resources, robust and informed strategies for water equality and GDP growth in the SADC region can be envisioned and implemented.  
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  ISSN 0022-1694 ISBN Medium  
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  Notes Approved no  
  Call Number THL @ christoph.kuells @ rooyen_using_2022 Serial 94  
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Author Heaton, T.H.E.; Talma, A.S.; Vogel, J.C. url  openurl
  Title Origin and history of nitrate in confined groundwater in the western Kalahari Type Journal Article
  Year 1983 Publication Journal of Hydrology Abbreviated Journal  
  Volume 62 Issue 1 Pages 243-262  
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  Abstract Data are presented for nitrate, dinitrogen and argon concentrations and 15N14N ratios in groundwater, with radiocarbon ages up to 40,000 yr. for three confined sandstone aquifers in the western Kalahari of South West Africa/Namibia. The nitrate is probably generated within the soil of the recharge areas, and its production rate during the period 3000-40,000 B.P. has remained between 0.5 and 1.6 meq NO−3l−1 of recharge water, with ° 15N between + 4 and + 8‰. Variations in the amount of nitrate and of “excess air” in groundwater recharge are found, and can only reflect changes in the environmental conditions during recharge. They must therefore be caused by the climatic changes that have taken place during the past 25,000 yr.  
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  ISSN 0022-1694 ISBN Medium  
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  Notes Approved no  
  Call Number THL @ christoph.kuells @ heaton_origin_1983 Serial 95  
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