Zeng, S., Shen, Y., Sun, B., Tan, K., Zhang, S., & Ye, W. (2022). Fractal kinetic characteristics of uranium leaching from low permeability uranium-bearing sandstone. Nuclear Engineering and Technology, 54(4), 1175–1184.
Abstract: The pore structure of uranium-bearing sandstone is one of the critical factors that affect the uranium leaching performance. In this article, uranium-bearing sandstone from the Yili Basin, Xinjiang, China, was taken as the research object. The fractal characteristics of the pore structure of the uranium-bearing sandstone were studied using mercury intrusion experiments and fractal theory, and the fractal dimension of the uranium-bearing sandstone was calculated. In addition, the effect of the fractal characteristics of the pore structure of the uranium-bearing sandstone on the uranium leaching kinetics was studied. Then, the kinetics was analyzed using a shrinking nuclear model, and it was determined that the rate of uranium leaching is mainly controlled by the diffusion reaction, and the dissolution rate constant (K) is linearly related to the pore specific surface fractal dimension (DS) and the pore volume fractal dimension (DV). Eventually, fractal kinetic models for predicting the in-situ leaching kinetics were established using the unreacted shrinking core model, and the linear relationship between the fractal dimension of the sample’s pore structure and the dissolution rate during the leaching was fitted.
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Klimkova, S., Cernik, M., Lacinova, L., Filip, J., Jancik, D., & Zboril, R. (2011). Zero-valent iron nanoparticles in treatment of acid mine water from in situ uranium leaching. Chemosphere, 82(8), 1178–1184.
Abstract: Acid mine water from in situ chemical leaching of uranium (Straz pod Ralskem, Czech Republic) was treated in laboratory scale experiments by zero-valent iron nanoparticles (nZVI). For the first time, nZVI were applied for the treatment of the real acid water system containing the miscellaneous mixture of pollutants, where the various removal mechanisms occur simultaneously. Toxicity of the treated saline acid water is caused by major contaminants represented by aluminum and sulphates in a high concentration, as well as by microcontaminants like As, Be, Cd, Cr, Cu, Ni, U, V, and Zn. Laboratory batch experiments proved a significant decrease in concentrations of all the monitored pollutants due to an increase in pH and a decrease in oxidation–reduction potential related to an application of nZVI. The assumed mechanisms of contaminants removal include precipitation of cations in a lower oxidation state, precipitation caused by a simple pH increase and co-precipitation with the formed iron oxyhydroxides. The possibility to control the reaction kinetics through the nature of the surface stabilizing shell (polymer vs. FeO nanolayer) is discussed as an important practical aspect.
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Robati, A., & Barani, G. A. (2009). Modeling of water surface profile in subterranean channel by differential quadrature method (DQM). Applied Mathematical Modelling, 33(3), 1295–1305.
Abstract: This study, investigates the hydraulic of flow in a subterranean channel headspring. The continuity and momentum equations of flow in porous media considering real conditions were used and the basic equation of flow in a subterranean channel was resulted. This equation is very similar to the spatially varied flow with increasing discharge. An equation, defining the hydraulic parameters of a subterranean channel section was adopted. Then differential quadrature method (DQM), was applied to the equation of flow in subterranean channel, consequently the water surface profile was resulted. To illustrate the rightness of model, the hydraulic parameters of flow in the Gavgard branch of the Joopar Goharriz Qanat were measured and the water surface profile was determined. This water surface profile was compared to the water surface profile computed by the model, which are in good agreement.
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Liu, Z., Tan, K., Li, C., Li, Y., Zhang, C., Song, J., et al. (2023). Geochemical and S isotopic studies of pollutant evolution in groundwater after acid in situ leaching in a uranium mine area in Xinjiang. Nuclear Engineering and Technology, 55(4), 1476–1484.
Abstract: Laboratory experiments and point monitoring of reservoir sediments have proven that stable sulfate reduction (SSR) can lower the concentrations of toxic metals and sulfate in acidic groundwater for a long time. Here, we hypothesize that SSR occurred during in situ leaching after uranium mining, which can impact the fate of acid groundwater in an entire region. To test this, we applied a sulfur isotope fractionation method to analyze the mechanism for natural attenuation of contaminated groundwater produced by acid in situ leaching of uranium (Xinjiang, China). The results showed that δ34S increased over time after the cessation of uranium mining, and natural attenuation caused considerable, area-scale immobilization of sulfur corresponding to retention levels of 5.3%–48.3% while simultaneously decreasing the concentration of uranium. Isotopic evidence for SSR in the area, together with evidence for changes of pollutant concentrations, suggest that area-scale SSR is most likely also important at other acid mining sites for uranium, where retention of acid groundwater may be strengthened through natural attenuation. To recapitulate, the sulfur isotope fractionation method constitutes a relatively accurate tool for quantification of spatiotemporal trends for groundwater during migration and transformation resulting from acid in situ leaching of uranium in northern China.
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Baram, S., Ronen, Z., Kurtzman, D., Külls, C., & Dahan, O. (2013). Desiccation-crack-induced salinization in deep clay sediment. Hydrology and Earth System Sciences, 17(4), 1533.
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