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Author Veerasamy, N.; Kasar, S.; Murugan, R.; Inoue, K.; Natarajan, T.; Ramola, R.C.; Fukushi, M.; Sahoo, S.K. url  openurl
  Title 234U/238U disequilibrium and 235U/238U ratios measured using MC-ICP-MS in natural high background radiation area soils to understand the fate of uranium Type Journal Article
  Year 2023 Publication (up) Chemosphere Abbreviated Journal  
  Volume 323 Issue Pages 138217  
  Keywords HBRA, MC-ICP-MS, Monazites, U/U, Uranium  
  Abstract The Chhatrapur-Gopalpur coastal area in Odisha, India is a well-known natural high background radiation (HBRA) area due to the abundance of monazite (a thorium bearing radioactive mineral) in beach sands and soils. Recent studies on Chhatrapur-Gopalpur HBRA groundwater have reported high concentrations of uranium and its decay products. Therefore, the soils of the Chhatrapur-Gopalpur HBRA are reasonably suspected as the sources of these high uranium concentrations in groundwater. In this report, first the uranium concentrations in soil samples were measured using inductively coupled plasma mass spectrometry (ICP-MS) and they were found to range from 0.61 ± 0.01 to 38.59 ± 0.16 mg kg−1. Next, the 234U/238U and 235U/238U isotope ratios were measured to establish a baseline for the first time in Chhatrapur-Gopalpur HBRA soil. Multi-collector inductively coupled plasma mass spectrometry (MC-ICP-MS) was used for measurement of these isotope ratios. The 235U/238U ratio was observed to be the normal terrestrial value. The 234U/238U activity ratio, was calculated to understand the secular equilibrium between 234U and 238U in soil and it varied from 0.959 to 1.070. To understand the dynamics of uranium in HBRA soil, physico-chemical characteristics of soil were correlated with uranium isotope ratios and this correlation of 234U/238U activity ratio indicated the leaching of 234U from Odisha HBRA soil.  
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  ISSN 0045-6535 ISBN Medium  
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  Notes Approved no  
  Call Number THL @ christoph.kuells @ veerasamy_234u238u_2023 Serial 149  
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Author Kumar, V.; Setia, R.; Pandita, S.; Singh, S.; Mitran, T. url  openurl
  Title Assessment of U and As in groundwater of India: A meta-analysis Type Journal Article
  Year 2022 Publication (up) Chemosphere Abbreviated Journal  
  Volume 303 Issue Pages 135199  
  Keywords Arsenic, Geology, Groundwater, Health risk, Soil texture, Uranium  
  Abstract More than 2.5 billion people depend upon groundwater worldwide for drinking, and giving quality water has become one of the great apprehensions of human culture. The contamination of Uranium (U) and Arsenic (As) in the groundwater of India is gaining global attention. The current review provides state-of-the-art groundwater contamination with U and As in different zones of India based on geology and soil texture. The average concentration of U in different zones of India was in the order: West Zone (41.07 μg/L) \textgreater North Zone (37.7 μg/L) \textgreater South Zone (13.5 μg/L)\textgreater Central Zone (7.4 μg/L) \textgreater East Zone (5.7 μg/L) \textgreaterSoutheast Zone (2.4 μg/L). The average concentration of As in groundwater of India is in the order: South Zone (369.7 μg/L)\textgreaterCentral Zone (260.4 μg/L)\textgreaterNorth Zone (67.7 μg/L)\textgreaterEast Zone (60.3 μg/L)\textgreaterNorth-east zone (9.78 μg/L)\textgreaterWest zone (4.14 μg/L). The highest concentration of U and As were found in quaternary sediments, but U in clay skeletal and As in loamy skeletal. Results of health risk assessment showed that the average health quotient of U in groundwater for children and adults was less than unity. In contrast, it was greater than unity for As posing a harmful impact on human health. This review provides the baseline data regarding the U and As contamination status in groundwater of India, and appropriate, effective control measures need to be taken to control this problem.  
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  Notes Approved no  
  Call Number THL @ christoph.kuells @ kumar_assessment_2022 Serial 161  
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Author Klimkova, S.; Cernik, M.; Lacinova, L.; Filip, J.; Jancik, D.; Zboril, R. url  openurl
  Title Zero-valent iron nanoparticles in treatment of acid mine water from in situ uranium leaching Type Journal Article
  Year 2011 Publication (up) Chemosphere Abbreviated Journal  
  Volume 82 Issue 8 Pages 1178-1184  
  Keywords Acid mine water, Contaminant removal, Surface stabilizing shell, Water treatment, Zero-valent iron nanoparticles  
  Abstract Acid mine water from in situ chemical leaching of uranium (Straz pod Ralskem, Czech Republic) was treated in laboratory scale experiments by zero-valent iron nanoparticles (nZVI). For the first time, nZVI were applied for the treatment of the real acid water system containing the miscellaneous mixture of pollutants, where the various removal mechanisms occur simultaneously. Toxicity of the treated saline acid water is caused by major contaminants represented by aluminum and sulphates in a high concentration, as well as by microcontaminants like As, Be, Cd, Cr, Cu, Ni, U, V, and Zn. Laboratory batch experiments proved a significant decrease in concentrations of all the monitored pollutants due to an increase in pH and a decrease in oxidation–reduction potential related to an application of nZVI. The assumed mechanisms of contaminants removal include precipitation of cations in a lower oxidation state, precipitation caused by a simple pH increase and co-precipitation with the formed iron oxyhydroxides. The possibility to control the reaction kinetics through the nature of the surface stabilizing shell (polymer vs. FeO nanolayer) is discussed as an important practical aspect.  
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  Notes Approved no  
  Call Number THL @ christoph.kuells @ klimkova_zero-valent_2011 Serial 196  
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Author Dávila, P.; Külls, C.; Weiler, M. url  openurl
  Title A toolkit for groundwater mean residence time interpretation with gaseous tracers Type Journal Article
  Year 2013 Publication (up) Computers & Geosciences Abbreviated Journal  
  Volume 61 Issue Pages 116-125  
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  Address  
  Corporate Author Thesis  
  Publisher Pergamon Place of Publication Editor  
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  Notes Approved no  
  Call Number THL @ christoph.kuells @ Davila2013toolkit Serial 22  
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Author Emparanza, A.R.; Kampmann, R.; Caso, F.D.; Morales, C.; Nanni, A. url  openurl
  Title Durability assessment of GFRP rebars in marine environments Type Journal Article
  Year 2022 Publication (up) Construction and Building Materials Abbreviated Journal  
  Volume 329 Issue Pages 127028  
  Keywords Composite FRP rebar, Durability, Service life, Marine structures, Reinforced concrete  
  Abstract Technologies developed over the last two decades have facilitated the use of glass fiber reinforced polymer (GFRP) bars as internal reinforcement for concrete structures, specially in coastal environments, mainly due to their corrosion resistance. To-date, most durability studies have focused on a single mechanical parameter (tensile strength) and a single aging environment (exposure to high alkalinity). However, knowledge gaps exists in understanding how other mechanical parameters and relevant conditioning environments may affect the durability of GFRP bars. To this end, this study assesses the durability for different physio-mechanical properties of GFRP rebars, post exposure to accelerated conditioning in seawater. Six different GFRP rebar types were submerged in seawater tanks, at various temperatures (23°C, 40°C and 60°C) for different time periods (60, 120, 210 and 365 days). In total six different physio-mechanical properties were assessed, including: tensile strength, E-modulus, transverse and horizontal shear strength, micro-structural composition and lastly, bond strength. It was inferred that rebars with high moisture absorption resulted in poor durability, in that it affected mainly the tensile strength. Based on the Arrhenius model, at 23°C all the rebars that met the acceptance criteria by ASTM D7957 are expected to retain 85% of the tensile strength capacity.  
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  ISSN 0950-0618 ISBN Medium  
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  Notes Approved no  
  Call Number THL @ christoph.kuells @ Ruizemparanza2022127028 Serial 83  
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