Abstract: The factors influencing uranium recovery in water-rock systems during acid in-situ leaching (ISL) were studied at the Kujieertai uranium deposit in Xinjiang. Using an ISL unit, a field leach trial (FLT) had been carried out to test the sequential effects of a leaching solution without oxidant (H2SO4 solution 4–8 g/L) and a leaching solution with oxidant (H2SO4 3–7 g/L, and Fe (III) 2–6 g/L). The observation of the leaching process revealed clearly defined stages of uranium release from the solid mineral to solution. Uranium mobilization from solid mineral into solution can be described in four stages. At the beginning of the acid ISL process, there was no oxidant to be added to the leaching solution and the desorption of hexavalent uranyl ions in the open pores, as well as dissolution of hexavalent uranium minerals, led to a short-term peak in the pregnant solution, which happened while pH decreased from about 5.3 to 2.62. Following the depletion of the adsorbed hexavalent uranium and a decline in uranium dissolution intensity, the addition of Fe(III) facilitated the oxidation of tetravalent uranium, which enabled intensive uranium mobilization again. During this process, the dissolution of uranium had a strong positive correlation with the reduction of Fe(III) and Eh in the leach solution. Beside hydrochemical factors, the deportment of uranium was also an important factor affecting uranium recovery. Uranium located in the open pores can be completely exposed to the solution and the mobilization intensity was significantly affected by hydrogeochemical conditions; but the uranium present in microfissures and in the ore matrix could not be fully exposed to the solution, so, their dissolution intensity was primarily controlled by corrosion and permeability of the ore. In general, the hydrogeochemical conditions and the deportment of uranium were the external and internal factors that significantly affected the dissolution and recovery of uranium in the early and middle stages of the FLT. However, in the latest stages, due to uranium depletion, enhancing the chemical potential of the leaching solution, specifically acidity and/or the amount of oxidant, had little improvement on uranium recovery.

Abstract: Groundwater resources around the world required periodic monitoring in order to ensure the safe and sustainable utilization for humans by keeping the good status of water quality. However, this could be a daunting task for developing countries due to the insufficient data in spatiotemporal resolution. Therefore, this research work aimed to assess groundwater quality in terms of drinking and irrigation purposes at the adjacent part of the Rooppur Nuclear Power Plant (RNPP) in Bangladesh. For the purposes of achieving the aim of this study, nine groundwater samples were collected seasonally (dry and wet season) and seventeen hydro-geochemical indicators were analyzed, including Temperature (Temp.), pH, electrical conductivity (EC), total dissolved solids (TDS), total alkalinity (TA), total hardness (TH), total organic carbon (TOC), bicarbonate (HCO3−), chloride (Cl−), phosphate (PO43−), sulfate (SO42−), nitrite (NO2−), nitrate (NO3−), sodium (Na+), potassium (K+), calcium (Ca2+) and magnesium (Mg2+). The present study utilized the Canadian Council of Ministers of the Environment water quality index (CCME-WQI) model to assess water quality for drinking purposes. In addition, nine indices including EC, TDS, TH, sodium adsorption ratio (SAR), percent sodium (Na%), permeability index (PI), Kelley’s ratio (KR), magnesium hazard ratio (MHR), soluble sodium percentage (SSP), and Residual sodium carbonate (RSC) were used in this research for assessing the water quality for irrigation purposes. The computed mean CCME-WQI score found higher during the dry season (ranges 48 to 74) than the wet season (ranges 40 to 65). Moreover, CCME-WQI model ranked groundwater quality between the “poor” and “marginal” categories during the wet season implying unsuitable water for human consumption. Like CCME-WQI model, majority of the irrigation index also demonstrated suitable water for crop cultivation during dry season. The findings of this research indicate that it requires additional care to improve the monitoring programme for protecting groundwater quality in the RNPP area. Insightful information from this study might be useful as baseline for national strategic planners in order to protect groundwater resources during the any emergencies associated with RNPP.

Abstract: This synthesis on groundwater recharge targets the Southern African region as a result of the dependence of the community and economic sector on the groundwater resource. Several literature based recharge studies were collected and assessed in order to find out the main controls to the occurrence of recharge. The Water Table Fluctuation and Base flow separation methods have been tested in the catchment that drains crystalline basement rocks and dolostones close to the city of Johannesburg, South Africa. Based on the assessed data the Chloride Mass Balance method resulted in groundwater recharge of less than 4% of the rainfall, while it reaches 20%, when rainfall exceeds 600mm. For the classical water balance method, recharge proportion is less than 3% of rainfall as a result of very high ambient temperature in the region. Based on the Saturated Volume Fluctuation and Water Table Fluctuation methods, recharge could be less than 6% for annual rainfall of less than 600mm. Observational results further suggest that sporadic recharge from high intensity rainfall has important contribution to the groundwater recharge in the region, owing to the presence of permeable geological cover, which could not be fully captured by most of the recharge estimation methods. This study further documents an evaluation of the most reliable recharge estimation methods in the area such as the chloride mass balance, saturated volume fluctuation and water table fluctuation methods in order to successfully manage the groundwater resource.

Abstract: Vietnam is a country with a long coastline and a high population density residing in the coastal plains. The largest dry area in Vietnam, the coastal plain of Ninh Thuan province, always lacks water in the first dry months of the year (Jan., Feb., Mar., and Apr.). Groundwater is an extremely valuable resource for supplies at this time. Therefore, the objective of this study is to establish a comprehensive approach to sustainable groundwater management in this semi-arid region. This approach is not only mitigating the negative impacts of factors such as climate change, sea level rise, and socio-economic development but also suggesting measures for management of aquifer recharge. A groundwater model for a 3-layer system with variable density flow SEAWAT is built to predict the impacts of climate change and sea level rise without a change in groundwater abstraction. This model helps to understand the trend of salt intrusion and lowering groundwater level in the study area. Afterwards, scenarios with different ground water abstraction and groundwater development such as ground dam, infiltration basin have been set up to meet the demands of socio-economic development in the future. Predicted results will show the impacts of the groundwater systems in the area such as groundwater level change, and saltwater intrusion. Controlled groundwater abstraction and some measures of groundwater development such as infiltration basin, underground dam would allow for an increase of up to 50000m3/day in the year 2050 without negative impacts on the aquifer system.

Abstract: Competing commercial demands on water resources need to be balanced as the world’s population rises. Generally, groundwater is raised by subsurface dams. In this paper, the geographic information system (GIS) software and a decision-making method were applied. As the first step, the limitations that affect the establishment of the subsurface dam were identified using eliminating criteria by the Boolean logic. Regarding the second step, the most appropriate axis was determined for subsurface dam construction in each of the limits. The analytical hierarchy process (AHP) was applied according to the evaluation criteria in this study. The aim of using AHP was to weigh and prioritize the criteria of the groundwater dam for recognizing appropriate sites. Among various places and regarding the subsurface dam construction, AHP was conducted using a hierarchy process for finding the most suitable sites in the third stage of the decision-making method. Finally, among the ten appropriate sites, cross comparison was drawn by using Decision Expert (DEX), Evaluation based on Distance from Average Solution (EDAS), and Technique for Order of Preference by Similarity to Ideal Solution (TOPSIS). Compared together (as a process of decision-making), DEX, TOPSIS, and EDAS methods assisted in ranking the most appropriate sites in the final step of subsurface dam pre-selection. A and C axes obtained scores between 1 and 2, among 10 axes according to the numerically ranked locations. Regarding the water shortage issue and better management of the underground water at certain levels, the findings of this study could be useful for the residents of Kajbid-Balaqly Watershed in the dry season. Further, water managers can use the above-mentioned methods for their decisions regarding the proper subsurface dam establishment.