Records |
Author |
Strandmann, P.A.E.P. von; Reynolds, B.C.; Porcelli, D.; James, R.H.; Calsteren, P. van; Baskaran, M.; Burton, K.W. |
Title |
Assessing continental weathering rates and actinide transport in the Great Artesian Basin |
Type |
Journal Article |
Year |
2006 |
Publication |
Geochimica et Cosmochimica Acta |
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Volume |
70 |
Issue |
18, Supplement |
Pages |
497 |
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0016-7037 |
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THL @ christoph.kuells @ strandmann_assessing_2006 |
Serial |
116 |
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Author |
Zeng, S.; Shen, Y.; Sun, B.; Zhang, N.; Zhang, S.; Feng, S. |
Title |
Pore structure evolution characteristics of sandstone uranium ore during acid leaching |
Type |
Journal Article |
Year |
2021 |
Publication |
Nuclear Engineering and Technology |
Abbreviated Journal |
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Volume |
53 |
Issue |
12 |
Pages |
4033-4041 |
Keywords |
Acid method, In situ leaching, Nuclear magnetic resonance, Pore characteristic, Sandstone uranium ore |
Abstract |
To better understand the permeability of uranium sandstone, improve the leaching rate of uranium, and explore the change law of pore structure characteristics and blocking mechanism during leaching, we systematically analyzed the microstructure of acid-leaching uranium sandstone. We investigated the variable rules of pore structure characteristics based on nuclear magnetic resonance (NMR). The results showed the following: (1) The uranium concentration change followed the exponential law during uranium deposits acid leaching. After 24 h, the uranium leaching rate reached 50%. The uranium leaching slowed gradually over the next 4 days. (2) Combined with the regularity of porosity variation, Stages I and II included chemical plugging controlled by surface reaction. Stage I was the major completion phase of uranium displacement with saturation precipitation of calcium sulfate. Stage II mainly precipitated iron (III) oxide-hydroxide and aluminum hydroxide. Stage III involved physical clogging controlled by diffusion. (3) In the three stages of leaching, the permeability of the leaching solution changed with the pore structure, which first decreased, then increased, and then decreased. |
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1738-5733 |
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Call Number |
THL @ christoph.kuells @ zeng_pore_2021 |
Serial |
199 |
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Author |
Kirchner, J.W. |
Title |
Mixing Models With Multiple, Overlapping, or Incomplete End-Members, Quantified Using Time Series of a Single Tracer |
Type |
Journal Article |
Year |
2023 |
Publication |
Geophysical Research Letters |
Abbreviated Journal |
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Volume |
50 |
Issue |
12 |
Pages |
2023 |
Keywords |
end-member mixing, tracers, stable isotopes, mixing models, EMMA, EEMMA |
Abstract |
Abstract Mixing models are used throughout earth and environmental science to quantify the relative contributions of sources to mixtures, based on chemical or isotopic tracers. Often, however, some end-members are missing or their tracer distributions overlap, precluding the use of conventional mixing models. Here I show how these constraints can be overcome by exploiting the information contained in tracer time-series fluctuations. This approach, ensemble end-member mixing analysis (EEMMA), can potentially quantify many sources using a single tracer, even if their mean concentrations are indistinguishable. EEMMA can also quantify source contributions when some sources are unknown, and even infer the tracer time series of a missing source. Benchmark tests with synthetic data verify the reliability of this approach, thus expanding the range of mixing models that can be quantified using tracer time series. An R script is provided for the necessary calculations, including error propagation. |
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Publisher |
AGU |
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English |
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English |
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e2023GL104147 2023GL104147 |
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THL @ christoph.kuells @ https://doi.org/10.1029/2023GL104147 |
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291 |
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Author |
Schwiede, M.; Duijnisveld, W.H.M.; Böttcher, J. |
Title |
Investigation of processes leading to nitrate enrichment in soils in the Kalahari Region, Botswana |
Type |
Journal Article |
Year |
2005 |
Publication |
Physics and Chemistry of the Earth, Parts A/B/C |
Abbreviated Journal |
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Volume |
30 |
Issue |
11 |
Pages |
712-716 |
Keywords |
Nitrate, Arenosol soils, Semi-arid, Kalahari, Cattle, Chloride, Travel time |
Abstract |
In Southern Africa elevated nitrate concentrations are observed in mostly uninhabited semi-arid areas. In the Kalahari of Botswana groundwater locally exhibits concentrations up to 600mg/l. It is assumed, that nitrate found in the groundwater originates mainly from nitrogen input and transformations in the soils. Our investigations in the Kalahari between Serowe and Orapa show that cattle raising is an important source for enhanced nitrate concentrations in the soils (Arenosols). But also in termite mounds very high nitrate stocks were found, and under natural vegetation (acacia trees and shrubs) nitrate concentrations were mostly unexpectedly high. This nitrate enrichment in the soils poses a serious threat to the groundwater quality. However, calculated soil water age distributions in the unsaturated zone clearly show that today’s nitrate pollution of the groundwater below the investigation area could originate from natural sources, but cannot be caused by the current land use for cattle raising. |
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ISSN |
1474-7065 |
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Integrated Water Resources Management (IWRM) and the Millennium Development Goals: Managing Water for Peace and Prosperity |
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no |
Call Number |
THL @ christoph.kuells @ Schwiede2005712 |
Serial |
276 |
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Author |
Zhao, Y.; Li, X.; Lei, L.; Chen, L.; Luo, Z. |
Title |
Permeability evolution mechanism and the optimum permeability determination of uranium leaching from low-permeability sandstone treated with low-frequency vibration |
Type |
Journal Article |
Year |
2023 |
Publication |
Journal of Rock Mechanics and Geotechnical Engineering |
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Volume |
15 |
Issue |
10 |
Pages |
2597-2610 |
Keywords |
Chemical reactive rate, Low-frequency vibration, Low-permeability sandstone, Optimum permeability, Permeability evolution mechanism, Uranium migration |
Abstract |
Low-frequency vibrations can effectively improve natural sandstone permeability, and higher vibration frequency is associated with larger permeability. However, the optimum permeability and permeability evolution mechanism for uranium leaching and the relationship between permeability and the change of chemical reactive rate affecting uranium leaching have not been determined. To solve the above problems, in this study, identical homogeneous sandstone samples were selected to simulate low-permeability sandstone; a permeability evolution model considering the combined action of vibration stress, pore water pressure, water flow impact force, and chemical erosion was established; and vibration leaching experiments were performed to test the model accuracy. Both the permeability and chemical reactions were found to simultaneously restrict U6+ leaching, and the vibration treatment increased the permeability, causing the U6+ leaching reaction to no longer be diffusion-constrained but to be primarily controlled by the reaction rate. Changes of the model calculation parameters were further analyzed to determine the permeability evolution mechanism under the influence of vibration and chemical erosion, to prove the correctness of the mechanism according to the experimental results, and to develop a new method for determining the optimum permeability in uranium leaching. The uranium leaching was found to primarily follow a process consisting of (1) a permeability control stage, (2) achieving the optimum permeability, (3) a chemical reactive rate control stage, and (4) a channel flow stage. The resolution of these problems is of great significance for facilitating the application and promotion of low-frequency vibration in the CO2 + O2 leaching process. |
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1674-7755 |
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THL @ christoph.kuells @ zhao_permeability_2023 |
Serial |
198 |
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Author |
Severi, A.; Masoudian, M.; Kordi, E.; Roettcher, K. |
Title |
Discharge coefficient of combined-free over-under flow on a cylindrical weir-gate |
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Journal Article |
Year |
2015 |
Publication |
ISH Journal of Hydraulic Engineering |
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Volume |
21 |
Issue |
1 |
Pages |
42-52 |
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Taylor & Francis |
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THL @ christoph.kuells @ doi:10.1080/09715010.2014.939503 |
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88 |
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Author |
Heaton, T.H.E.; Talma, A.S.; Vogel, J.C. |
Title |
Origin and history of nitrate in confined groundwater in the western Kalahari |
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Journal Article |
Year |
1983 |
Publication |
Journal of Hydrology |
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62 |
Issue |
1 |
Pages |
243-262 |
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Data are presented for nitrate, dinitrogen and argon concentrations and 15N14N ratios in groundwater, with radiocarbon ages up to 40,000 yr. for three confined sandstone aquifers in the western Kalahari of South West Africa/Namibia. The nitrate is probably generated within the soil of the recharge areas, and its production rate during the period 3000-40,000 B.P. has remained between 0.5 and 1.6 meq NO−3l−1 of recharge water, with ° 15N between + 4 and + 8‰. Variations in the amount of nitrate and of “excess air” in groundwater recharge are found, and can only reflect changes in the environmental conditions during recharge. They must therefore be caused by the climatic changes that have taken place during the past 25,000 yr. |
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0022-1694 |
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THL @ christoph.kuells @ heaton_origin_1983 |
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95 |
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Author |
Gasse, F. |
Title |
Hydrological changes in the African tropics since the Last Glacial Maximum |
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Journal Article |
Year |
2000 |
Publication |
Quaternary Science Reviews |
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19 |
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1 |
Pages |
189-211 |
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Paleohydrological data from the African tropics and subtropics, including lake, groundwater and speleothem records, are reviewed to show how environments and climates from both hemispheres are inter-related. Although orbitally induced changes in the monsoon strength account for a large part of long-term climatic changes in tropical Africa, the Late Pleistocene–Holocene hydrological fluctuations rather appear to have been a series of abrupt events that reflect complex interactions between orbital forcing, atmosphere, ocean and land surface conditions. During the Last Glacial Maximum (23–18ka BP), most records indicate that generally dry conditions have prevailed in both hemispheres, associated with lower tropical land- and sea-surface temperatures. This agrees with simulations using coupled ocean–atmosphere models, which predict cooling and reduced summer precipitation in tropical Africa; the global hydrological cycle was weaker than today when the extent of large polar ice-sheets and sea-ice was a prominent forcing factor of the Earth’s climate. Glacial-interglacial climatic changes started early: a first wetting/warming phase at ca. 17–16ka BP took place during a period of rapid temperature increase in Antarctica. Next, two drastic arid-humid transitions in equatorial and northern Africa occurred around 15–14.5ka BP and 11.5–11ka BP. Both are thought to match the major Greenland warming events, in concert with the switching of the oceanic thermohaline circulation to modern mode. However, part of the climatic signal after 15 ka BP also seems related to the Antarctica climate. During the Holocene, Africa has also experienced rapid hydrological fluctuations of dramatic magnitude compared to the climatic changes at high latitudes. In particular, major dry spells occurred around 8.4–8ka and 4.2–4ka BP in the northern monsoon domain. Comparison with other parts of the world indicates that these events have a worldwide distribution but different regional expressions. In the absence of large polar ice sheets, changes in the continental hydrological cycles in the tropics may have a significant impact on the global climate system. Climate information gathered here allows to identify geographical and methodological gaps, and raise some scientific questions that remain to be solved to better understand how the tropics respond to changes in major climate-forcing factors, and how they influence climate globally. |
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0277-3791 |
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THL @ christoph.kuells @ gasse_hydrological_2000 |
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96 |
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Author |
Brook, G.A.; Marais, E.; Srivastava, P.; Jordan, T. |
Title |
Timing of lake-level changes in Etosha Pan, Namibia, since the middle Holocene from OSL ages of relict shorelines in the Okondeka region |
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Journal Article |
Year |
2007 |
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Quaternary International |
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175 |
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1 |
Pages |
29-40 |
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Abstract |
In 2003 examination of aerial photographs revealed a series of previously unknown relict shorelines on the arcuate ridge, possibly a clay lunette dune, that marks the western boundary of Etosha Pan in Namibia. The shorelines are 120–600m wide and the most prominent extend for tens of km around the lunette dune. The shorelines were examined on the ground in 2004 and an attempt was made to date the three lowest levels at ca. 5, 2.5 and 1m above the present pan surface. The OSL ages obtained indicate higher and more prolonged lake conditions than today at ca. 6.4, 4.0 and 2.1ka with the youngest shoreline sediments resting on an ancient pan surface dating to ca. 13ka. The evidence indicates dry conditions in the pan at ca. 13ka, wetter conditions and higher lake levels in the middle Holocene followed by a decline in lake levels to the present. Periods of inundation were of sufficient duration to produce shorelines at the southwestern end of the pan due to the prevailing northeasterly winds that would have maximized wave action along this section of the pan margin. The Etosha findings, together with other regional paleoclimate data, suggest four periods of increased wetness in SW Africa during the Holocene at 7–5, 4.5–3.5, 2.5–1.7 and ca. 1.0ka. There is widespread evidence for the oldest of these periods suggesting that it was a prominent and widespread interval of wetness. Prior to ca. 8.0ka the climate may have been drier than today. |
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1040-6182 |
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THL @ christoph.kuells @ brook_timing_2007 |
Serial |
97 |
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Author |
Brook, G.A.; Railsback, L.B.; Marais, E. |
Title |
Reassessment of carbonate ages by dating both carbonate and organic material from an Etosha Pan (Namibia) stromatolite: Evidence of humid phases during the last 20ka |
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Journal Article |
Year |
2011 |
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Quaternary International |
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229 |
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1 |
Pages |
24-37 |
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Previous research on lacustrine stromatolites from Etosha Pan in Namibia obtained ages on carbonate close to or beyond the limits of radiocarbon dating. These ages suggested that the basin was likely not subject to extensive flooding during the last ca. 40ka. This study shows that AMS radiocarbon ages for the carbonate of a stromatolite from Poacher’s Point are 15–21ka older than ages for organic material in the stromatolite structure. Calibrated ages range from 30 to 40ka for carbonate and 3–19ka for the organic residue. The new ages, together with petrographic and isotopic data for the stromatolite, have provided important new information on past flooding of Etosha Pan including evidence of prolonged lacustrine conditions during the Holocene Climatic Optimum. |
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1040-6182 |
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THL @ christoph.kuells @ brook_reassessment_2011 |
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110 |
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