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Author Xie, T.; Lian, B.; Chen, C.; Qian, T.; Liu, X.; Shang, Z.; Li, T.; Wang, R.; Wang, Z.; Zhang, A.; Zhu, J.
Title Leaching behaviour and mechanism of U, 226Ra and 210Pb from uranium tailings at different pH conditions Type Journal Article
Year 2023 Publication Journal of Environmental Radioactivity Abbreviated Journal
Volume 270 Issue Pages 107300
Keywords Leaching experiments, Pb, Ra, U, Uranium tailings
Abstract A large number of radionuclides remain in uranium tailings, and U, 226Ra and 210Pb leach out with water chemistry, causing potential radioactive contamination to the surrounding environment. In this paper, uranium tailings from a uranium tailings pond in southern China were collected at different depths by means of borehole sampling, mixed and homogenised, and analysed for mineral and chemical composition, microscopic morphology, U, 226Ra and 210Pb fugacity, static leaching and dynamic leaching of U, 226Ra and 210Pb in uranium tailings at different pH conditions. The variation of U, 226Ra and 210Pb concentrations in the leachate under different pH conditions with time was obtained, and the leaching mechanism was analysed. The results showed that the uranium tailings were dominated by quartz, plagioclase and other minerals, of which SiO2 and Al2O3 accounted for 65.45% and 13.32% respectively, and U, 226Ra and 210Pb were mainly present in the residue form. The results of the static leaching experiments show that pH mainly influences the leaching of U, 226Ra and 210Pb by changing their chemical forms and the particle properties of the tailings, and that the lower the pH the more favourable the leaching. The results of dynamic leaching experiments during the experimental cycle showed that the leaching concentration and cumulative release of U, 226Ra and 210Pb in the leach solution were greater at lower pH conditions than at higher pH conditions, and the leaching of U, 226Ra and 210Pb at different pH conditions was mainly from the water-soluble and exchangeable states. The present research results are of great significance for the environmental risk management and control of radioactive contamination in existing uranium tailings ponds, and are conducive to ensuring the long-term safety, stability and sustainability of uranium mining sites.
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Series Editor Series Title Abbreviated Series Title
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ISSN 0265-931x ISBN Medium
Area Expedition Conference
Notes Approved no
Call Number THL @ christoph.kuells @ xie_leaching_2023 Serial (down) 200
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Author Zeng, S.; Shen, Y.; Sun, B.; Zhang, N.; Zhang, S.; Feng, S.
Title Pore structure evolution characteristics of sandstone uranium ore during acid leaching Type Journal Article
Year 2021 Publication Nuclear Engineering and Technology Abbreviated Journal
Volume 53 Issue 12 Pages 4033-4041
Keywords Acid method, In situ leaching, Nuclear magnetic resonance, Pore characteristic, Sandstone uranium ore
Abstract To better understand the permeability of uranium sandstone, improve the leaching rate of uranium, and explore the change law of pore structure characteristics and blocking mechanism during leaching, we systematically analyzed the microstructure of acid-leaching uranium sandstone. We investigated the variable rules of pore structure characteristics based on nuclear magnetic resonance (NMR). The results showed the following: (1) The uranium concentration change followed the exponential law during uranium deposits acid leaching. After 24 h, the uranium leaching rate reached 50%. The uranium leaching slowed gradually over the next 4 days. (2) Combined with the regularity of porosity variation, Stages I and II included chemical plugging controlled by surface reaction. Stage I was the major completion phase of uranium displacement with saturation precipitation of calcium sulfate. Stage II mainly precipitated iron (III) oxide-hydroxide and aluminum hydroxide. Stage III involved physical clogging controlled by diffusion. (3) In the three stages of leaching, the permeability of the leaching solution changed with the pore structure, which first decreased, then increased, and then decreased.
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Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 1738-5733 ISBN Medium
Area Expedition Conference
Notes Approved no
Call Number THL @ christoph.kuells @ zeng_pore_2021 Serial (down) 199
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Author Zhao, Y.; Li, X.; Lei, L.; Chen, L.; Luo, Z.
Title Permeability evolution mechanism and the optimum permeability determination of uranium leaching from low-permeability sandstone treated with low-frequency vibration Type Journal Article
Year 2023 Publication Journal of Rock Mechanics and Geotechnical Engineering Abbreviated Journal
Volume 15 Issue 10 Pages 2597-2610
Keywords Chemical reactive rate, Low-frequency vibration, Low-permeability sandstone, Optimum permeability, Permeability evolution mechanism, Uranium migration
Abstract Low-frequency vibrations can effectively improve natural sandstone permeability, and higher vibration frequency is associated with larger permeability. However, the optimum permeability and permeability evolution mechanism for uranium leaching and the relationship between permeability and the change of chemical reactive rate affecting uranium leaching have not been determined. To solve the above problems, in this study, identical homogeneous sandstone samples were selected to simulate low-permeability sandstone; a permeability evolution model considering the combined action of vibration stress, pore water pressure, water flow impact force, and chemical erosion was established; and vibration leaching experiments were performed to test the model accuracy. Both the permeability and chemical reactions were found to simultaneously restrict U6+ leaching, and the vibration treatment increased the permeability, causing the U6+ leaching reaction to no longer be diffusion-constrained but to be primarily controlled by the reaction rate. Changes of the model calculation parameters were further analyzed to determine the permeability evolution mechanism under the influence of vibration and chemical erosion, to prove the correctness of the mechanism according to the experimental results, and to develop a new method for determining the optimum permeability in uranium leaching. The uranium leaching was found to primarily follow a process consisting of (1) a permeability control stage, (2) achieving the optimum permeability, (3) a chemical reactive rate control stage, and (4) a channel flow stage. The resolution of these problems is of great significance for facilitating the application and promotion of low-frequency vibration in the CO2 + O2 leaching process.
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Language Summary Language Original Title
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Series Volume Series Issue Edition
ISSN 1674-7755 ISBN Medium
Area Expedition Conference
Notes Approved no
Call Number THL @ christoph.kuells @ zhao_permeability_2023 Serial (down) 198
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Author Uhrie, J.L.; Drever, J.I.; Colberg, P.J.S.; Nesbitt, C.C.
Title In situ immobilization of heavy metals associated with uranium leach mines by bacterial sulfate reduction Type Journal Article
Year 1996 Publication Hydrometallurgy Abbreviated Journal
Volume 43 Issue 1 Pages 231-239
Keywords
Abstract Laboratory experiments with mixed populations of sulfate-reducing bactreria were shown to mediate the removal of milligrams/liter concentrations of uranium, selenium, arsenic and vanadium from aqueous solution via reduction, precipitation and adsorption. Results of laboratory experiments with active sulfidogenic biomass suggest that injection of sulfate and a source of carbon could enhance anaerobic microbial activity in and around uranium leach mines leading to in situ immobilization contaminating metals.
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ISSN 0304-386x ISBN Medium
Area Expedition Conference
Notes Approved no
Call Number THL @ christoph.kuells @ uhrie_situ_1996 Serial (down) 197
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Author Klimkova, S.; Cernik, M.; Lacinova, L.; Filip, J.; Jancik, D.; Zboril, R.
Title Zero-valent iron nanoparticles in treatment of acid mine water from in situ uranium leaching Type Journal Article
Year 2011 Publication Chemosphere Abbreviated Journal
Volume 82 Issue 8 Pages 1178-1184
Keywords Acid mine water, Contaminant removal, Surface stabilizing shell, Water treatment, Zero-valent iron nanoparticles
Abstract Acid mine water from in situ chemical leaching of uranium (Straz pod Ralskem, Czech Republic) was treated in laboratory scale experiments by zero-valent iron nanoparticles (nZVI). For the first time, nZVI were applied for the treatment of the real acid water system containing the miscellaneous mixture of pollutants, where the various removal mechanisms occur simultaneously. Toxicity of the treated saline acid water is caused by major contaminants represented by aluminum and sulphates in a high concentration, as well as by microcontaminants like As, Be, Cd, Cr, Cu, Ni, U, V, and Zn. Laboratory batch experiments proved a significant decrease in concentrations of all the monitored pollutants due to an increase in pH and a decrease in oxidation–reduction potential related to an application of nZVI. The assumed mechanisms of contaminants removal include precipitation of cations in a lower oxidation state, precipitation caused by a simple pH increase and co-precipitation with the formed iron oxyhydroxides. The possibility to control the reaction kinetics through the nature of the surface stabilizing shell (polymer vs. FeO nanolayer) is discussed as an important practical aspect.
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Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0045-6535 ISBN Medium
Area Expedition Conference
Notes Approved no
Call Number THL @ christoph.kuells @ klimkova_zero-valent_2011 Serial (down) 196
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