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Author Liu, Z.; Li, C.; Tan, K.; Li, Y.; Tan, W.; Li, X.; Zhang, C.; Meng, S.; Liu, L. url  openurl
  Title Study of natural attenuation after acid in situ leaching of uranium mines using isotope fractionation and geochemical data Type Journal Article
  Year 2023 Publication Science of The Total Environment Abbreviated Journal  
  Volume 865 Issue Pages 161033  
  Keywords Acid in situ leaching, Geochemical and isotopic tracing, Groundwater contamination, Natural attenuation, Uranium post-mining  
  Abstract Acid in situ leaching (AISL) is a subsurface mining approach suitable for low-grade ores which does not generate tailings, and has been adopted widely in uranium mining. However, this technique causes an extremely high concentration of contaminants at post-mining sites and in the surroundings soon after the mining ceases. As a potential AISL remediation strategy, natural attenuation has not been studied in detail. To address this problem, groundwater collected from 26 wells located within, adjacent, upgradient, and downgradient of a post-mining site were chosen to analyze the fate of U(VI), SO42−, δ34S, and δ238U, to reveal the main mechanisms governing the migration and attenuation of the dominant contaminants and the spatio-temporal evolutions of contaminants in the confined aquifer of the post-mining site. The δ238U values vary from −0.07 ‰ to 0.09 ‰ in the post-mining site and from −1.43 ‰ to 0.03 ‰ around the post-mining site. The δ34S values were found to vary from 3.3 ‰ to 6.2 ‰ in the post-mining site and from 6.0 ‰ to 11.0 ‰ around the post-mining site. Detailed analysis suggests that there are large differences between the range of isotopic composition variation and the range of pollutants concentration distribution, and the estimated Rayleigh isotope fractionation factor is 0.9994–0.9997 for uranium and 1.0032–1.0061 for sulfur. The isotope ratio of uranium and sulfur can be used to deduce the migration history of the contaminants and the irreversibility of the natural attenuation process in the anoxic confined aquifer. Combining the isotopic fractionation data for U and S with the concentrations of uranium and sulfate improved the accuracy of understanding of reducing conditions along the flow path. The study also indicated that as long as the geological conditions are favorable for redox reactions, natural attenuation could be used as a cost-effective remediation scheme.  
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  Series Volume Series Issue Edition  
  ISSN 0048-9697 ISBN Medium  
  Area Expedition Conference  
  Notes Approved no  
  Call Number THL @ christoph.kuells @ liu_study_2023 Serial 155  
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Author Jroundi, F.; Povedano-Priego, C.; Pinel-Cabello, M.; Descostes, M.; Grizard, P.; Purevsan, B.; Merroun, M.L. url  openurl
  Title Evidence of microbial activity in a uranium roll-front deposit: Unlocking their potential role as bioenhancers of the ore genesis Type Journal Article
  Year 2023 Publication Science of The Total Environment Abbreviated Journal  
  Volume 861 Issue Pages 160636  
  Keywords ISR, Metatranscriptomes, Microbial metabolisms, Ore genesis, Roll-front deposit, Uranium  
  Abstract Uranium (U) roll-front deposits constitute a valuable source for an economical extraction by in situ recovery (ISR) mining. Such technology may induce changes in the subsurface microbiota, raising questions about the way their activities could build a functional ecosystem in such extreme environments (i.e.: oligotrophy and high SO4 concentration and salinity). Additionally, more information is needed to dissipate the doubts about the microbial role in the genesis of such U orebodies. A U roll-front deposit hosted in an aquifer driven system (in Zoovch Ovoo, Mongolia), intended for mining by acid ISR, was previously explored and showed to be governed by a complex bacterial diversity, linked to the redox zonation and the geochemical conditions. Here for the first time, transcriptional activities of microorganisms living in such U ore deposits are determined and their metabolic capabilities allocated in the three redox-inherited compartments, naturally defined by the roll-front system. Several genes encoding for crucial metabolic pathways demonstrated a strong biological role controlling the subsurface cycling of many elements including nitrate, sulfate, metals and radionuclides (e.g.: uranium), through oxidation-reduction reactions. Interestingly, the discovered transcriptional behaviour gives important insights into the good microbial adaptation to the geochemical conditions and their active contribution to the stabilization of the U ore deposits. Overall, evidences on the importance of these microbial metabolic activities in the aquifer system are discussed that may clarify the doubts on the microbial role in the genesis of low-temperature U roll-front deposits, along the Zoovch Ovoo mine.  
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  ISSN 0048-9697 ISBN Medium  
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  Notes Approved no  
  Call Number THL @ christoph.kuells @ jroundi_evidence_2023 Serial 138  
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Author Veerasamy, N.; Kasar, S.; Murugan, R.; Inoue, K.; Natarajan, T.; Ramola, R.C.; Fukushi, M.; Sahoo, S.K. url  openurl
  Title 234U/238U disequilibrium and 235U/238U ratios measured using MC-ICP-MS in natural high background radiation area soils to understand the fate of uranium Type Journal Article
  Year 2023 Publication Chemosphere Abbreviated Journal  
  Volume 323 Issue Pages 138217  
  Keywords HBRA, MC-ICP-MS, Monazites, U/U, Uranium  
  Abstract The Chhatrapur-Gopalpur coastal area in Odisha, India is a well-known natural high background radiation (HBRA) area due to the abundance of monazite (a thorium bearing radioactive mineral) in beach sands and soils. Recent studies on Chhatrapur-Gopalpur HBRA groundwater have reported high concentrations of uranium and its decay products. Therefore, the soils of the Chhatrapur-Gopalpur HBRA are reasonably suspected as the sources of these high uranium concentrations in groundwater. In this report, first the uranium concentrations in soil samples were measured using inductively coupled plasma mass spectrometry (ICP-MS) and they were found to range from 0.61 ± 0.01 to 38.59 ± 0.16 mg kg−1. Next, the 234U/238U and 235U/238U isotope ratios were measured to establish a baseline for the first time in Chhatrapur-Gopalpur HBRA soil. Multi-collector inductively coupled plasma mass spectrometry (MC-ICP-MS) was used for measurement of these isotope ratios. The 235U/238U ratio was observed to be the normal terrestrial value. The 234U/238U activity ratio, was calculated to understand the secular equilibrium between 234U and 238U in soil and it varied from 0.959 to 1.070. To understand the dynamics of uranium in HBRA soil, physico-chemical characteristics of soil were correlated with uranium isotope ratios and this correlation of 234U/238U activity ratio indicated the leaching of 234U from Odisha HBRA soil.  
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  Series Volume Series Issue Edition  
  ISSN 0045-6535 ISBN Medium  
  Area Expedition Conference  
  Notes Approved no  
  Call Number THL @ christoph.kuells @ veerasamy_234u238u_2023 Serial 149  
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Author Borrego-Alonso, D.; Quintana-Arnés, B.; Lozano, J.C. url  openurl
  Title Natural radionuclides behaviour in drinking groundwaters from Castilla y León (Spain); radiological implications Type Journal Article
  Year 2023 Publication Water Research Abbreviated Journal  
  Volume 245 Issue Pages 120616  
  Keywords Drinking water, Environmental monitoring, Natural radioactivity, Public health, Radiological characterisation  
  Abstract Since the coming into force of the European Council Directive 51/2013 EURATOM and its transposition into the Spanish legislation, the presence of radioactive substances in drinking waters must be kept under surveillance to ensure that the health protection requirements are met. Driven by this regulatory framework, in an attempt to know the starting point from which to design surveillance plans, the groundwaters intended for human consumption of Castilla y León (Spain) have been radiologically characterised by using both low-level γ-ray and α-particle spectrometry to determine the activity concentration of the natural radionuclides needed to account for the indicative dose estimation. This extensive research has comprised the radiological characterisation of more than 400 drinking water samples from one of the European Union’s largest regions. Furthermore, the gross α and gross β activities have been analysed. Results showed a high geographical variability that can be related to the hydrogeological formations where the groundwaters come from. The uranium isotopes, 234U and 238U, are the main radionuclides present in the analysed drinking waters reaching values up to 2000 mBq/L, in the southwestern and western of Castilla y León, where U-rich minerals are part of the host rock. High 210Pb and 226,228Ra occurrences are found in the low permeability igneous and metasedimentary hydrogeological formations of Salamanca province. From a public health protection point of view, 4.4% of the total drinking water samples from intakes exceeded the Indicative Dose parametric value of 0.1 mSv, which is a not negligible number of samples, being very likely related to granitic and metamorphosed host rock under specific local conditions. This fact highlights the need for research and consideration of special surveillance of the groundwaters from these areas.  
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  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0043-1354 ISBN Medium  
  Area Expedition Conference  
  Notes Approved no  
  Call Number THL @ christoph.kuells @ borrego-alonso_natural_2023 Serial 157  
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Author Soh, Q.Y.; O’Dwyer, E.; Acha, S.; Shah, N. url  openurl
  Title Robust optimisation of combined rainwater harvesting and flood mitigation systems Type Journal Article
  Year 2023 Publication Water Research Abbreviated Journal  
  Volume 245 Issue Pages 120532  
  Keywords Rainwater harvesting, Flood mitigation, Robust stochastic optimisation, Sustainable environmental engineering, Decision tool, Urban residential estates  
  Abstract Combined large-scale rainwater harvesting (RWH) and flood mitigation systems are promising as a sustainable water management strategy in urban areas. These are multi-purpose infrastructure that not only provide a secondary, localised water resource, but can also reduce discharge and hence loads on any downstream wastewater networks if these are integrated into the wider water network. However, the performance of these systems is dependent on the specific design used for its local catchment which can vary significantly between different implementations. A multitude of design strategies exist, however there is no universally accepted standard framework. To tackle these issues, this paper presents a two-player optimisation framework which utilises a stochastic design optimisation model and a competing, high-intensity rainfall design model to optimise passively-operated RWH systems. A customisable tool set is provided, under which optimisation models specific to a given catchment can be built quickly. This reduces the barriers to implementing computationally complex sizing strategies and encouraging more resource-efficient systems to be built. The framework was applied to a densely populated high-rise residential estate, eliminating overflow events from historical rainfall. The optimised configuration resulted in a 32% increase in harvested water yield, but its ability to meet irrigation demands was limited by the operational levels of the treatment pump. Hence, with the inclusion of operational levels in the optimisation model, the framework can provide an efficient large-scale RWH system that is capable of simultaneously meeting water demands and reducing stresses within and beyond its local catchment.  
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  Series Volume Series Issue Edition  
  ISSN 0043-1354 ISBN Medium  
  Area Expedition Conference  
  Notes Approved no  
  Call Number THL @ christoph.kuells @ Soh2023120532 Serial 243  
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Author Zhang, Y.; Liu, X.; Yuan, S.; Song, J.; Chen, W.; Dias, D. url  openurl
  Title A two-dimensional experimental study of active progressive failure of deeply buried Qanat tunnels in sandy ground Type Journal Article
  Year 2023 Publication Soils and Foundations Abbreviated Journal  
  Volume 63 Issue 3 Pages 101323  
  Keywords Qanat tunnel, Sand, Failure effect, Soil arching, Model test  
  Abstract As an ancient underground hydraulic engineering facility, the Qanat system has been used to draw groundwater from arid regions. A qanat is a horizontal tunnel with a slight incline that draws groundwater from a higher location and delivers it to lower agricultural land. During long-term water delivery, the qanat tunnel has experienced different degrees of aging and collapse, which may result in the significant ground settlement and even disasters. This paper developed a two-dimensional laboratory system to investigate the influence of progressive failure on the stability of deeply buried qanat tunnels. The developed system is fully instrumented with a particle image velocimetry (PIV) system and earth pressure and displacement monitoring. A special cylindrical membrane tube is designed and connected to an advanced pressure–volume controller to simulate the step-wise failure process of the tunnel. Three model tests were conducted on a dry sand considering the buried qanat tunnels at three different depths. Experimental results clearly show the progressive evolution of soil arching effect in the dry sand associated with the progressive failure of the tunnels. The failure of the Qanat ground starts from the vault and develops upwards, which is closely related to the evolution of stress contour at three consecutive stages. Ground surface settlement and volume loss corresponding to three burial depths were compared. A deeply buried qanat tunnel has a small effect on surface settlement. Earth pressure evolution on the 2D plane shows the load redistribution when the qanat collapses. The maximum arch and the initial point of the limit state correspond to a volume loss of 12.5 % and 50 %, respectively. For the collapse of the deep buried qanat tunnel, ground earth pressure evolution can be divided into a stress-increasing region, stress-decreasing region, and no redistribution region. Furthermore, a multi trap-door model considering soil expansion is proposed to describe the progressive failure behavior and its effects.  
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  Series Volume Series Issue Edition  
  ISSN 0038-0806 ISBN Medium  
  Area Expedition Conference  
  Notes Approved no  
  Call Number THL @ christoph.kuells @ Zhang2023101323 Serial 274  
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Author Wang, B.; Luo, Y.; Qian, J.-zhong; Liu, J.-hui; Li, X.; Zhang, Y.-hong; Chen, Q.-qian; Li, L.-yao; Liang, D.-ye; Huang, J. url  openurl
  Title Machine learning–based optimal design of the in-situ leaching process parameter (ISLPP) for the acid in-situ leaching of uranium Type Journal Article
  Year 2023 Publication Journal of Hydrology Abbreviated Journal  
  Volume 626 Issue Pages 130234  
  Keywords In-situ leaching, Injection rate design, Lixiviant concentration design, Machine learning, Simulation-optimisation, Uncertainty  
  Abstract The migration process of leached uranium in the in-situ leaching of uranium is considered a typical reactive transport problem. During this process, the lixiviant concentration and injection rate are important in-situ leaching process parameters (ISLPP) to efficiently recover uranium. However, several uncertain factors affect the outcomes of the ISLPP design. In addition, the repeated use of the reactive transport model (RTM) for investigating the acid in-situ leaching of uranium with the application of the Monte Carlo method leads to a substantial computational load. For this reason, a machine learning (ML)–based surrogate model was developed with the backpropagation neural network (BPNN) method to replace the RTM under the condition of uncertain parameters. Moreover, the simulated annealing optimisation model for ISLPP was created based on the proposed surrogate model. The optimal ISLPP was achieved that generated maximum profits from uranium recovery under different lixiviant prices, uranium prices and exploitation times. The optimal design framework of ISLPP based on the proposed ML algorithm was then applied in the Bayan-Uul sandstone-type uranium deposit in Inner Mongolia, China. From our analysis, it was demonstrated that the ML-based surrogate model exhibited great fitness with the RTM. The optimal results of the ISLPP indicated that the lixiviant concentration and injection rate could be adjusted based on the fluctuations in lixiviant price, uranium price and exploitation time. If the prices of sulphuric acid were high, a specific concentration of hydrogen peroxide could be injected into the injection well to promote the oxidation and dissolution of the uranium ore to increase the income from the uranium recovery. The optimisation model can also use the ISLPP scheme to boost the revenues from different lixiviant prices, uranium prices and exploitation times under the uncertainty of porosity, illustrating the applicability of the ML-based optimal design method of ISLPP in ISL mining. A general framework for developing surrogate models, as well as for conducting uncertainty analyses for a wide range of groundwater models was proposed here yielding valuable insights.  
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  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0022-1694 ISBN Medium  
  Area Expedition Conference  
  Notes Approved no  
  Call Number THL @ christoph.kuells @ wang_machine_2023 Serial 210  
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Author Johnson, R.S.H.; Alila, Y. url  openurl
  Title Nonstationary stochastic paired watershed approach: Investigating forest harvesting effects on floods in two large, nested, and snow-dominated watersheds in British Columbia, Canada Type Journal Article
  Year 2023 Publication Journal of Hydrology Abbreviated Journal  
  Volume 625 Issue Pages 129970  
  Keywords Probabilistic physics, Forest hydrology, Attribution science, Flood Frequency Analysis, Stochastic hydrology, Nonstationarity  
  Abstract Drawing on advances in nonstationary frequency analysis and the science of causation and attribution, this study employs a newly developed nonstationary stochastic paired watershed approach to determine the effect of forest harvesting on snowmelt-generated floods. Moreover, this study furthers the application of stochastic physics to evaluate the environmental controls and drivers of flood response. Physically-based climate and time-varying harvesting data are used as covariates to drive the nonstationary flood frequency distribution parameters to detect, attribute, and quantify the effect of harvesting on floods in the snow-dominated Deadman River (878 km2) and nested Joe Ross Creek (99 km2) watersheds. Harvesting only 21% of the watershed caused a 38% and 84% increase in the mean but no increase in variability around the mean of the frequency distribution in the Deadman River and Joe Ross Creek, respectively. Consequently, the 7-year, 20-year, 50-year, and 100-year flood events became approximately two, four, six, and ten times more frequent in both watersheds. An increase in the mean is posited to occur from an increase in moisture availability following harvest from suppressed snow interception and increased net radiation reaching the snowpack. Variability was not increased because snowmelt synchronization was inhibited by the buffering capacity of abundant lakes, evenly distributed aspects, and widespread spatial distribution of cutblocks in the watersheds, preventing any potential for harvesting to increase the efficiency of runoff delivery to the outlet. Consistent with similar recent studies, the effect of logging on floods is controlled not only by the harvest rate but most importantly the physiographic characteristics of the watershed and the spatial distribution of the cutblocks. Imposed by the probabilistic framework to understanding and predicting the relation between extremes and their environmental controls, commonly used in the general sciences but not forest hydrology, it is the inherent nature of snowmelt-driven flood regimes which cause even modest increases in magnitude, especially in the upper tail of the distribution, to translate into surprisingly large changes in frequency. Contrary to conventional wisdom, harvesting influenced small, medium, and very large flood events, and the sensitivity to harvest increased with increasing flood event size and watershed area.  
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  ISSN 0022-1694 ISBN Medium  
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  Notes Approved no  
  Call Number THL @ christoph.kuells @ Johnson2023129970 Serial 245  
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Author Gimeno, M.J.; Tullborg, E.-L.; Nilsson, A.-C.; Auqué, L.F.; Nilsson, L. url  openurl
  Title Hydrogeochemical characterisation of the groundwater in the crystalline basement of Forsmark, the selected area for the geological nuclear repositories in Sweden Type Journal Article
  Year 2023 Publication Journal of Hydrology Abbreviated Journal  
  Volume 624 Issue Pages 129818  
  Keywords Crystalline bedrock, Deep geological repository, Glacial meltwater intrusion, Groundwater mixing, Hydrogeochemical model, Nuclear waste disposal  
  Abstract Numerous groundwater analyses from the crystalline bedrock in the Forsmark area have been performed between 2002 and 2019, together with thorough geological, geophysical, and hydrogeological studies, within the site investigations carried out by the Swedish Nuclear Fuel and Waste Management Company. The groundwater samples have been taken from boreholes down to ≈ 1000 m and the analysis include major- and trace-elements, stable and radiogenic isotopes, gases and microbes. The chemical and isotopic composition of these groundwaters evidences the presence of non-marine brackish to saline groundwaters with very long residence times (many hundreds of thousands of years) and a series of complex mixing events resulting from the recharge of different waters over time: glacial meltwaters, probably from different glaciations of which the latest culminated some 20,000 years ago, and marine waters from the Baltic starting some 7000 years ago. Later, meteoric water and present Baltic Sea water have recharged in different parts of the upper 100 m. These mixing events have also triggered chemical and microbial reactions that have conditioned some of the important groundwater parameters and, together with the structural complexity of the area, they have promoted a heterogeneous distribution of groundwater compositions in the bedrock. Due to these evident differences in chemistry, residence time and origin of the groundwater, several groundwater types were defined in order to facilitate the visualisation and communication. The differentiation (linked to the paleohydrological history of the area) was based on Cl concentration, Cl/Mg ratio (marine component), and δ18O value (glacial component). The work presented in this paper increases the understanding of the groundwater evolution in fractured and compartmentalised aquifers where mixing processes are the most important mechanisms. The model proposed to characterise the present groundwater system of the Forsmark area will also help to predict the future hydrogeochemical behaviour of the groundwater system after the construction of the repositories for the nuclear wastes.  
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  ISSN 0022-1694 ISBN Medium  
  Area Expedition Conference  
  Notes Approved no  
  Call Number THL @ christoph.kuells @ gimeno_hydrogeochemical_2023 Serial 137  
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Author Heidari, B.; Prideaux, V.; Jack, K.; Jaber, F.H. url  openurl
  Title A planning framework to mitigate localized urban stormwater inlet flooding using distributed Green Stormwater Infrastructure at an urban scale: Case study of Dallas, Texas Type Journal Article
  Year 2023 Publication Journal of Hydrology Abbreviated Journal  
  Volume 621 Issue Pages 129538  
  Keywords Green stormwater infrastructure, Localized inlet pluvial flooding, Opportunity subwatersheds, Stormwater investment prioritization, Resilient urban watershed planning  
  Abstract Mitigation of localized pluvial flooding is one of the major resiliency goals in urban environments, and Green Stormwater Infrastructure (GSI) has the potential to deliver such an outcome. However, there is a lack of systematic approaches to prioritize investment in different candidate areas. This study provides a framework to identify vulnerable stormwater drainage inlets and their contributing areas, prioritize them, identify dominant factors in their selection, assess the potential of GSI in mitigating their overflows, and compare the impact and its cost to gray infrastructure upgrade alternatives. Using SWMM 5.1.013, decision trees, and a volumetric-based assessment of GSI overflow capture, we applied the framework to the City of Dallas, Texas, for three design storms with three GSI practices— bioretention cells, raingardens, and rainwater harvesting tanks. Results showed that there was a significant increase in the number of overflowing stormwater drainage inlets, referred to as hotspots, and their contributing subwatersheds, referred to as opportunity areas, with more intense storms especially in problematic watersheds. Also, prioritization results provided a series of maps to rank the opportunity areas based on overflow severity, recurrence of the overflows, and GSI availability. Moreover, classification results showed that inlet features, especially the inlet depth, were the dominant factors in the identification of the non-problematic inlets. Finally, the GSI impact assessment showed substantial overflow mitigation even at the “very high” severity levels when GSI is comprehensively deployed across opportunity areas. Despite gray infrastructure upgrades yielding higher reduction levels, their cost per cubic meter was higher than GSI. Therefore, a combination of GSI and gray results in maximum overflow reduction at a lower cost compared to common practices.  
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  ISSN 0022-1694 ISBN Medium  
  Area Expedition Conference  
  Notes Approved no  
  Call Number THL @ christoph.kuells @ Heidari2023129538 Serial 226  
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