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Author Hall, S.M.; Gosen, B.S.V.; Paces, J.B.; Zielinski, R.A.; Breit, G.N. url  openurl
  Title Calcrete uranium deposits in the Southern High Plains, USA Type Journal Article
  Year 2019 Publication Ore Geology Reviews Abbreviated Journal  
  Volume (down) 109 Issue Pages 50-78  
  Keywords Calcrete, Carnotite, Finchite, Geochemistry, Uranium, Vanadium  
  Abstract The Southern High Plains (SHP) is a new and emerging U.S. uranium province. Here, uranyl vanadates form deposits in Pliocene to Pleistocene sandstone, dolomite, and limestone. Fifteen calcrete uranium occurrences are identified; two of these, the Buzzard Draw and Sulfur Springs Draw deposits, have combined in-place resources estimated at about 4 million pounds of U3O8. Ore minerals carnotite and finchite are hosted in dolomite at the Sulfur Springs Draw deposit, with accessory fluorite, celestine, smectite/illite, autunite, and strontium carbonate. Host carbonate at the Sulfur Springs Draw deposit is ∼190 ka and mineralization mobilized as recently as 3.8 ka. Ash collected near the deposit is 631 ka and erupted from the Yellowstone caldera complex. The Triassic Dockum Group that contains sandstone-hosted uranium deposits throughout the region and underlies the SHP is a potential source for uranium and vanadium. Regional uplift and dissection reintroduced oxygenated groundwater into the Dockum Group, mobilizing uranium. Additional uranium may have been contributed to groundwater by weathering of volcanic ash in Pliocene and Pleistocene host rocks. The locations of the uranium occurrences are mostly in modern drainage systems in the southeast portion of the SHP. Modelling of modern groundwater in the SHP carried out in a parallel study shows that a single fluid could form carnotite through evaporation, and that fluids of the requisite composition are more prevalent in the southern portion of the SHP. The southeastern portion of the SHP hosts more uranium occurrences due to a variety of factors including (1) upward transport of groundwater and connectivity between source and host rock, (2) higher uranium and vanadium content of groundwater, (3) higher rates of groundwater recharge in this region to drive the mineralizing system, and (4) shallower groundwater facilitating surface evaporation. Ongoing erosion of host rocks challenges preservation of deposits and may limit their size.  
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  ISSN 0169-1368 ISBN Medium  
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  Notes Approved no  
  Call Number THL @ christoph.kuells @ hall_calcrete_2019 Serial 124  
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Author Ruiz, O.; Thomson, B.; Cerrato, J.M.; Rodriguez-Freire, L. url  openurl
  Title Groundwater restoration following in-situ recovery (ISR) mining of uranium Type Journal Article
  Year 2019 Publication Applied Geochemistry Abbreviated Journal  
  Volume (down) 109 Issue Pages 104418  
  Keywords Aquifer stabilization, Ground water restoration, In-situ leach mining, In-situ recovery, Uranium  
  Abstract From 1950 through the early 1980’s New Mexico accounted for roughly half of domestic uranium (U) production for the nuclear power industry and the nation’s weapon programs. Increased interest in nuclear energy has led to proposals for renewed development using both underground mining and uranium in situ recovery (ISR). When feasible, ISR greatly reduces waste generated by the mining and milling processes, however, the ability to restore ground water to acceptable quality after ISR ends is uncertain. This research investigated two methods of stabilizing an aquifer following ISR. Batch and column studies were performed to evaluate chemical and biological methods of stabilization. Columns packed with ore were first leached with an aerated NaHCO3 ground water solution to simulate ISR. Constituents present at elevated concentrations after leaching included molybdenum (Mo), selenium (Se), U, and vanadium (V). Chemical stabilization was studied by passing a phosphate (PO43-) amended solution through the ore to achieve passivation of mineral surfaces by P precipitates. Microbial stabilization was studied by passing a lactate solution through the ore to stimulate growth of anaerobic metal- and sulfate-reducing organisms to reduce U and other elements to less soluble phases. Analyses of the solids from the columns after completion of these experiments by X-ray photo electron spectroscopy (XPS) identified phosphate on samples near the column inlet of the chemically stabilized columns. Microbial populations were characterized by Illumina DNA sequencing and confirmed the presence of metal- and sulfate-reducing organisms. Neither chemical nor microbial stabilization method achieved contaminant immobilization, which is believed due to limited mixing of the stabilization solutions with the contaminated leach solutions. These results emphasize that ground water hydrodynamics, especially mixing, must be considered in aquifer restoration of soluble constituents.  
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  ISSN 0883-2927 ISBN Medium  
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  Notes Approved no  
  Call Number THL @ christoph.kuells @ ruiz_groundwater_2019 Serial 153  
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Author Rossetto, R.; Filippis, G.D.; Borsi, I.; Foglia, L.; Cannata, M.; Criollo, R.; Vázquez-Suñé, E. url  openurl
  Title Integrating free and open source tools and distributed modelling codes in GIS environment for data-based groundwater management Type Journal Article
  Year 2018 Publication Environmental Modelling & Software Abbreviated Journal  
  Volume (down) 107 Issue Pages 210-230  
  Keywords Free and Open Source Software, FREEWAT, Groundwater management, ICT, MODFLOW, QGIS  
  Abstract Integrating advanced simulation techniques and data analysis tools in a freeware Geographic Information System (GIS) provides a valuable contribution to the management of conjunctive use of groundwater (the world’s largest freshwater resource) and surface-water. To this aim, we describe here the FREEWAT (FREE and open source software tools for WATer resource management) platform. FREEWAT is a free and open source, QGIS-integrated interface for planning and management of water resources, with specific attention to groundwater. The FREEWAT platform couples the power of GIS geo-processing and post-processing tools in spatial data analysis with that of process-based simulation models. The FREEWAT environment allows storage of large spatial datasets, data management and visualization, and running of several distributed modelling codes (mainly belonging to the MODFLOW family). It simulates hydrologic and transport processes, and provides a database framework and visualization capabilities for hydrochemical analysis. Examples of real case study applications are provided.  
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  ISSN 1364-8152 ISBN Medium  
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  Notes Approved no  
  Call Number THL @ christoph.kuells @ rossetto_integrating_2018 Serial 92  
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Author Brutsaert, W. url  openurl
  Title Global land surface evaporation trend during the past half century: Corroboration by Clausius-Clapeyron scaling Type Journal Article
  Year 2017 Publication Advances in Water Resources Abbreviated Journal  
  Volume (down) 106 Issue Pages 3-5  
  Keywords Evaporation, Climate change, Evaporation trend  
  Abstract Analyses of satellite data mainly over the world’s ocean surfaces have shown that during 1986–2006 global average values of atmospheric water vapor, precipitation and evaporation have increased at a relative rate of 0.0013a−1; this is roughly in accordance with the Clausius-Clapeyron equation for the average temperature trend during this period, and amounts to 0.065K−1 at the average temperature of T=14∘C. Application of this concept over the world’s land surfaces yields an average global evaporation trend during the past half century of around 0.4 to 0.5 mma−2; this confirms the values obtained in previous studies with totally different methods.  
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  ISSN 0309-1708 ISBN Medium  
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  Notes Tribute to Professor Garrison Sposito: An Exceptional Hydrologist and Geochemist Approved no  
  Call Number THL @ christoph.kuells @ Brutsaert20173 Serial 287  
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Author Stone, A.E.C.; Edmunds, W.M. url  openurl
  Title Naturally-high nitrate in unsaturated zone sand dunes above the Stampriet Basin, Namibia Type Journal Article
  Year 2014 Publication Journal of Arid Environments Abbreviated Journal  
  Volume (down) 105 Issue Pages 41-51  
  Keywords Kalahari, Namibia, Nitrate in the unsaturated zone, Stampriet Basin, Transboundary basin, Unsaturated zone recharge  
  Abstract Elevated groundwater nitrate levels are common in drylands, often in excess of WHO guidelines, with concern for human and animal health. In light of recent attempts to identify nitrate sources in the Kalahari this paper presents the first unsaturated zone (USZ) nitrate profiles and recharge rate estimates for the important transboundary Stampriet Basin, alongside the first rainfall chemistry records. Elevated subsurface nitrate reaches 100–250 and 250–525 mg/L NO3–N, with NO3–N/Cl of 4–12, indicating input above evapotranspiration. Chloride mass balance recharge rates range from 4 to 27 mm/y, indicating a vertical movement of these nitrate pulses toward the water table over multi-decadal timescales. These profiles are sampled from dune crests, away from high concentrations of animals and without termite mounds. Given low-density animal grazing is unlikely to contribute consistent spot-scale nitrate over decades, these profiles give an initial estimate of naturally-produced concentrations. This insight is important for the management of the Stampriet Basin and wider Kalahari groundwater. This study expands our knowledge about elevated nitrate in dryland USZs, demonstrating that it can occur as pulses, probably in response to transient vegetation cover and that it is not limited to long-residence time USZs with very limited downward moisture flux (recharge).  
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  ISSN 0140-1963 ISBN Medium  
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  Notes Approved no  
  Call Number THL @ christoph.kuells @ stone_naturally-high_2014 Serial 91  
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