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Author Asare, P.; Atun, F.; Pfeffer, K.
Title (down) Nature-Based Solutions (NBS) in spatial planning for urban flood mitigation: The perspective of flood management experts in Accra Type Journal Article
Year 2023 Publication Land Use Policy Abbreviated Journal
Volume 133 Issue Pages 106865
Keywords Naure-Based Solutions, Urban expansion, Urban floods, Urban flood management, Spatial planning, NBS integration
Abstract The rapid rate of urban expansion with its associated physical development in recent years conflicts with the urban ecosystem and the services it provides. In most Sub-Saharan African cities, rapid urban expansion often does not conform to existing spatial plans. Physical developments are sometimes carried out in unauthorized areas, contributing to urban floods. The Sub-Saharan African regions’ flood management strategies mainly focus on engineering solutions but have not been fully functional in mitigating urban floods. There is a scarcity of knowledge on how urban flood-related NBS measures can be part of the spatial development in Sub-Saharan African cities for effective flood management. In order to address this gap, this study employed content and text analysis of policy documents and interviews to understand how current spatial and flood mitigation schemes in Accra, Ghana reflect possible NBS applicability and identify possible approaches to integrating NBS into existing planning schemes to prevent urban floods. The study found that Accra’s spatial plans and flood mitigation schemes reflect a possibility of NBS integration. Additionally, the study unveiled techniques for integrating NBS measures and possible implementation barriers and facilitation in the Ghanaian context, which can be linked to combating the challenges that the Ghanaian spatial planning and flood management authorities face. The research, therefore, contributes to knowledge of how NBS can be integrated into spatial planning systems and flood mitigation schemes in Sub-Saharan African regions.
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ISSN 0264-8377 ISBN Medium
Area Expedition Conference
Notes Approved no
Call Number THL @ christoph.kuells @ Asare2023106865 Serial 236
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Author Borrego-Alonso, D.; Quintana-Arnés, B.; Lozano, J.C.
Title (down) Natural radionuclides behaviour in drinking groundwaters from Castilla y León (Spain); radiological implications Type Journal Article
Year 2023 Publication Water Research Abbreviated Journal
Volume 245 Issue Pages 120616
Keywords Drinking water, Environmental monitoring, Natural radioactivity, Public health, Radiological characterisation
Abstract Since the coming into force of the European Council Directive 51/2013 EURATOM and its transposition into the Spanish legislation, the presence of radioactive substances in drinking waters must be kept under surveillance to ensure that the health protection requirements are met. Driven by this regulatory framework, in an attempt to know the starting point from which to design surveillance plans, the groundwaters intended for human consumption of Castilla y León (Spain) have been radiologically characterised by using both low-level γ-ray and α-particle spectrometry to determine the activity concentration of the natural radionuclides needed to account for the indicative dose estimation. This extensive research has comprised the radiological characterisation of more than 400 drinking water samples from one of the European Union’s largest regions. Furthermore, the gross α and gross β activities have been analysed. Results showed a high geographical variability that can be related to the hydrogeological formations where the groundwaters come from. The uranium isotopes, 234U and 238U, are the main radionuclides present in the analysed drinking waters reaching values up to 2000 mBq/L, in the southwestern and western of Castilla y León, where U-rich minerals are part of the host rock. High 210Pb and 226,228Ra occurrences are found in the low permeability igneous and metasedimentary hydrogeological formations of Salamanca province. From a public health protection point of view, 4.4% of the total drinking water samples from intakes exceeded the Indicative Dose parametric value of 0.1 mSv, which is a not negligible number of samples, being very likely related to granitic and metamorphosed host rock under specific local conditions. This fact highlights the need for research and consideration of special surveillance of the groundwaters from these areas.
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Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0043-1354 ISBN Medium
Area Expedition Conference
Notes Approved no
Call Number THL @ christoph.kuells @ borrego-alonso_natural_2023 Serial 157
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Author Hofmann, H.; Pearce, J.K.; Hayes, P.; Golding, S.D.; Hall, N.; Baublys, K.A.; Raiber, M.; Suckow, A.
Title (down) Multi-tracer approach to constrain groundwater flow and geochemical baseline assessments for CO2 sequestration in deep sedimentary basins Type Journal Article
Year 2023 Publication International Journal of Coal Geology Abbreviated Journal
Volume Issue Pages 104438
Keywords CO geological storage, Great Artesian Basin, Groundwater chemistry, Isotopic tracer, Surat Basin
Abstract Geological storage of gases will be necessary in the push to net zero and the energy transition to reduce carbon emissions to atmosphere. These include CO2 geological storage in suitable sandstone reservoirs. Understanding groundwater flow, connectivity and hydrogeochemical processes in aquifer and storage systems is vital to prevent risk and protect important water resources, such as the Great Artesian Basin. Here, we provide a ‘tool-box’ of geochemical assessment methods to provide information on flow patterns through the basin’s aquifers (changes in chemistry along flow path), stagnant versus flowing conditions (cosmogenic isotopes and noble gases), inter-aquifer connectivity and seal properties (major ions, Sr and stable isotopes), water quality (major ions and metals) and general assessments on residence times of groundwater (cosmogenic isotopes and noble gases). This information can be used with reservoir and groundwater models to inform on possible changes in the above-mentioned processes and serve as input parameters for CO2 injection impact modelling. We demonstrate the use and interpretation on an example of a potential CO2 storage geological sequestration site in the Surat Basin, part of the Great Artesian Basin, and the aquifers that overly the reservoir. The stable water isotopes are depleted compared to average rainfall and most likely indicate greater contributions from monsoonal rain events from the northern monsoonal troughs, where amount and rainout effects lead to the depletion rather than colder recharge climates. This is supported by the modern recharge temperatures from noble gases. Inter-aquifer mixing between the Precipice Sandstone reservoir and the Hutton Sandstone aquifer seems unlikely as the Sr isotope ratios are distinctly different suggesting that the Evergreen Formation is a seal in the locations sampled. Mixing, however, occurs on the edges of the basin, especially in the south-east and east where the Surat Basin transitions into the Clarence-Moreton Basin. Groundwater flow appears to be to the south in the Precipice Sandstone, with a component of flow east to the Clarence-Morton Basin. The cosmogenic isotopes and noble gases strongly indicate very long residence times of groundwater in the central south Precipice Sandstone around a proposed storage site. 14C values below analytical uncertainty, R36Cl ratios at secular equilibrium as well as high He concentrations and high 40Ar/36Ar ratios support the argument that groundwater flow in this area is extremely slow or groundwater is stagnant. The results of this study reflect the geological and hydrogeological complexities of sedimentary basins and that baseline studies, such as this one, are paramount for management strategies.
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Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0166-5162 ISBN Medium
Area Expedition Conference
Notes Approved no
Call Number THL @ christoph.kuells @ hofmann_multi-tracer_2023 Serial 165
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Author Smedley, P.L.; Bearcock, J.M.; Ward, R.S.; Crewdson, E.; Bowes, M.J.; Darling, W.G.; Smith, A.C.
Title (down) Monitoring of methane in groundwater from the Vale of Pickering, UK: Temporal variability and source discrimination Type Journal Article
Year 2023 Publication Chemical Geology Abbreviated Journal
Volume 636 Issue Pages 121640
Keywords Aquifer, Biogenic, Ethane, Hydrocarbons, Methane, Shale gas
Abstract Groundwater abstracted from aquifers in the Vale of Pickering, North Yorkshire, UK and monitored over the period 2015–2022, shows evidence of variable but commonly high concentrations of dissolved CH4. Sampled groundwater from the Jurassic organic-rich Kimmeridge Clay Formation (boreholes up to 180 m depth) has concentrations up to 57 mg/L, and concentrations up to 59 mg/L are found in groundwater from underlying confined Corallian Group limestone (borehole depths 50–227 m). The high concentrations are mainly from boreholes in the central parts of the vale. Small concentrations of ethane (C2H6, up to 800 μg/L) have been found in the Kimmeridge Clay and confined Corallian groundwaters, and of propane (C3H8, up to 160 μg/L) in deeper boreholes (110–180 m) from these formations. The concentrations are typically higher in groundwater from the deeper boreholes and vary with hydrostatic pressure, reflecting the pressure control on CH4 solubility. The occurrences contrast with groundwater from shallow Quaternary superficial deposits which have low CH4 concentrations (up to 0.39 mg/L), and with the unconfined and semi-confined sections of the Corallian aquifer (up to 0.7 mg/L) around the margins of the vale. Groundwater from the Quaternary, Kimmeridge Clay formations and to a small extent the confined Corallian aquifer, supports local private-water supplies, that from the peripheral unconfined sections of Corallian also supports public supply for towns and villages across the region. Dissolved methane/ethane (C1/C2) ratios and stable-isotopic compositions (δ13C-CH4, δ2H-CH4 and δ13C-CO2) suggest that the high-CH4 groundwater from both the Kimmeridge Clay and confined Corallian formations derives overwhelmingly from biogenic reactions, the methanogenesis pathway by CO2 reduction. A small minority of groundwater samples shows a more enriched δ13C-CH4 composition (−50 to −44 ‰) which has been interpreted as due to anaerobic or aerobic methylotrophic oxidation in situ or post-sampling oxidation, rather than derivation by a thermogenic route. Few of the existing groundwater sites are proximal to abandoned or disused conventional hydrocarbon wells that exist in the region, and little evidence has been found for an influence on groundwater dissolved gases from these sites. The Vale of Pickering has also been under recent consideration for development of an unconventional hydrocarbon (shale-gas) resource. In this context, the monitoring of dissolved gases has been an important step in establishing the high-CH4 baseline of groundwaters from Jurassic deposits in the region and in apportioning their sources and mechanisms of genesis.
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Language Summary Language Original Title
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0009-2541 ISBN Medium
Area Expedition Conference
Notes Approved no
Call Number THL @ christoph.kuells @ smedley_monitoring_2023 Serial 172
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Author Bresinsky, L.; Kordilla, J.; Hector, T.; Engelhardt, I.; Livshitz, Y.; Sauter, M.
Title (down) Managing climate change impacts on the Western Mountain Aquifer: Implications for Mediterranean karst groundwater resources Type Journal Article
Year 2023 Publication Journal of Hydrology X Abbreviated Journal
Volume 20 Issue Pages 100153
Keywords Groundwater recharge, Storage, Hydrogeological droughts, Climate change effects, Groundwater management, Mitigation of climate change effects
Abstract Many studies highlight the decrease in precipitation due to climate change in the Mediterranean region, making it a prominent hotspot. This study examines the combined impacts of climate change and three groundwater demand scenarios on the water resources of the Western Mountain Aquifer (WMA) in Israel and the West Bank. While commonly used methods for quantifying groundwater recharge and water resources rely on regression models, it is important to acknowledge their limitations when assessing climate change impacts. Regression models and other data-driven approaches are effective within observed variability but may lack predictive power when extrapolated to conditions beyond historical fluctuations. A comprehensive assessment requires distributed process-based numerical models incorporating a broader range of relevant physical flow processes and, ideally, ensemble model projections. In this study, we simulate the dynamics of dual-domain infiltration and precipitation partitioning using a HydroGeoSphere (HGS) model for variably saturated water flow coupled to a soil-epikarst water balance model in the WMA. The model input includes downscaled high-resolution climate projections until 2070 based on the IPCC RCP4.5 scenario. The results reveal a 5% to 10% decrease in long-term average groundwater recharge compared to a 30% reduction in average precipitation. The heterogeneity of karstic flow and increased intensity of individual rainfall events contribute to this mitigated impact on groundwater recharge, underscoring the importance of spatiotemporally resolved climate models with daily precipitation data. However, despite the moderate decrease in recharge, the study highlights the increasing length and severity of consecutive drought years with low recharge values. It emphasizes the need to adjust current management practices to climate change, as freshwater demand is expected to rise during these periods. Additionally, the study examines the emergence of hydrogeological droughts and their propagation from the surface to the groundwater. The results suggest that the 48-month standardized precipitation index (SPI-48) is a suitable indicator for hydrogeological drought emergence due to reduced groundwater recharge.
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Series Editor Series Title Abbreviated Series Title
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ISSN 2589-9155 ISBN Medium
Area Expedition Conference
Notes Approved no
Call Number THL @ christoph.kuells @ Bresinsky2023100153 Serial 223
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Author Wang, B.; Luo, Y.; Qian, J.-zhong; Liu, J.-hui; Li, X.; Zhang, Y.-hong; Chen, Q.-qian; Li, L.-yao; Liang, D.-ye; Huang, J.
Title (down) Machine learning–based optimal design of the in-situ leaching process parameter (ISLPP) for the acid in-situ leaching of uranium Type Journal Article
Year 2023 Publication Journal of Hydrology Abbreviated Journal
Volume 626 Issue Pages 130234
Keywords In-situ leaching, Injection rate design, Lixiviant concentration design, Machine learning, Simulation-optimisation, Uncertainty
Abstract The migration process of leached uranium in the in-situ leaching of uranium is considered a typical reactive transport problem. During this process, the lixiviant concentration and injection rate are important in-situ leaching process parameters (ISLPP) to efficiently recover uranium. However, several uncertain factors affect the outcomes of the ISLPP design. In addition, the repeated use of the reactive transport model (RTM) for investigating the acid in-situ leaching of uranium with the application of the Monte Carlo method leads to a substantial computational load. For this reason, a machine learning (ML)–based surrogate model was developed with the backpropagation neural network (BPNN) method to replace the RTM under the condition of uncertain parameters. Moreover, the simulated annealing optimisation model for ISLPP was created based on the proposed surrogate model. The optimal ISLPP was achieved that generated maximum profits from uranium recovery under different lixiviant prices, uranium prices and exploitation times. The optimal design framework of ISLPP based on the proposed ML algorithm was then applied in the Bayan-Uul sandstone-type uranium deposit in Inner Mongolia, China. From our analysis, it was demonstrated that the ML-based surrogate model exhibited great fitness with the RTM. The optimal results of the ISLPP indicated that the lixiviant concentration and injection rate could be adjusted based on the fluctuations in lixiviant price, uranium price and exploitation time. If the prices of sulphuric acid were high, a specific concentration of hydrogen peroxide could be injected into the injection well to promote the oxidation and dissolution of the uranium ore to increase the income from the uranium recovery. The optimisation model can also use the ISLPP scheme to boost the revenues from different lixiviant prices, uranium prices and exploitation times under the uncertainty of porosity, illustrating the applicability of the ML-based optimal design method of ISLPP in ISL mining. A general framework for developing surrogate models, as well as for conducting uncertainty analyses for a wide range of groundwater models was proposed here yielding valuable insights.
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Language Summary Language Original Title
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0022-1694 ISBN Medium
Area Expedition Conference
Notes Approved no
Call Number THL @ christoph.kuells @ wang_machine_2023 Serial 210
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Author Lawrinenko, M.; Kurwadkar, S.; Wilkin, R.T.
Title (down) Long-term performance evaluation of zero-valent iron amended permeable reactive barriers for groundwater remediation – A mechanistic approach Type Journal Article
Year 2023 Publication Geoscience Frontiers Abbreviated Journal
Volume 14 Issue 2 Pages 101494
Keywords Geochemistry, Iron, Permeable reactive barrier, Plating reactions, Reduction potential, Surface passivation
Abstract Permeable reactive barriers (PRBs) are used for groundwater remediation at contaminated sites worldwide. This technology has been efficient at appropriate sites for treating organic and inorganic contaminants using zero-valent iron (ZVI) as a reductant and as a reactive material. Continued development of the technology over the years suggests that a robust understanding of PRB performance and the mechanisms involved is still lacking. Conflicting information in the scientific literature downplays the critical role of ZVI corrosion in the remediation of various organic and inorganic pollutants. Additionally, there is a lack of information on how different mechanisms act in tandem to affect ZVI-groundwater systems through time. In this review paper, we describe the underlying mechanisms of PRB performance and remove isolated misconceptions. We discuss the primary mechanisms of ZVI transformation and aging in PRBs and the role of iron corrosion products. We review numerous sites to reinforce our understanding of the interactions between groundwater contaminants and ZVI and the authigenic minerals that form within PRBs. Our findings show that ZVI corrosion products and mineral precipitates play critical roles in the long-term performance of PRBs by influencing the reactivity of ZVI. Pore occlusion by mineral precipitates occurs at the influent side of PRBs and is enhanced by dissolved oxygen and groundwater rich in dissolved solids and high alkalinity, which negatively impacts hydraulic conductivity, allowing contaminants to potentially bypass the treatment zone. Further development of site characterization tools and models is needed to support effective PRB designs for groundwater remediation.
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Language Summary Language Original Title
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 1674-9871 ISBN Medium
Area Expedition Conference
Notes Approved no
Call Number THL @ christoph.kuells @ lawrinenko_long-term_2023 Serial 143
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Author Xie, T.; Lian, B.; Chen, C.; Qian, T.; Liu, X.; Shang, Z.; Li, T.; Wang, R.; Wang, Z.; Zhang, A.; Zhu, J.
Title (down) Leaching behaviour and mechanism of U, 226Ra and 210Pb from uranium tailings at different pH conditions Type Journal Article
Year 2023 Publication Journal of Environmental Radioactivity Abbreviated Journal
Volume 270 Issue Pages 107300
Keywords Leaching experiments, Pb, Ra, U, Uranium tailings
Abstract A large number of radionuclides remain in uranium tailings, and U, 226Ra and 210Pb leach out with water chemistry, causing potential radioactive contamination to the surrounding environment. In this paper, uranium tailings from a uranium tailings pond in southern China were collected at different depths by means of borehole sampling, mixed and homogenised, and analysed for mineral and chemical composition, microscopic morphology, U, 226Ra and 210Pb fugacity, static leaching and dynamic leaching of U, 226Ra and 210Pb in uranium tailings at different pH conditions. The variation of U, 226Ra and 210Pb concentrations in the leachate under different pH conditions with time was obtained, and the leaching mechanism was analysed. The results showed that the uranium tailings were dominated by quartz, plagioclase and other minerals, of which SiO2 and Al2O3 accounted for 65.45% and 13.32% respectively, and U, 226Ra and 210Pb were mainly present in the residue form. The results of the static leaching experiments show that pH mainly influences the leaching of U, 226Ra and 210Pb by changing their chemical forms and the particle properties of the tailings, and that the lower the pH the more favourable the leaching. The results of dynamic leaching experiments during the experimental cycle showed that the leaching concentration and cumulative release of U, 226Ra and 210Pb in the leach solution were greater at lower pH conditions than at higher pH conditions, and the leaching of U, 226Ra and 210Pb at different pH conditions was mainly from the water-soluble and exchangeable states. The present research results are of great significance for the environmental risk management and control of radioactive contamination in existing uranium tailings ponds, and are conducive to ensuring the long-term safety, stability and sustainability of uranium mining sites.
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Language Summary Language Original Title
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0265-931x ISBN Medium
Area Expedition Conference
Notes Approved no
Call Number THL @ christoph.kuells @ xie_leaching_2023 Serial 200
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Author Abadi, B.; Sadeghfam, S.; Ehsanitabar, A.; Nadiri, A.A.
Title (down) Investigating socio-economic and hydrological sustainability of ancient Qanat water systems in arid regions of central Iran Type Journal Article
Year 2023 Publication Groundwater for Sustainable Development Abbreviated Journal
Volume 23 Issue Pages 100988
Keywords Ancient irrigation, QWSs, GIS, Indigenous knowledge, Maintenance, Distribution
Abstract The Qanat water systems (QWSs), the ancient water engineering systems in Iran belonging to the very distant past, have harvested groundwater from drainages to convey it toward the surface with no use of energy. The present article highlights the socio-economic aspects of the sustainability of the QWSs and gives a satisfactory explanation of why the QWSs should be restored. In doing so, we subscribe to the view that indigenous and scientific knowledge should be incorporated. The former serves to tackle the restoration of the QWSs, the latter contributes to the distribution of water into the farmlands as efficiently as possible. Measured by (a) resilience, (b) reliability, (c) vulnerability, and (d) sustainability, the GIS technique made clear the performance of the QWSs has, therefore, the worst condition observed in terms of resiliency; the best condition observed concerning the vulnerability. Moreover, the QWSs have intermediate performance in terms of reliability. Finally, the sustainability index (SI) classifies the QWSs into different bands, which provide explicit support to take priority of the selection of the QWSs for restoration. In conclusion, a theoretical framework has been drawn to keep the QWSs sustainable.
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Language Summary Language Original Title
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 2352-801x ISBN Medium
Area Expedition Conference
Notes Approved no
Call Number THL @ christoph.kuells @ Abadi2023100988 Serial 268
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Author Custódio, D.A.; Ghisi, E.
Title (down) Impact of residential rainwater harvesting on stormwater runoff Type Journal Article
Year 2023 Publication Journal of Environmental Management Abbreviated Journal
Volume 326 Issue Pages 116814
Keywords Rainwater harvesting, Residential buildings, Stormwater runoff, Floods, Computer simulation
Abstract Population increase, climate change and soil impermeability are factors causing floods in large urban centres. Such places also always have water shortage problems. This research aims to evaluate the influence of rainwater harvesting in residential buildings on stormwater in a basin located in southern Brazil (Rio Cachoeira Basin). Urbanised and non-urbanised areas, soil types, curve numbers and time of concentration of each sub-basin were taken into account. Through the HEC-HMS programme, it was possible to calculate hydrographs for the base scenario (when there is no rainwater harvesting). Then, rainwater tanks for the residential buildings were sized using the computer programme Netuno. In the second scenario, there is rainwater harvesting in all residential buildings. Thus, the hydrographs for the second scenario were also calculated. The peak flow reduction potentials for the sub-basins ranged from 2.7% to 14.3%. The highest percentage (14.3%) did not occur in the sub-basin with the most extensive roof area; such highest peak flow reduction occurred in Bom Retiro sub-basin. In Bom Retiro sub-basin, there are more houses than multi-storey residential buildings. Even when considering the full potential of rainwater harvesting for roof areas of all existing buildings in the Rio Cachoeira Basin, the average potential reduction in peak flow was 7.2%. The conclusion is that rainwater tanks in residential buildings have little influence on stormwater runoff, and the stormwater runoff will be less affected when the area of the hydrographic basin is larger. Thus, the reduction in peak flows is insignificant when considering the flooding in the region.
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Language Summary Language Original Title
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0301-4797 ISBN Medium
Area Expedition Conference
Notes Approved no
Call Number THL @ christoph.kuells @ Custodio2023116814 Serial 231
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