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Author Sedghi, M.M.; Zhan, H. url  openurl
  Title Semi-analytical solutions of discharge variation of a qanat in an unconfined aquifer subjected to general areal recharge and nearby pumping well discharge Type Journal Article
  Year 2020 Publication (down) Journal of Hydrology Abbreviated Journal  
  Volume 584 Issue Pages 124691  
  Keywords Analytical solution, Laplace domain, Screen segmentation, Qanat, Areal recharge, Constant head  
  Abstract Qanat is a type of drain that extract water from aquifers by gravity. Significant amount of fresh water used in Middle East and other parts of the world are supplied by qanats. Despite their importance, discharge variation of these type of wells received almost no attention. The aim of this research is to obtain a Laplace domain solution of discharge variation of a qanat installed in an anisotropic unconfined aquifer subjected to arbitrary areal recharge and nearby pumping well(s) discharge. A new semi-analytical solution of drawdown is obtained first to implement the effects of arbitrary areal recharge and nearby pumping well(s) using the principle of superposition. Then, the discharge variation solution of the qanat is obtained from the drawdown solution. To establish a constant-head boundary condition at the qanat periphery, the qanat is discretized into several segments. The results of this study are presented in dimensionless discharge-dimensionless time curves. The effects of hydraulic as well as geometric parameters on the discharge variation of the qanat due to arbitrary areal recharge, falling of water table from its initial position and discharge of nearby wells are explored. We also investigate the influences of distance and screen depth and location of the nearby well on the discharge variation of the qanat. The results of this study can be utilized for multiple purposes: 1) to predict discharge of qanat in response to rainfall and nearby pumping well(s); 2) to estimate the aquifer parameters using hydrograph of the qanat; 3) to determine optimal location and pumping pattern of the nearby wells to minimize their influences on the discharge of the qanat; 4) to calculate water budget of aquifers drained by a qanat. The equation presented in this work can also be used to estimate discharge of a horizontal drain installed in cropland subjected to arbitrary irrigation pattern.  
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  ISSN 0022-1694 ISBN Medium  
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  Call Number THL @ christoph.kuells @ Sedghi2020124691 Serial 261  
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Author Sedghi, M.M.; Zhan, H. url  openurl
  Title On the discharge variation of a qanat in an alluvial fan aquifer Type Journal Article
  Year 2022 Publication (down) Journal of Hydrology Abbreviated Journal  
  Volume 610 Issue Pages 127922  
  Keywords Analytical solution, Wedge-shaped aquifer, Image well, Areal recharge  
  Abstract Qanat is a passive (unpumped) horizontal well (or a slant well with a very mild inclined angle) that is capable of extracting water from aquifers by gravity. Many qanats are constructed along the radius of the alluvial fan wedge-shaped aquifers. Analytical modeling of such a qanat-aquifer system provides great benefit for quickly screening different designs of qanats and accessing the performance of qanat discharge in the field. The previous analytical modeling of discharge of qanats, however, did not consider the wedge-shaped aquifers. Thus, the goal of this research is to obtain semi-analytical solutions of discharge variations of qanats in alluvial fan aquifers with nearby pumping wells, subjected to areal recharges due to rainfall. The uniform head boundary is considered inside the qanat (because of its enormous permeability in respect to the background aquifer). The influences of the aquifer lateral boundaries on discharge of qanat and its sensitivity to hydraulic and geometric parameters are explored. The influences of the lateral boundaries on the discharge of qanat due to areal recharge and nearby pumping wells discharge are also explored. The results of this study can be utilized for multiple purposes: 1) to predict the discharge of qanat in an alluvial fan aquifer and explore the influences of the areal recharge and nearby pumping well discharge; 2) to estimate the hydraulic parameters of the alluvial fan aquifer depleted by a qanat; 3) to determine the location of the nearby pumping well to minimize its influences on the discharge of a qanat; 4) to calculate the water budgets of aquifers depleted by qanats and pumping wells and replenished by areal recharge among other applications. This paper is an extension to the work presented by Sedghi and Zhan (2020) (which concerns an infinite unconfined aquifer) for an unconfined alluvial fan aquifer setting.  
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  ISSN 0022-1694 ISBN Medium  
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  Notes Approved no  
  Call Number THL @ christoph.kuells @ Sedghi2022127922 Serial 267  
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Author Seidl, C.; Wheeler, S.A.; Page, D. url  openurl
  Title Understanding the global success criteria for managed aquifer recharge schemes Type Journal Article
  Year 2024 Publication (down) Journal of Hydrology Abbreviated Journal  
  Volume 628 Issue Pages 130469  
  Keywords Managed Aquifer Recharge (MAR), Fuzzy-set Qualitative Comparative Analysis, Water banking, Groundwater, Water management, Water storage  
  Abstract Water availability and quality issues will only gain importance in the future, with climate change impacts putting increasing pressure on global water resources. Dealing with these challenges requires drawing on all available water management tools, including Managed Aquifer Recharge (MAR). Although MAR has seen increasing global implementation during the last half a century, it is still often overlooked as a management tool. While technical, bio-physical, and hydrogeological aspects of MAR are well researched, this cannot be said for socio-economic and other governance factors. Where information is available, this study seeks to understand the conditions necessary for MAR success. We apply fuzzy-set Qualitative Comparative Analysis on 313 world MAR applications, and also model separately for high- and low-middle-income countries. Results show that sophisticated hydrogeological site understanding and scheme operation is paramount for MAR success, as is utilizing natural water sources for high value end uses. Successful high-income country MAR schemes tend to be large and utilize natural water sources and sophisticated water injection and treatment methods to augment potable water supply; while successful low-middle-income country schemes are not large, older than 20 years, and use gravity infiltration methods and (limited) no water treatment. These findings will help inform the future suitability of MAR application design and its likely success within various contexts.  
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  Notes Approved no  
  Call Number THL @ christoph.kuells @ Seidl2024130469 Serial 273  
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Author Heaton, T.H.E. url  openurl
  Title Sources of the nitrate in phreatic groundwater in the western Kalahari Type Journal Article
  Year 1984 Publication (down) Journal of Hydrology Abbreviated Journal  
  Volume 67 Issue 1 Pages 249-259  
  Keywords  
  Abstract Elevated levels of nitrate occur in phreatic groundwater in the western Kalahari, Namibia. Nitrate in water containing 0.4–3.1 meq NO−3l−1, of widespread occurrence, has δ15N values in the range +4.9 to +8.0‰, suggesting natural derivation from the soil. The sporadic occurrence of very high levels of nitrate (> 4 meq NO−3l−1), which has δ15N between +9.3 to +18.7‰, reflects pollution derived from animal waste. The importance of considering the possible isotopic effects of denitrification, and the significance of leaching in the nitrogen budget of the Kalahari soil, are also discussed.  
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  Notes Approved no  
  Call Number THL @ christoph.kuells @ Heaton1984249 Serial 278  
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Author Vogel, J.C.; Talma, A.S.; Heaton, T.H.E. url  openurl
  Title Gaseous nitrogen as evidence for denitrification in groundwater Type Journal Article
  Year 1981 Publication (down) Journal of Hydrology Abbreviated Journal  
  Volume 50 Issue Pages 191-200  
  Keywords  
  Abstract By investigating the nitrate, oxygen, nitrogen and argon concentrations and 15N14N ratios in artesian groundwater with radiocarbon ages ranging up to 27,000 yr. a process of very slow denitrification in a confined aquifer is demonstrated. The calculated nitrogenisotope fractionation factor associated with this reaction is comparable to that reported for bacterial cultures in vitro and in vivo.  
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  Notes Approved no  
  Call Number THL @ christoph.kuells @ Vogel1981191 Serial 280  
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Author Heaton, T.H.E.; Talma, A.S.; Vogel, J.C. url  openurl
  Title Origin and history of nitrate in confined groundwater in the western Kalahari Type Journal Article
  Year 1983 Publication (down) Journal of Hydrology Abbreviated Journal  
  Volume 62 Issue 1 Pages 243-262  
  Keywords  
  Abstract Data are presented for nitrate, dinitrogen and argon concentrations and 15N14N ratios in groundwater, with radiocarbon ages up to 40,000 yr. for three confined sandstone aquifers in the western Kalahari of South West Africa/Namibia. The nitrate is probably generated within the soil of the recharge areas, and its production rate during the period 3000-40,000 B.P. has remained between 0.5 and 1.6 meq NO−3l−1 of recharge water, with ° 15N between + 4 and + 8‰. Variations in the amount of nitrate and of “excess air” in groundwater recharge are found, and can only reflect changes in the environmental conditions during recharge. They must therefore be caused by the climatic changes that have taken place during the past 25,000 yr.  
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  Notes Approved no  
  Call Number THL @ christoph.kuells @ Heaton1983243 Serial 282  
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Author Rubin, R. url  openurl
  Title Water conservation methods in Israel’s Negev desert in late antiquity Type Journal Article
  Year 1988 Publication (down) Journal of Historical Geography Abbreviated Journal  
  Volume 14 Issue 3 Pages 229-244  
  Keywords  
  Abstract Settlement in Israel’s Negev desert historically has been dependent on water conservation techniques. Fieldwork carried out on settlement sites constructed during the Byzantine period, when agriculture and trade flourished, revealed a variety of water installations some of which are in use today. Perennial springs in the Negev are generally small and difficult of access. Cisterns were the most common conservation devices and came in both large, enclosed and single, open forms. Cisterns were common particularly in the towns, where they were usually built as part of house foundations. Dams were discovered at several sites but proved to be inefficient and easily abandoned because of evaporation and siltation problems. Public reservoirs were part of the structure of the largest towns and were open and among the larges structures uncovered at settlement sites. Wells were distributed widely throughout the desert and were part of the only conservation system that did not depend directly on surface rainfall. A qanat system was located in the eastern Negev dating from the late settlement period before the area was abandoned at the turn of the eighth century. These various water systems raise questions about their builders and their origins, and suggests that builders originating in more humid Mediterranean environments tended to produce less adaptable installations than builders derived from the south or the east.  
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  ISSN 0305-7488 ISBN Medium  
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  Notes Approved no  
  Call Number THL @ christoph.kuells @ Rubin1988229 Serial 262  
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Author Vogel, J.C.; Talma, A.S.; Heaton, T.H.E.; Kronfeld, J. url  openurl
  Title Evaluating the rate of migration of an uranium deposition front within the Uitenhage Aquifer Type Journal Article
  Year 1999 Publication (down) Journal of Geochemical Exploration Abbreviated Journal  
  Volume 66 Issue 1 Pages 269-276  
  Keywords redox changes in aquifer, sandstone-type uranium deposit, South Africa, uranium series  
  Abstract The solubility of uranium in groundwater is very sensitive to changes in redox conditions. Many secondary (sandstone-type) uranium deposits have been formed when soluble U has precipitated after encountering reducing conditions in the subsurface. In the groundwater of the Uitenhage Aquifer (Cape Province, South Africa), 238U-series isotopes were used to assist in studying the history of the reducing barrier. Uranium isotopes were used to determine the present position of the barrier. Radium and radon were used to evaluate the path of migration that the front of the oxygen depletion zone has taken over the past 105 years. During this time the reducing barrier has moved, leaving in its wake a trail of U in various stages of secular equilibrium with its daughter 230Th. The 226Ra daughter of 230Th is not very mobile. Its growth upon the aquifer wall is reflected in the Rn content of the water. This in turn, due to the relatively great age of the water, indicates the extent of the 230Th ingrowth (from precipitated U) that took place before the barrier migrated.  
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  Notes Approved no  
  Call Number THL @ christoph.kuells @ vogel_evaluating_1999 Serial 126  
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Author Hubbard, B.E.; Gallegos, T.J.; Stengel, V.; Hoefen, T.M.; Kokaly, R.F.; Elliott, B. url  openurl
  Title Hyperspectral (VNIR-SWIR) analysis of roll front uranium host rocks and industrial minerals from Karnes and Live Oak Counties, Texas Coastal Plain Type Journal Article
  Year 2024 Publication (down) Journal of Geochemical Exploration Abbreviated Journal  
  Volume 257 Issue Pages 107370  
  Keywords Critical minerals, Hyperspectral, Industrial minerals, Mine waste, Texas coastal plain, Uranium  
  Abstract VNIR-SWIR (400–2500 nm) reflectance measurements were made on the surfaces of various cores, cuttings and sample splits of sedimentary rocks from the Tertiary Jackson Group, and Catahoula, Oakville and Goliad Formations. These rocks vary in composition and texture from mudstone and claystone to sandstone and are known host rocks for roll front uranium occurrences in Karnes and Live Oak Counties, Texas. Spectral reflectance profiles, 569 in total, were reduced to 125 representative spectral signatures, which were analyzed using the U.S. Geological Survey’s (USGS) Material Identification and Characterization Algorithm (MICA). MICA uses an automated continuum-removal procedure together with a least-squares linear regression to determine the fit of observed sample spectral absorption features to those of reference mineral standards in a spectral library. The reference minerals include various clay, mica, carbonate, ferric and ferrous iron minerals and their mixtures. In addition, absorption feature band-depth analysis was done to identify rock surfaces exhibiting absorption features related to uranium and zeolite minerals, which were not included in the command files used to execute MICA. Rocks from each of the four geologic units produced broadly similar spectral signatures as a result of comparable mineral compositions, but there were some notable differences. For example, Ca- and Na-montmorillonite was matched most frequently to the spectral absorption features in 2-μm (∼2000–2500 nm) wavelengths, while goethite occurred often at 1-μm (∼400–1000 nm) wavelengths. The latter is related to limonitic iron-staining in and around oxidized zones of the uranium roll front as described in previous papers. Rocks of the Jackson Group differed from those of the Catahoula, Oakville and Goliad units in that the former exhibited spectral features we interpret as being due to the presence of lignite-bearing mudstone layers. Goliad rocks exhibit spectral features related to dolomite, gypsum, anhydrite, and an unidentified green clay mineral that is possibly glauconite. Jackson Group rocks also exhibit weak but well-resolved absorption features at 964 and 1157 nm related to either or both zeolite minerals clinoptilolite and heulandite. These zeolite minerals and a few spectra exhibiting hydrous silica absorption features are indicative of alteration of volcanic glass in tuffaceous mudstone and claystone layers. A few sample spectra exhibited strong absorption features at around 1135 nm related to the uranium mineral coffinite. Both the 1135 nm coffinite and 1157 nm zeolite absorption features overlap somewhat, potentially making them difficult to distinguish without additional hyperspectral field, laboratory or remote sensing data. The results of this study were compared to mixtures of minerals described for ore, gangue and alteration minerals in deposit models for sandstone-hosted uranium, sedimentary bentonite and sedimentary zeolite. Use of these spectra can help facilitate mapping of both waste materials from the legacy mining of the above commodities, as well as future exploration and resource assessment activities.  
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  Call Number THL @ christoph.kuells @ hubbard_hyperspectral_2024 Serial 178  
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Author Grozeva, N.G.; Radwan, J.; Beaucaire, C.; Descostes, M. url  openurl
  Title Reactive transport modeling of U and Ra mobility in roll-front uranium deposits: Parameters influencing 226Ra/238U disequilibria Type Journal Article
  Year 2022 Publication (down) Journal of Geochemical Exploration Abbreviated Journal  
  Volume 236 Issue Pages 106961  
  Keywords Ra/U, Radioactive disequilibria, Radium, Reactive transport modeling, Roll-front uranium deposit  
  Abstract Uranium reserve estimates in ore deposits can be significantly impacted by 226Ra/238U disequilibria arising from the differential mobility of uranium and radium during groundwater transport. 1D reactive transport models were developed to investigate the long-term effects of retention processes (UO2(am) precipitation, U(VI) and Ra sorption on smectite, Ra co-precipitation with barite) on the repartitioning of 238U and 226Ra during formation of roll-front type deposits. Analytical solutions to radioactive decay chains were used in complement to examine the influence of geochemical parameters, including fluid 234U/238U activity ratios and α-recoil loss, on 226Ra/238U disequilibria in uranium ores. Model results demonstrate that smectite and barite can produce 226Ra/238U ratios \textgreater1 at low uranium contents and may explain 226Ra/238U disequilibria occurring in altered rock up- and downstream of roll-front deposits. The capacity of these phases to take up Ra and generate 226Ra/238U disequilibria depends on both mineral contents and groundwater compositions, and is thus expected to be site-specific. Simulations of ore deposits that advance downstream with time demonstrate the formation of stronger 226Ra/238U disequilibria, as expected, in the downgradient side or nose of the ore, reflecting both younger mineralization ages and the presence of active uranium precipitation. Whether disequilibria are positive or negative with respect to secular equilibrium, however, depends on the 234U/238U activity ratio in the fluid from which uranium minerals precipitate. Smaller hydraulic conductivities are shown to generate a narrower range in 226Ra/238U activity ratios with distance, and may explain the occurrence of disequilibria in the limb ore that are less pronounced than those in the nose. Furthermore, the ability of α-recoil loss to decrease 226Ra/238U activity ratios at secular equilibrium may account for negative disequilibria in high grade ores. The South Tortkuduk uranium deposits (Kazakhstan) are subsequently used as a case study to identify the processes and parameters that may contribute to 226Ra/238U disequilibria at this site. Variations in multiple parameters, including clay contents, barite contents, and mineralization ages, are found to reproduce measured 226Ra/238U activity ratios in the roll-front ore. Prioritization of these parameters will necessitate field measurements targeting both groundwater fluids and the host rock. Results from this study will ultimately aid geologists in building appropriate hydrogeochemical data sets to more efficiently locate and exploit uranium ore deposits.  
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  Notes Approved no  
  Call Number THL @ christoph.kuells @ grozeva_reactive_2022 Serial 180  
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