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Author Marteleto, T. de P.; Abreu, A.E.S. de; Barbosa, M.B.; Yoshinaga-Pereira, S.; Bertolo, R.A.; Enzweiler, J. url  openurl
  Title Groundwater apparent ages and isotopic composition in Crystalline, Diabase and Tubarão aquifers contact area in Campinas, Southeastern Brazil Type Journal Article
  Year 2024 Publication Journal of South American Earth Sciences Abbreviated Journal  
  Volume 135 Issue Pages 104783  
  Keywords (up) Fractured aquifer, Groundwater mixing, Isotopes, Water management  
  Abstract This study refines the hydrogeological conceptual model of an area with three interconnected aquifers, namely the Crystalline Aquifer System (CAS – igneous and metamorphic rocks), which is in contact with the Tubarão Aquifer System (TAS – sedimentary rocks) and the Diabase Aquifer System (DAS – diabase rocks). The detailed investigation involved geophysical logging and hydraulic and hydrodynamic characterization with straddle packers in a local tubular well, in which groundwater presents high uranium concentrations. Hydrogeochemical and isotope (δ2H, δ18O, 3H, δ13C, 14C) analysis in this well and in other three neighboring wells, with lower U concentrations, showed that ancient and modern waters (3H from <0.8 to 1.12 TU, 14C from 69.43 to 78.72 pMC) mix within the aquifer. During groundwater pumping, vertical fractures in the diabase aquifer possibly induce water mixing and recharge of the deeper levels of the aquifers from shallow layers. The high [U] are related to ancient waters from a confined aquifer hosted in CAS that reaches the wells through hydraulically active fractures located deeper than 159 m depth. Groundwater apparent ages do not increase systematically with depth, revealing a complex circulation model for CAS. The results obtained from the other wells, which are all located on drainage lineaments, reveal that one extracts modern water from DAS and TAS, another one extracts modern and ancient water from DAS and CAS, and the third extracts only ancient water from CAS, confirming the complexity of the local hydrogeology. Regarding regional groundwater management, the study revealed the need to characterize the sources of groundwater in each well, in order to protect modern waters from anthropogenic contamination and to protect ancient groundwater from overexploitation, as CAS hosts groundwaters recharged thousands of years ago or more.  
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  ISSN 0895-9811 ISBN Medium  
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  Notes Approved no  
  Call Number THL @ christoph.kuells @ Depaulamarteleto2024104783 Serial 221  
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Author Rossetto, R.; Filippis, G.D.; Borsi, I.; Foglia, L.; Cannata, M.; Criollo, R.; Vázquez-Suñé, E. url  openurl
  Title Integrating free and open source tools and distributed modelling codes in GIS environment for data-based groundwater management Type Journal Article
  Year 2018 Publication Environmental Modelling & Software Abbreviated Journal  
  Volume 107 Issue Pages 210-230  
  Keywords (up) Free and Open Source Software, FREEWAT, Groundwater management, ICT, MODFLOW, QGIS  
  Abstract Integrating advanced simulation techniques and data analysis tools in a freeware Geographic Information System (GIS) provides a valuable contribution to the management of conjunctive use of groundwater (the world’s largest freshwater resource) and surface-water. To this aim, we describe here the FREEWAT (FREE and open source software tools for WATer resource management) platform. FREEWAT is a free and open source, QGIS-integrated interface for planning and management of water resources, with specific attention to groundwater. The FREEWAT platform couples the power of GIS geo-processing and post-processing tools in spatial data analysis with that of process-based simulation models. The FREEWAT environment allows storage of large spatial datasets, data management and visualization, and running of several distributed modelling codes (mainly belonging to the MODFLOW family). It simulates hydrologic and transport processes, and provides a database framework and visualization capabilities for hydrochemical analysis. Examples of real case study applications are provided.  
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  Series Volume Series Issue Edition  
  ISSN 1364-8152 ISBN Medium  
  Area Expedition Conference  
  Notes Approved no  
  Call Number THL @ christoph.kuells @ rossetto_integrating_2018 Serial 92  
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Author Love, A.J.; Shand, P.; Karlstrom, K.; Crossey, L.; Rousseau-Gueutin, P.; Priestley, S.; Wholing, D.; Fulton, S.; Keppel, M. url  openurl
  Title Geochemistry and Travertine Dating Provide New Insights into the Hydrogeology of the Great Artesian Basin, South Australia Type Journal Article
  Year 2013 Publication Procedia Earth and Planetary Science Abbreviated Journal  
  Volume 7 Issue Pages 521-524  
  Keywords (up) GAB springs, Great Artesian Basin, Helium isotope data, Uranium series dating  
  Abstract While of great national and societal significance, and importance in its own right, the Great Artesian Basin of Australia is an iconic example of a continental scale artesian groundwater system. New geochemical, hydrological, and neo-tectonic data suggests that existing models that involve recharge in eastern Australia, relatively simple flowpaths and discharge in springs in the western margin require modification. New geochemical data indicate a small volume flux of deeply derived (endogenic) fluids mixing into the aquifer system at a continental scale. Neo- tectonic data indicates active tectonism today that provides a fluid pathway through faults for the deeply sourced endogenic fluids to discharge in GAB travertine depositing springs.  
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  ISSN 1878-5220 ISBN Medium  
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  Notes Approved no  
  Call Number THL @ christoph.kuells @ love_geochemistry_2013 Serial 122  
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Author Stavi, I.; Eldad, S.; Xu, C.; Xu, Z.; Gusarov, Y.; Haiman, M.; Argaman, E. url  openurl
  Title Ancient agricultural terrace walls control floods and regulate the distribution of Asphodelus ramosus geophytes in the Israeli arid Negev Type Journal Article
  Year 2024 Publication Catena Abbreviated Journal  
  Volume 234 Issue Pages 107588  
  Keywords (up) Geo-archaeology, Hydrological connectivity, Hydrological modelling, Runoff harvesting, Soil and water conservation, Watershed management  
  Abstract Ancient stone terrace walls aimed at harvesting water runoff and facilitating crop production are widespread across the drylands of the Middle East and beyond. In addition to retaining the scarce water resource, the terrace walls also conserve soil and thicken its profile along ephemeral stream channels (wadis) by decreasing fluvial connectivity and mitigating erosional processes. In this study, we created hydrological models for three wadis with ancient stone terrace walls in the arid northern Negev of Israel, where the predominant geophyte species is Asphodelus ramosus L. A two-dimensional (2D) rain-on-grid (RoG) approach with a resolution of 2 m was used to simulate the rain events with return periods of 10, 20, 50, and 99 % (10-y, 5-y, 2-y, and yearly, respectively) based on the Intensity-Duration-Frequency rain curves for the region. To evaluate the effect of stone terrace walls on fluvial hydrology and geomorphology, the ground level was artificially elevated by 20 cm at the wall locations in a digital terrain model (DTM), using the built-in HEC-RAS 2D terrain modification tool. Our results showed that the terraced wadis have a high capacity to mitigate runoff loss, but a lesser capacity to delay the peak flow. Yet, for all rainstorm return periods, peak flow mitigation was positively related to the number of terrace walls along the stream channel. Field surveys in two of the studied wadis demonstrated that the A. ramosus clones were found in proximity to the stone terrace walls, presumably due to the greater soil–water content there. The results thus suggest that the terrace walls provide improved habitat conditions for these geophytes, supporting their growth and regulating their distribution along the wadi beds.  
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  ISSN 0341-8162 ISBN Medium  
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  Notes Approved no  
  Call Number THL @ christoph.kuells @ Stavi2024107588 Serial 229  
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Author Su, X.; Liu, Z.; Yao, Y.; Du, Z. url  openurl
  Title Petrology, mineralogy, and ore leaching of sandstone-hosted uranium deposits in the Ordos Basin, North China Type Journal Article
  Year 2020 Publication Ore Geology Reviews Abbreviated Journal  
  Volume 127 Issue Pages 103768  
  Keywords (up) Geochemical composition, leach mining, Mineralogy, Ordos Basin, Sandstone-hosted uranium deposit  
  Abstract The Nalinggou–Daying uranium metallogenic belt is situated at the northern Ordos Basin, China. Petrographical, mineralogical and geochemical techniques were used to study the ore-bearing sandstones and host rocks in the Nalinggou–Daying uranium metallogenic belt. The present study shows that uranium minerals, i.e., coffinite, pitchblende, and brannerite, are mostly disseminated around pyrite and detrital particles. The ore-bearing sandstones are enriched in organic matter, with which this reductive environment influenced uranium leaching. The carbonate concentration of the uranium ores is markedly higher than that of the host rocks, and intense carbonatization occurs in the ore-bearing sandstones. In this case, the usage of the classical in-situ leach uranium mining technique by injecting H2SO4 + H2O2 solution produces calcium sulfate precipitate, which can lead to blocking of the ore-bearing strata. For this reason, laboratory and field uranium mining tests were conducted using CO2 + O2 in-situ leaching technology and were demonstrated to be successful, illustrating that this approach is technically feasible. Inhibiting ore bed blockage and increasing the amount of injected O2 are important for uranium leaching in this setting.  
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  Series Volume Series Issue Edition  
  ISSN 0169-1368 ISBN Medium  
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  Notes Approved no  
  Call Number THL @ christoph.kuells @ su_petrology_2020 Serial 120  
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Author Gómez, P.; Garralón, A.; Buil, B.; Turrero, M.J.; Sánchez, L.; Cruz, B. de la url  openurl
  Title Modeling of geochemical processes related to uranium mobilization in the groundwater of a uranium mine Type Journal Article
  Year 2006 Publication Science of The Total Environment Abbreviated Journal  
  Volume 366 Issue 1 Pages 295-309  
  Keywords (up) Geochemical modeling, Granite, Groundwater, Uranium mine, Uranium retention  
  Abstract This paper describes the processes leading to uranium distribution in the groundwater of five boreholes near a restored uranium mine (dug in granite), and the environmental impact of restoration work in the discharge area. The groundwater uranium content varied from \textless1 μg/L in reduced water far from the area of influence of the uranium ore-containing dyke, to 104 μg/L in a borehole hydraulically connected to the mine. These values, however, fail to reflect a chemical equilibrium between the water and the pure mineral phases. A model for the mobilization of uranium in this groundwater is therefore proposed. This involves the percolation of oxidized waters through the fractured granite, leading to the oxidation of pyrite and arsenopyrite and the precipitation of iron oxyhydroxides. This in turn leads to the dissolution of the primary pitchblende and, subsequently, the release of U(VI) species to the groundwater. These U(VI) species are retained by iron hydroxides. Secondary uranium species are eventually formed as reducing conditions are re-established due to water–rock interactions.  
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  ISSN 0048-9697 ISBN Medium  
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  Notes Approved no  
  Call Number THL @ christoph.kuells @ gomez_modeling_2006 Serial 162  
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Author Post, V.E.A.; Vassolo, S.I.; Tiberghien, C.; Baranyikwa, D.; Miburo, D. url  openurl
  Title Weathering and evaporation controls on dissolved uranium concentrations in groundwater – A case study from northern Burundi Type Journal Article
  Year 2017 Publication Science of The Total Environment Abbreviated Journal  
  Volume 607-608 Issue Pages 281-293  
  Keywords (up) Geochemical modelling, Hydrochemistry, Lake Tshohoha South, Public health, Radionuclides, Water supply  
  Abstract The potential use of groundwater for potable water supply can be severely compromised by natural contaminants such as uranium. The environmental mobility of uranium depends on a suite of factors including aquifer lithology, redox conditions, complexing agents, and hydrological processes. Uranium concentrations of up to 734μg/L are found in groundwater in northern Burundi, and the objective of the present study was to identify the causes for these elevated concentrations. Based on a comprehensive data set of groundwater chemistry, geology, and hydrological measurements, it was found that the highest dissolved uranium concentrations in groundwater occur near the shores of Lake Tshohoha South and other smaller lakes nearby. A model is proposed in which weathering and evapotranspiration during groundwater recharge, flow and discharge exert the dominant controls on the groundwater chemical composition. Results of PHREEQC simulations quantitatively confirm this conceptual model and show that uranium mobilization followed by evapo-concentration is the most likely explanation for the high dissolved uranium concentrations observed. The uranium source is the granitic sand, which was found to have a mean elemental uranium content of 14ppm, but the exact mobilization process could not be established. Uranium concentrations may further be controlled by adsorption, especially where calcium-uranyl‑carbonate complexes are present. Water and uranium mass balance calculations for Lake Tshohoha South are consistent with the inferred fluxes and show that high‑uranium groundwater represents only a minor fraction of the overall water input to the lake. These findings highlight that the evaporation effects that cause radionuclide concentrations to rise to harmful levels in groundwater discharge areas are not only confined to arid regions, and that this should be considered when selecting suitable locations for water supply wells.  
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  ISSN 0048-9697 ISBN Medium  
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  Notes Approved no  
  Call Number THL @ christoph.kuells @ post_weathering_2017 Serial 132  
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Author Christofi, C.; Bruggeman, A.; Külls, C.; Constantinou, C. url  doi
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  Title Hydrochemical evolution of groundwater in gabbro of the Troodos Fractured Aquifer. A comprehensive approach Type Journal Article
  Year 2020 Publication Applied Geochemistry Abbreviated Journal  
  Volume 114 Issue Pages 104524  
  Keywords (up) geochemistry  
  Abstract  
  Address  
  Corporate Author Thesis  
  Publisher Pergamon Place of Publication Editor  
  Language English Summary Language Original Title  
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  Notes Approved no  
  Call Number THL @ christoph.kuells @ Christofi2020hydrochemical Serial 13  
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Author Lawrinenko, M.; Kurwadkar, S.; Wilkin, R.T. url  openurl
  Title Long-term performance evaluation of zero-valent iron amended permeable reactive barriers for groundwater remediation – A mechanistic approach Type Journal Article
  Year 2023 Publication Geoscience Frontiers Abbreviated Journal  
  Volume 14 Issue 2 Pages 101494  
  Keywords (up) Geochemistry, Iron, Permeable reactive barrier, Plating reactions, Reduction potential, Surface passivation  
  Abstract Permeable reactive barriers (PRBs) are used for groundwater remediation at contaminated sites worldwide. This technology has been efficient at appropriate sites for treating organic and inorganic contaminants using zero-valent iron (ZVI) as a reductant and as a reactive material. Continued development of the technology over the years suggests that a robust understanding of PRB performance and the mechanisms involved is still lacking. Conflicting information in the scientific literature downplays the critical role of ZVI corrosion in the remediation of various organic and inorganic pollutants. Additionally, there is a lack of information on how different mechanisms act in tandem to affect ZVI-groundwater systems through time. In this review paper, we describe the underlying mechanisms of PRB performance and remove isolated misconceptions. We discuss the primary mechanisms of ZVI transformation and aging in PRBs and the role of iron corrosion products. We review numerous sites to reinforce our understanding of the interactions between groundwater contaminants and ZVI and the authigenic minerals that form within PRBs. Our findings show that ZVI corrosion products and mineral precipitates play critical roles in the long-term performance of PRBs by influencing the reactivity of ZVI. Pore occlusion by mineral precipitates occurs at the influent side of PRBs and is enhanced by dissolved oxygen and groundwater rich in dissolved solids and high alkalinity, which negatively impacts hydraulic conductivity, allowing contaminants to potentially bypass the treatment zone. Further development of site characterization tools and models is needed to support effective PRB designs for groundwater remediation.  
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  ISSN 1674-9871 ISBN Medium  
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  Notes Approved no  
  Call Number THL @ christoph.kuells @ lawrinenko_long-term_2023 Serial 143  
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Author Heidari, B.; Prideaux, V.; Jack, K.; Jaber, F.H. url  openurl
  Title A planning framework to mitigate localized urban stormwater inlet flooding using distributed Green Stormwater Infrastructure at an urban scale: Case study of Dallas, Texas Type Journal Article
  Year 2023 Publication Journal of Hydrology Abbreviated Journal  
  Volume 621 Issue Pages 129538  
  Keywords (up) Green stormwater infrastructure, Localized inlet pluvial flooding, Opportunity subwatersheds, Stormwater investment prioritization, Resilient urban watershed planning  
  Abstract Mitigation of localized pluvial flooding is one of the major resiliency goals in urban environments, and Green Stormwater Infrastructure (GSI) has the potential to deliver such an outcome. However, there is a lack of systematic approaches to prioritize investment in different candidate areas. This study provides a framework to identify vulnerable stormwater drainage inlets and their contributing areas, prioritize them, identify dominant factors in their selection, assess the potential of GSI in mitigating their overflows, and compare the impact and its cost to gray infrastructure upgrade alternatives. Using SWMM 5.1.013, decision trees, and a volumetric-based assessment of GSI overflow capture, we applied the framework to the City of Dallas, Texas, for three design storms with three GSI practices— bioretention cells, raingardens, and rainwater harvesting tanks. Results showed that there was a significant increase in the number of overflowing stormwater drainage inlets, referred to as hotspots, and their contributing subwatersheds, referred to as opportunity areas, with more intense storms especially in problematic watersheds. Also, prioritization results provided a series of maps to rank the opportunity areas based on overflow severity, recurrence of the overflows, and GSI availability. Moreover, classification results showed that inlet features, especially the inlet depth, were the dominant factors in the identification of the non-problematic inlets. Finally, the GSI impact assessment showed substantial overflow mitigation even at the “very high” severity levels when GSI is comprehensively deployed across opportunity areas. Despite gray infrastructure upgrades yielding higher reduction levels, their cost per cubic meter was higher than GSI. Therefore, a combination of GSI and gray results in maximum overflow reduction at a lower cost compared to common practices.  
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  ISSN 0022-1694 ISBN Medium  
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  Notes Approved no  
  Call Number THL @ christoph.kuells @ Heidari2023129538 Serial 226  
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