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Author |
Christofi, C.; Bruggeman, A.; Külls, C.; Constantinou, C. |
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Title |
Isotope hydrology and hydrogeochemical modeling of Troodos Fractured Aquifer, Cyprus: The development of hydrogeological descriptions of observed water types |
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2020 |
Publication |
Applied Geochemistry |
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123 |
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104780 |
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Isotope hydrology, Hydrogeochemical modelling, Hydrochemistry, Kargiotis, Troodos |
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Abstract |
The origin of groundwater recharge and subsequent flow paths are often difficult to establish in fractured, multi-lithological, and highly compartmentalized aquifers such as the Troodos Fractured Aquifer (TFA). As the conjunctive use of stable isotopes and hydrogeochemical data provides additional information, we established a monitoring network for stable isotopes in precipitation in Cyprus. The local meteoric water line, altitude effect and seasonal variation of stable isotopes in precipitation are derived from monitoring data. Stable isotopes and hydrogeochemical data are combined to model water-rock interactions and groundwater evolution along a complete ophiolite sequence. As a result a generic hydrogeologic description for the observed water types is developed. Isotope hydrology was applied in conjunction with hydrogeochemical modelling in Kargiotis Watershed, a major north-south transect of the TFA. PHREEQC was used for hydrogeochemical modelling to establish generic descriptions for observed water types. Mean precipitation-weighted values from 16 monitoring stations were used to calculate the Local Meteoric Water Line (LMWL), which was found to be equal to δ2H = (6.58 ± 0.13)*δ18O + (12.64 ± 0.91). A general decrease of 1.22‰ for δ2H and 0.20‰ for δ18O in precipitation was calculated per 100 m altitude. A generic groundwater evolution path was established: 1. Na/MgClHCO3, 2. MgHCO3, 3. Ca/MgHCO3, 4. Ca/MgNaHCO3, 4a. MgNa/CaHCO3/Cl, 5. NaMg/CaHCO3/Cl, 6. NaHCO3, 7. Na/MgHCO3SO4, 8. NaSO4Cl/HCO3. Hydrogeologic descriptions, consisting of groundwater origin, flow path and possible active water-rock processes, have been realised for the observed water types. The first two water types occur in serpentine and ultramafic-gabbro springs. Type 3 waters represent early stages of recharge and/or short flow paths, in gabbro whereas types 4 and 5 are typical for further percolating waters in gabbro and diabase. Water types 6 and 7 occur both in diabase and in the basal group and represent the regional flow. Water type 8 is the end member of regional, upwelling groundwater in the basal group. The presented descriptions and methods have practical applications in groundwater exploration, characterization, and protection. The methodology can be applied in other complex aquifer systems. |
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english |
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english |
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0883-2927 |
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Cyprus |
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THL @ christoph.kuells @ Christofi2020104780 |
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76 |
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Krüger, N.; Külls, C.; Bruggeman, A.; Eliades, M.; Christophi, C.; Rigas, M.; Eracleous, T. |
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Title |
Groundwater recharge estimates with soil isotope profiles-is there a bias on coarse-grained hillslopes? |
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2020 |
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EGU General Assembly Conference Abstracts |
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9840 |
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THL @ christoph.kuells @ Krueger2020groundwater |
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42 |
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Külls, C.H.; Eichinger, F.; Fader, H.J.; Leistert, H.; Lorenz, G.; Szakacs, E. |
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New Environmental Analytical Techniques to Monitor Carbon Sequestration |
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2011 |
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1st EAGE Sustainable Earth Sciences (SES) Conference and Exhibition |
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268 |
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European Association of Geoscientists & Engineers |
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THL @ christoph.kuells @ Kuells2011new |
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47 |
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Frey, S.; Külls, C.; Schlosser, C. |
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New Hydrological Age-Dating techniques using cosmogenic radionuclides Beryllium-7 and Sodium-22 |
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2011 |
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Proc. IAEA Conf. Monacco |
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THL @ christoph.kuells @ Frey2011new |
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48 |
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Adolph, G.; Römer, T.; Külls, C. |
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Deriving complex groundwater age structure by combining age dating and analytic element modelling |
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G-DAT 2008-Leipzig |
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12 |
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THL @ christoph.kuells @ Adolph2008deriving |
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55 |
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Külls, C.; Haering, M.; Leistert, H.; Oster, H. |
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Title |
Hydrological, physical and chemical constraints for groundwater age dating with CFC and SF6 |
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G-DAT 2008-Leipzig |
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29 |
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THL @ christoph.kuells @ Kuells2008hydrological |
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57 |
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Tröger, U.; Dias, C.L.; Guillaumon, J.R.; Iritani, M.A.; Külls, C.; Schuler, G. |
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Title |
Remarks and new data about the recharge of the Guarani Aquifer System |
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2004 |
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XXXIII IAH Congress, Abstracts, IAH, Mexico |
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THL @ christoph.kuells @ Troeger2004remarks |
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59 |
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Author |
Udluft, P.; Külls, C. |
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Title |
Mapping the availability and dynamics of groundwater recharge. Part 1: modelling techniques |
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2000 |
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Proceedings of the Third Congress on Regional Geological Cartography and Information Systems |
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337-340 |
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THL @ christoph.kuells @ Udluft2000mapping |
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64 |
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Author |
Külls, C.; Jobin, J.; Weiler, M. |
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Title |
Environmental analytics for water carbon management: enable WCM: Schlussbericht |
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2015 |
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Albert Ludwigs Universität, Professur für Hydrologie |
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THL @ christoph.kuells @ Kuells2015environmental |
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65 |
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Udluft, P.; Dünkeloh, A.; Mederer, J.; Külls, C.; Schaller, J. |
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Title |
Re-evaluation of the groundwater resources of Cyprus |
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2006 |
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Lefkosia |
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THL @ christoph.kuells @ Udluft2006re |
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66 |
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